Materials Data on RhF3 by Materials Project
RhF3 crystallizes in the trigonal P321 space group. The structure is three-dimensional. there are two inequivalent Rh3+ sites. In the first Rh3+ site, Rh3+ is bonded to six F1- atoms to form corner-sharing RhF6 octahedra. The corner-sharing octahedral tilt angles are 45°. There are three shorter (1.98 Å) and three longer (2.02 Å) Rh–F bond lengths. In the second Rh3+ site, Rh3+ is bonded to six equivalent F1- atoms to form distorted corner-sharing RhF6 pentagonal pyramids. The corner-sharing octahedral tilt angles are 38°. All Rh–F bond lengths are 2.06 Å. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a bent 150 degrees geometry to two Rh3+ atoms. In the second F1- site, F1- is bonded in a distorted bent 150 degrees geometry to two equivalent Rh3+ atoms.
- Research Organization:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Contributing Organization:
- MIT; UC Berkeley; Duke; U Louvain
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- OSTI ID:
- 1196484
- Report Number(s):
- mp-21208
- Resource Relation:
- Related Information: https://materialsproject.org/citing
- Country of Publication:
- United States
- Language:
- English
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