Materials Data on TbSF by Materials Project
TbSF is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. The structure is three-dimensional. Tb3+ is bonded in a 9-coordinate geometry to five equivalent S2- and four equivalent F1- atoms. There are four shorter (2.83 Å) and one longer (2.86 Å) Tb–S bond lengths. All Tb–F bond lengths are 2.47 Å. S2- is bonded in a 5-coordinate geometry to five equivalent Tb3+ atoms. F1- is bonded to four equivalent Tb3+ atoms to form a mixture of distorted corner and edge-sharing FTb4 tetrahedra.
- Research Organization:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Contributing Organization:
- MIT; UC Berkeley; Duke; U Louvain
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- OSTI ID:
- 1187469
- Report Number(s):
- mp-10930
- Resource Relation:
- Related Information: https://materialsproject.org/citing
- Country of Publication:
- United States
- Language:
- English
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