The crystalline sponge method: MOF terminal ligand effects
Abstract
Bromide and chloride analogs of the commonly used zinc iodide-based metal organic framework for the crystalline sponge method were synthesized and evaluated. Inclusion of (1R)-(–)-menthyl acetate into these MOFs was analysed using third-generation synchrotron radiation, and the effects and potential benefits of varying the MOF terminal ligand are discussed.
- Authors:
-
- Harvard Medical School, Boston, MA (United States)
- Harvard Univ., Cambridge, MA (United States)
- Univ. of Chicago, IL (United States); Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
- Sponsoring Org.:
- National Institutes of Health (NIH); National Science Foundation (NSF); USDOE Office of Science (SC)
- OSTI Identifier:
- 1203759
- Grant/Contract Number:
- U19-AI109673; F32-GM108415; NSF/CHE-1346572; AC02-06CH11357
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- ChemComm
- Additional Journal Information:
- Journal Volume: 51; Journal Issue: 56; Journal ID: ISSN 1359-7345
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- ENGLISH
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Ramadhar, Timothy R., Zheng, Shao-Liang, Chen, Yu-Sheng, and Clardy, Jon. The crystalline sponge method: MOF terminal ligand effects. United States: N. p., 2015.
Web. doi:10.1039/c5cc03840e.
Ramadhar, Timothy R., Zheng, Shao-Liang, Chen, Yu-Sheng, & Clardy, Jon. The crystalline sponge method: MOF terminal ligand effects. United States. https://doi.org/10.1039/c5cc03840e
Ramadhar, Timothy R., Zheng, Shao-Liang, Chen, Yu-Sheng, and Clardy, Jon. 2015.
"The crystalline sponge method: MOF terminal ligand effects". United States. https://doi.org/10.1039/c5cc03840e. https://www.osti.gov/servlets/purl/1203759.
@article{osti_1203759,
title = {The crystalline sponge method: MOF terminal ligand effects},
author = {Ramadhar, Timothy R. and Zheng, Shao-Liang and Chen, Yu-Sheng and Clardy, Jon},
abstractNote = {Bromide and chloride analogs of the commonly used zinc iodide-based metal organic framework for the crystalline sponge method were synthesized and evaluated. Inclusion of (1R)-(–)-menthyl acetate into these MOFs was analysed using third-generation synchrotron radiation, and the effects and potential benefits of varying the MOF terminal ligand are discussed.},
doi = {10.1039/c5cc03840e},
url = {https://www.osti.gov/biblio/1203759},
journal = {ChemComm},
issn = {1359-7345},
number = 56,
volume = 51,
place = {United States},
year = {Tue Jun 02 00:00:00 EDT 2015},
month = {Tue Jun 02 00:00:00 EDT 2015}
}
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