Metal-organic frameworks with exceptionally large pore aperatures

Yaghi, Omar M.; Furukawa, Hiroyasu; Deng, Hexiang

Title: Metal-organic frameworks with exceptionally large pore aperatures

Patent · Tue Jul 14 00:00:00 EDT 2015

OSTI ID:1193402

Yaghi, Omar M.; Furukawa, Hiroyasu; Deng, Hexiang

The disclosure relates to metal organic frameworks or isoreticular metal organic frameworks, methods of production thereof, and methods of use thereof.

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Research Organization:: Univ. of California, Oakland, CA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: FG02-08ER15935

Assignee:: The Regents of the University of California (Oakland, CA)

Patent Number(s):: 9,078,922

Application Number:: 13/650,232

OSTI ID:: 1193402

Resource Relation:: Patent File Date: 2012 Oct 12

Country of Publication:: United States

Language:: English

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Modular Chemistry: Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal−Organic Carboxylate Frameworks Eddaoudi, Mohamed; Moler, David B.; Li, Hailian Accounts of Chemical Research, Vol. 34, Issue 4, p. 319-330 https://doi.org/10.1021/ar000034b	journal	April 2001
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Preparation of Single Crystals of Coordination Solids in Silica Gels: Synthesis and Structure of Cu^II(1,4-C₄H₄N₂)(C₄O₄)(OH₂)₄ Yaghi, O. M.; Li, Guangming; Groy, T. L. Journal of Solid State Chemistry, Vol. 117, Issue 2, p. 256-260 https://doi.org/10.1006/jssc.1995.1271	journal	July 1995
Hydrothermal Synthesis of a Metal-Organic Framework Containing Large Rectangular Channels Yaghi, O. M.; Li, Hailian Journal of the American Chemical Society, Vol. 117, Issue 41, p. 10401-10402 https://doi.org/10.1021/ja00146a033	journal	October 1995
T-Shaped Molecular Building Units in the Porous Structure of Ag(4,4‘-bpy)·NO₃ Yaghi, O. M.; Li, Hailian Journal of the American Chemical Society, Vol. 118, Issue 1, p. 295-296 https://doi.org/10.1021/ja953438l	journal	January 1996
Construction of Porous Solids from Hydrogen-Bonded Metal Complexes of 1,3,5-Benzenetricarboxylic Acid Yaghi, O. M.; Li, Hailian; Groy, T. L. Journal of the American Chemical Society, Vol. 118, Issue 38, p. 9096-9101 https://doi.org/10.1021/ja960746q	journal	January 1996
Selective Guest Binding by Tailored Channels in a 3-D Porous Zinc(II)−Benzenetricarboxylate Network Yaghi, O. M.; Davis, Charles E.; Li, Guangming Journal of the American Chemical Society, Vol. 119, Issue 12, p. 2861-2868 https://doi.org/10.1021/ja9639473	journal	March 1997
Crystal Growth of Extended Solids by Nonaqueous Gel Diffusion Yaghi, O. M.; Li, Guangming; Li, Hailian Chemistry of Materials, Vol. 9, Issue 5, p. 1074-1076 https://doi.org/10.1021/cm970069e	journal	May 1997
A Molecular Railroad with Large Pores: Synthesis and Structure of Ni(4,4‘-bpy)_2.5(H₂O)₂(ClO₄)₂·1.5(4,4‘-bpy)·2H₂O Yaghi, O. M.; Li, Hailian; Groy, Thomas L. Inorganic Chemistry, Vol. 36, Issue 20, p. 4292-4293 https://doi.org/10.1021/ic970423a	journal	September 1997
Construction of a new open-framework solid from 1,3,5-cyclohexanetricarboxylate and zinc(II) building blocks Yaghi, Omar M.; Jernigan, Ryan; Li, Hailian Journal of the Chemical Society, Dalton Transactions, Vol. 0, Issue 14, p. 2383-2384 https://doi.org/10.1039/a702287e	journal	January 1997
Synthetic Strategies, Structure Patterns, and Emerging Properties in the Chemistry of Modular Porous Solids^† Yaghi, Omar M.; Li, Hailian; Davis, Charles Accounts of Chemical Research, Vol. 31, Issue 8, p. 474-484 https://doi.org/10.1021/ar970151f	journal	August 1998
Design of Solids from Molecular Building Blocks: Golden Opportunities for Solid State Chemistry Yaghi, O. M.; O'Keeffe, M.; Kanatzidis, M. Journal of Solid State Chemistry, Vol. 152, Issue 1, p. 1-2 https://doi.org/10.1006/jssc.2000.8733	journal	June 2000
Reticular synthesis and the design of new materials Yaghi, Omar M.; O'Keeffe, Michael; Ockwig, Nathan W. Nature, Vol. 423, Issue 6941, p. 705-714 https://doi.org/10.1038/nature01650	journal	June 2003
Metal–organic Frameworks: A tale of two entanglements Yaghi, Omar M. Nature Materials, Vol. 6, Issue 2, p. 92-93 https://doi.org/10.1038/nmat1824	journal	February 2007
Reticular Chemistry and Metal-Organic Frameworks for Clean Energy Yaghi, Omar M.; Li, Qiaowei MRS Bulletin, Vol. 34, Issue 9, p. 682-690 https://doi.org/10.1557/mrs2009.180	journal	September 2009
Docking in Metal-Organic Frameworks Li, Qiaowei; Zhang, Wenyu; Miljanic, Ognjen S. Science, Vol. 325, Issue 5942, p. 855-859 https://doi.org/10.1126/science.1175441	journal	August 2009
Rigid-Strut-Containing Crown Ethers and [2]Catenanes for Incorporation into Metal-Organic Frameworks Zhao, Yan-Li; Liu, Lihua; Zhang, Wenyu Chemistry - A European Journal, Vol. 15, Issue 48, p. 13356-13380 https://doi.org/10.1002/chem.200902350	journal	November 2009
Selective binding and removal of guests in a microporous metal–organic framework Yaghi, O. M.; Li, Guangming; Li, Hailian Nature, Vol. 378, Issue 6558, p. 703-706 https://doi.org/10.1038/378703a0	journal	December 1995
Open-Framework Solids with Diamond-Like Structures Prepared from Clusters and Metal-Organic Building Blocks Yaghi, Omar M.; Richardson, D. A.; Li, G. MRS Proceedings, Vol. 371 https://doi.org/10.1557/PROC-371-15	journal	January 1994
Construction of Microporous Materials from Molecular Building Blocks Yaghi, Omar M.; Pinnavaia, Thomas J.; Thorpe, M. F. Access in Nanoporous Materials, p. 111-121 https://doi.org/10.1007/0-306-47066-7_8	book	January 2002
Synthesis and Structure of a Metal-Organic Solid Having the Cadmium(II) Sulfate Net Yaghi, O. M.; Li, Hailian; O'Keeffe, M. MRS Proceedings, Vol. 453, Article No. 127 https://doi.org/10.1557/PROC-453-127	journal	January 1996

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