A new family of fluidic precursors for the self-templated synthesis of hierarchical nanoporous carbons

Fulvio, Pasquale F.; Hillesheim, Patrick C.; Oyola, Yatsandra; Mahurin, Shannon Mark; Veith, Gabriel M.; Dai, Sheng

doi:10.1039/c3cc44175j

Title: A new family of fluidic precursors for the self-templated synthesis of hierarchical nanoporous carbons

Journal Article · Fri Jun 24 00:00:00 EDT 2016 · ChemComm

DOI:https://doi.org/10.1039/c3cc44175j· OSTI ID:1185352

Fulvio, Pasquale F. ^[1]; Hillesheim, Patrick C. ^[1]; Oyola, Yatsandra ^[1]; Mahurin, Shannon Mark ^[1]; Veith, Gabriel M. ^[2]; Dai, Sheng ^[3]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry

Hierarchical nanoporous nitrogen-doped carbons were prepared from task specific ionic liquids having a bis-imidazolium motif linked with various organic groups. While ethyl chains linking the imidazolium ions afford microporous-mesoporous carbons, long or aromatic groups resulted in microporous samples.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1185352

Journal Information:: ChemComm, Vol. 49, Issue 66; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 29 works

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References (34)

Carbon properties and their role in supercapacitors Pandolfo, A. G.; Hollenkamp, A. F. Journal of Power Sources, Vol. 157, Issue 1, p. 11-27 https://doi.org/10.1016/j.jpowsour.2006.02.065	journal	June 2006
Synthesis of New, Nanoporous Carbon with Hexagonally Ordered Mesostructure Jun, Shinae; Joo, Sang Hoon; Ryoo, Ryong Journal of the American Chemical Society, Vol. 122, Issue 43 https://doi.org/10.1021/ja002261e	journal	November 2000
Synthesis of Highly Ordered Carbon Molecular Sieves via Template-Mediated Structural Transformation Ryoo, Ryong; Joo, Sang Hoon; Jun, Shinae The Journal of Physical Chemistry B, Vol. 103, Issue 37 https://doi.org/10.1021/jp991673a	journal	September 1999
High-Rate Electrochemical Capacitors Based on Ordered Mesoporous Silicon Carbide-Derived Carbon Korenblit, Yair; Rose, Marcus; Kockrick, Emanuel ACS Nano, Vol. 4, Issue 3 https://doi.org/10.1021/nn901825y	journal	February 2010
Facile Synthesis of Ordered Mesoporous Carbons with High Thermal Stability by Self-Assembly of Resorcinol−Formaldehyde and Block Copolymers under Highly Acidic Conditions Wang, Xiqing; Liang, Chengdu; Dai, Sheng Langmuir, Vol. 24, Issue 14, p. 7500-7505 https://doi.org/10.1021/la800529v	journal	July 2008
Synthesis of Mesoporous Carbon Materials via Enhanced Hydrogen-Bonding Interaction Liang, Chengdu; Dai, Sheng Journal of the American Chemical Society, Vol. 128, Issue 16, p. 5316-5317 https://doi.org/10.1021/ja060242k	journal	April 2006
Synthesis of a Large-Scale Highly Ordered Porous Carbon Film by Self-Assembly of Block Copolymers Liang, Chengdu; Hong, Kunlun; Guiochon, Georges A. Angewandte Chemie International Edition, Vol. 43, Issue 43, p. 5785-5789 https://doi.org/10.1002/anie.200461051	journal	November 2004
Carbon materials for the electrochemical storage of energy in capacitors Frackowiak, Elzbieta; Béguin, François Carbon, Vol. 39, Issue 6, p. 937-950 https://doi.org/10.1016/S0008-6223(00)00183-4	journal	May 2001
Materials for electrochemical capacitors Simon, Patrice; Gogotsi, Yury Nature Materials, Vol. 7, Issue 11 https://doi.org/10.1038/nmat2297	journal	November 2008
Electrochemical characterizations of carbon nanomaterials by the cavity microelectrode technique Portet, C.; Chmiola, J.; Gogotsi, Y. Electrochimica Acta, Vol. 53, Issue 26, p. 7675-7680 https://doi.org/10.1016/j.electacta.2008.05.019	journal	November 2008
Electrochemical performance of carbon onions, nanodiamonds, carbon black and multiwalled nanotubes in electrical double layer capacitors Portet, C.; Yushin, G.; Gogotsi, Y. Carbon, Vol. 45, Issue 13, p. 2511-2518 https://doi.org/10.1016/j.carbon.2007.08.024	journal	November 2007
Charge storage mechanism in nanoporous carbons and its consequence for electrical double layer capacitors Simon, P.; Gogotsi, Y. Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 368, Issue 1923, p. 3457-3467 https://doi.org/10.1098/rsta.2010.0109	journal	June 2010
Anomalous Increase in Carbon Capacitance at Pore Sizes Less Than 1 Nanometer Chmiola, J. Science, Vol. 313, Issue 5794 https://doi.org/10.1126/science.1132195	journal	September 2006
Ionic liquids: solvent properties and organic reactivity Chiappe, Cinzia; Pieraccini, Daniela Journal of Physical Organic Chemistry, Vol. 18, Issue 4 https://doi.org/10.1002/poc.863	journal	January 2005
