Pressure-Induced Enhanced Magnetic Anisotropy in Mn(N(CN)2)2
Using DC and AC magnetometry, the pressure dependence of the magnetization of the threedimensional antiferromagnetic coordination polymer Mn(N(CN)2)2 was studied up to 12 kbar and down to 8 K. The magnetic transition temperature, Tc, increases dramatically with applied pressure (P), where a change from Tc(P = ambient) = 16:0 K to Tc(P = 12:1 kbar) = 23:5 K was observed. In addition, a marked difference in the magnetic behavior is observed above and below 7.1 kbar. Specifically, for P < 7:1 kbar, the differences between the field-cooled and zero-field-cooled (fc-zfc) magnetizations, the coercive field, and the remanent magnetization decrease with increasing pressure. However, for P > 7:1 kbar, the behavior is inverted. Additionally, for P > 8:6 kbar, minor hysteresis loops are observed. All of these effects are evidence of the increase of the superexchange interaction and the appearance of an enhanced exchange anisotropy with applied pressure.
- Publication Date:
- OSTI Identifier:
- DOE Contract Number:
- Resource Type:
- Journal Article
- Resource Relation:
- Journal Name: Physical Review B; Journal Volume: 91; Journal Issue: 1
- Research Org:
- Oak Ridge National Laboratory (ORNL)
- Sponsoring Org:
- SC USDOE - Office of Science (SC)
- Country of Publication:
- United States
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