Materials Data on RbAl(H2N)4 by Materials Project

Dataset · Thu May 11 00:00:00 EDT 2017

DOI:https://doi.org/10.17188/1200129· OSTI ID:1200129

The Materials Project

RbAl(NH)4(H2)2 crystallizes in the tetragonal P4/n space group. The structure is two-dimensional and consists of four hydrogen molecules and one RbAl(NH)4 sheet oriented in the (0, 0, 1) direction. In the RbAl(NH)4 sheet, Rb1+ is bonded in a square co-planar geometry to four equivalent N3- atoms. All Rb–N bond lengths are 3.21 Å. Al3+ is bonded in a tetrahedral geometry to four equivalent N3- atoms. All Al–N bond lengths are 1.90 Å. N3- is bonded in a distorted water-like geometry to one Rb1+, one Al3+, and one H1+ atom. The N–H bond length is 1.04 Å. H1+ is bonded in a single-bond geometry to one N3- atom.

• Research Organization: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
• Sponsoring Organization: USDOE Office of Science (SC), Basic Energy Sciences (BES)
• Contributing Organization: MIT; UC Berkeley; Duke; U Louvain
• DOE Contract Number: AC02-05CH11231; EDCBEE
• OSTI ID: 1200129
• Report Number(s): mp-24515
• Resource Relation: Related Information: https://materialsproject.org/citing
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
crystal structure
RbAl(H2N)4
Al-H-N-Rb