Ionic Liquids as Versatile Precursors for Functionalized Porous Carbon and Carbon-Oxide Composite Materials by Confined Carbonization Wang, Xiqing; Dai, Sheng Angewandte Chemie International Edition, Vol. 49, Issue 37 https://doi.org/10.1002/anie.201003163	journal	August 2010
A detailed view on the polycondensation of ionic liquid monomers towards nitrogen doped carbon materials Paraknowitsch, Jens Peter; Thomas, Arne; Antonietti, Markus Journal of Materials Chemistry, Vol. 20, Issue 32 https://doi.org/10.1039/c0jm00869a	journal	January 2010
Ionic Liquids as Precursors for Nitrogen-Doped Graphitic Carbon Paraknowitsch, Jens Peter; Zhang, Jian; Su, Dangsheng Advanced Materials, Vol. 22, Issue 1 https://doi.org/10.1002/adma.200900965	journal	January 2010
Fluidic Carbon Precursors for Formation of Functional Carbon under Ambient Pressure Based on Ionic Liquids Lee, Je Seung; Wang, Xiqing; Luo, Huimin Advanced Materials, Vol. 22, Issue 9 https://doi.org/10.1002/adma.200903403	journal	December 2009
Facile Ionothermal Synthesis of Microporous and Mesoporous Carbons from Task Specific Ionic Liquids Lee, Je Seung; Wang, Xiqing; Luo, Huimin Journal of the American Chemical Society, Vol. 131, Issue 13 https://doi.org/10.1021/ja900686d	journal	April 2009
Boron and nitrogen-rich carbons from ionic liquid precursors with tailorable surface properties Fulvio, Pasquale F.; Lee, Je Seung; Mayes, Richard T. Physical Chemistry Chemical Physics, Vol. 13, Issue 30 https://doi.org/10.1039/c1cp20631a	journal	January 2011
Room-Temperature Ionic Liquids. Solvents for Synthesis and Catalysis Welton, Thomas Chemical Reviews, Vol. 99, Issue 8, p. 2071-2084 https://doi.org/10.1021/cr980032t	journal	August 1999
Preparation of Inorganic Materials Using Ionic Liquids Ma, Zhen; Yu, Jihong; Dai, Sheng Advanced Materials, Vol. 22, Issue 2 https://doi.org/10.1002/adma.200900603	journal	January 2010
Functional Carbon Materials From Ionic Liquid Precursors Paraknowitsch, Jens Peter; Thomas, Arne Macromolecular Chemistry and Physics, Vol. 213, Issue 10-11 https://doi.org/10.1002/macp.201100573	journal	March 2012
Gas Adsorption Characterization of Ordered Organic−Inorganic Nanocomposite Materials Kruk, Michal; Jaroniec, Mietek Chemistry of Materials, Vol. 13, Issue 10 https://doi.org/10.1021/cm0101069	journal	October 2001
Nitrogen-Enriched Nonporous Carbon Electrodes with Extraordinary Supercapacitance Hulicova-Jurcakova, Denisa; Kodama, Masaya; Shiraishi, Soshi Advanced Functional Materials, Vol. 19, Issue 11 https://doi.org/10.1002/adfm.200801100	journal	June 2009
Effect of nitrogen in carbon electrode on the supercapacitor performance Lota, G.; Grzyb, B.; Machnikowska, H. Chemical Physics Letters, Vol. 404, Issue 1-3 https://doi.org/10.1016/j.cplett.2005.01.074	journal	March 2005
Low-Temperature Fluorination of Soft-Templated Mesoporous Carbons for a High-Power Lithium/Carbon Fluoride Battery Fulvio, Pasquale F.; Brown, Suree S.; Adcock, Jamie Chemistry of Materials, Vol. 23, Issue 20 https://doi.org/10.1021/cm2012395	journal	October 2011
Fluorination of carbon blacks: An X-ray photoelectron spectroscopy study: I. A literature review of XPS studies of fluorinated carbons. XPS investigation of some reference compounds Nansé, G.; Papirer, E.; Fioux, P. Carbon, Vol. 35, Issue 2 https://doi.org/10.1016/S0008-6223(96)00095-4	journal	January 1997
Mechanochemical Synthesis of Carbon Fluorides Read, Jeffrey A.; Behl, Wishvender K. Electrochemical and Solid-State Letters, Vol. 12, Issue 1 https://doi.org/10.1149/1.3008701	journal	January 2009
On the so-called “semi-ionic” C–F bond character in fluorine–GIC Sato, Yuta; Itoh, Keiji; Hagiwara, Rika Carbon, Vol. 42, Issue 15 https://doi.org/10.1016/j.carbon.2004.08.012	journal	January 2004
“Brick-and-Mortar” Self-Assembly Approach to Graphitic Mesoporous Carbon Nanocomposites Fulvio, Pasquale F.; Mayes, Richard T.; Wang, Xiqing Advanced Functional Materials, Vol. 21, Issue 12, p. 2208-2215 https://doi.org/10.1002/adfm.201002641	journal	April 2011
Synthesis of a Large-Scale Highly Ordered Porous Carbon Film by Self-Assembly of Block Copolymers Liang, Chengdu; Hong, Kunlun; Guiochon, Georges A. Angewandte Chemie, Vol. 116, Issue 43 https://doi.org/10.1002/ange.200461051	journal	November 2004
Ionic Liquids as Versatile Precursors for Functionalized Porous Carbon and Carbon-Oxide Composite Materials by Confined Carbonization Wang, Xiqing; Dai, Sheng Angewandte Chemie, Vol. 122, Issue 37 https://doi.org/10.1002/ange.201003163	journal	August 2010
Ionic Liquids: Solvent Properties and Organic Reactivity Chiappe, Cinzia; Pieraccini, Daniela ChemInform, Vol. 36, Issue 33 https://doi.org/10.1002/chin.200533313	journal	August 2005

