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Title: The crystalline sponge method: MOF terminal ligand effects

Abstract

Bromide and chloride analogs of the commonly used zinc iodide-based metal organic framework for the crystalline sponge method were synthesized and evaluated. Inclusion of (1R)-(–)-menthyl acetate into these MOFs was analysed using third-generation synchrotron radiation, and the effects and potential benefits of varying the MOF terminal ligand are discussed.

Authors:
 [1];  [2];  [3];  [1]
  1. Harvard Medical School, Boston, MA (United States)
  2. Harvard Univ., Cambridge, MA (United States)
  3. Univ. of Chicago, IL (United States); Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Publication Date:
Research Org.:
Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Org.:
National Institutes of Health (NIH); National Science Foundation (NSF); USDOE Office of Science (SC)
OSTI Identifier:
1203759
Grant/Contract Number:  
U19-AI109673; F32-GM108415; NSF/CHE-1346572; AC02-06CH11357
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 51; Journal Issue: 56; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
ENGLISH
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Ramadhar, Timothy R., Zheng, Shao-Liang, Chen, Yu-Sheng, and Clardy, Jon. The crystalline sponge method: MOF terminal ligand effects. United States: N. p., 2015. Web. doi:10.1039/c5cc03840e.
Ramadhar, Timothy R., Zheng, Shao-Liang, Chen, Yu-Sheng, & Clardy, Jon. The crystalline sponge method: MOF terminal ligand effects. United States. https://doi.org/10.1039/c5cc03840e
Ramadhar, Timothy R., Zheng, Shao-Liang, Chen, Yu-Sheng, and Clardy, Jon. 2015. "The crystalline sponge method: MOF terminal ligand effects". United States. https://doi.org/10.1039/c5cc03840e. https://www.osti.gov/servlets/purl/1203759.
@article{osti_1203759,
title = {The crystalline sponge method: MOF terminal ligand effects},
author = {Ramadhar, Timothy R. and Zheng, Shao-Liang and Chen, Yu-Sheng and Clardy, Jon},
abstractNote = {Bromide and chloride analogs of the commonly used zinc iodide-based metal organic framework for the crystalline sponge method were synthesized and evaluated. Inclusion of (1R)-(–)-menthyl acetate into these MOFs was analysed using third-generation synchrotron radiation, and the effects and potential benefits of varying the MOF terminal ligand are discussed.},
doi = {10.1039/c5cc03840e},
url = {https://www.osti.gov/biblio/1203759}, journal = {ChemComm},
issn = {1359-7345},
number = 56,
volume = 51,
place = {United States},
year = {Tue Jun 02 00:00:00 EDT 2015},
month = {Tue Jun 02 00:00:00 EDT 2015}
}

Journal Article:
Free Publicly Available Full Text
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Cited by: 56 works
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Works referenced in this record:

X-ray analysis on the nanogram to microgram scale using porous complexes
journal, March 2013


One size fits most
journal, March 2013


Preparation and guest-uptake protocol for a porous complex useful for 'crystal-free' crystallography
journal, January 2014


Structural Reevaluation of the Electrophilic Hypervalent Iodine Reagent for Trifluoromethylthiolation Supported by the Crystalline Sponge Method for X-ray Analysis
journal, February 2014


Radical CH Functionalization of Heteroarenes under Electrochemical Control
journal, September 2014


Absolute structure determination of compounds with axial and planar chirality using the crystalline sponge method
journal, January 2015


Erratum: Corrigendum: X-ray analysis on the nanogram to microgram scale using porous complexes
journal, August 2013


Dramatic Structural Rearrangements in Porous Coordination Networks
journal, April 2011


Interpenetrating Nets: Ordered, Periodic Entanglement
journal, June 1998


Use of intensity quotients and differences in absolute structure refinement
journal, May 2013


PLATON SQUEEZE: a tool for the calculation of the disordered solvent contribution to the calculated structure factors
journal, January 2015


OLEX2 : a complete structure solution, refinement and analysis program
journal, January 2009


Radical CH Functionalization of Heteroarenes under Electrochemical Control
journal, September 2014


Dramatic Structural Rearrangements in Porous Coordination Networks
journal, April 2011


Bird-like fossil footprints from the Late Triassic
journal, June 2002


Single-crystal X-ray diffraction studies on structural transformations of porous coordination polymers
journal, January 2014


Determination of absolute structure using Bayesian statistics on Bijvoet differences
journal, January 2008


Data-collection strategies
journal, October 1999


Analysis of rapidly synthesized guest-filled porous complexes with synchrotron radiation: practical guidelines for the crystalline sponge method
journal, January 2015


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A flexible thioether-based MOF as a crystalline sponge for structural characterization of liquid organic molecules
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journal, March 2016