Humidity-dependent compression-induced glass transition of the air–water interfacial Langmuir films of poly(D,L-lactic acid-ran-glycolic acid) (PLGA)

Kim, Hyun Chang; Lee, Hoyoung; Jung, Hyunjung; Choi, Yun -Hwa; Meron, Mati; Lin, Binhua; Bang, Joona; Won, You -Yeon

doi:10.1039/C4SM02535K

Title: Humidity-dependent compression-induced glass transition of the air–water interfacial Langmuir films of poly(D,L-lactic acid-ran-glycolic acid) (PLGA)

Journal Article · Tue Jul 21 00:00:00 EDT 2015 · Soft Matter

DOI:https://doi.org/10.1039/C4SM02535K· OSTI ID:1197045

Kim, Hyun Chang ^[1]; Lee, Hoyoung ^[1]; Jung, Hyunjung ^[2]; Choi, Yun -Hwa ^[1]; Meron, Mati ^[3]; Lin, Binhua ^[3]; Bang, Joona ^[2]; Won, You -Yeon ^[1]

Purdue Univ., West Lafayette, IN (United States)
Korea Univ., Seoul (Korea)
Univ. of Chicago, Chicago, IL (United States)

Constant rate compression isotherms of the air–water interfacial Langmuir films of poly(D,L-lactic acid-ran-glycolic acid) (PLGA)show a distinct feature of an exponential increase in surface pressure in the high surface polymer concentration regime. We have previously demonstrated that this abrupt increase in surface pressure is linked to the glass transition of the polymer film, but the detailed mechanism of this process is not understood. In order to obtain a molecular-level understanding of this behavior, we performed extensive characterizations of the surface mechanical, structural and rheological properties of Langmuir PLGA films at the air–water interface, using combined experimental techniques including the Langmuir film balance, X-ray reflectivity and double-wall-ring interfacial rheometry methods.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: National Science Foundation (NSF)

OSTI ID:: 1197045

Journal Information:: Soft Matter, Vol. 11, Issue 28; ISSN 1744-683X

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: ENGLISH

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Cited by: 15 works

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Title: Humidity-dependent compression-induced glass transition of the air–water interfacial Langmuir films of poly(D,L-lactic acid-ran-glycolic acid) (PLGA)

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