An Iodide-Based Li 7 P 2 S 8 I Superionic Conductor

Rangasamy, Ezhiylmurugan; Liu, Zengcai; Gobet, Mallory; Pilar, Kartik; Sahu, Gayatri; Zhou, Wei; Wu, Hui; Greenbaum, Steve; Liang, Chengdu

doi:10.1021/ja508723m

Title: An Iodide-Based Li ₇ P ₂ S ₈ I Superionic Conductor

Journal Article · Tue Jan 20 00:00:00 EST 2015 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/ja508723m· OSTI ID:1185568

Rangasamy, Ezhiylmurugan ^[1]; Liu, Zengcai ^[1]; Gobet, Mallory ^[2]; Pilar, Kartik ^[2]; Sahu, Gayatri ^[1]; Zhou, Wei ^[3]; Wu, Hui ^[3]; Greenbaum, Steve ^[2]; Liang, Chengdu ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Hunter College of the City Univ. of New York, NY (United States)
NIST Center for Neutron Research, Gaithersburg, MD (United States); Univ. of Maryland, College Park, MD (United States)

Stability from Instability: A Li₇P₂S₈I solid state Li-ion conductor derived from -Li₃PS₄ and LiI demonstrates exceptional electrochemical stability. The oxidation instability of I is subverted nullified via its incorporation into the coordinated structure. The inclusion of I also creates stability with metallic Li anode while simultaneously improving the interfacial kinetics. Low temperature membrane processability enables facile fabrication of dense membranes, making it suitable for industrial adoption.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: AC05-00OR22725; SC0005029

OSTI ID:: 1185568

Journal Information:: Journal of the American Chemical Society, Vol. 137, Issue 4; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

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Title: An Iodide-Based Li 7 P 2 S 8 I Superionic Conductor

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Title: An Iodide-Based Li ₇ P ₂ S ₈ I Superionic Conductor