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Synthesis of Functional Nanomaterials in Ionic Liquids Kang, Xinchen; Sun, Xiaofu; Han, Buxing Advanced Materials, Vol. 28, Issue 6 https://doi.org/10.1002/adma.201502924	journal	November 2015
Silica‐assisted urea‐formaldehyde‐based carbon microspheres with enhanced supercapacitor performances as electrode Yue, Jiaji; Yuan, Mengying; Zhao, Hui Journal of Applied Polymer Science, Vol. 137, Issue 8 https://doi.org/10.1002/app.48388	journal	August 2019
Synthesis of Highly Active and Stable Spinel-Type Oxygen Evolution Electrocatalysts by a Rapid Inorganic Self-Templating Method Ma, Tian Yi; Dai, Sheng; Jaroniec, Mietek Chemistry - A European Journal, Vol. 20, Issue 39 https://doi.org/10.1002/chem.201403946	journal	August 2014
Heteroatom-Containing Porous Carbons Derived from Ionic Liquid-Doped Alkali Organic Salts for Supercapacitors Zhu, Jingyue; Xu, Dan; Qian, Wenjing Small, Vol. 12, Issue 14 https://doi.org/10.1002/smll.201600010	journal	February 2016
Ionic liquids and their solid-state analogues as materials for energy generation and storage MacFarlane, Douglas R.; Forsyth, Maria; Howlett, Patrick C. Nature Reviews Materials, Vol. 1, Issue 2 https://doi.org/10.1038/natrevmats.2015.5	journal	January 2016
N-doped ordered mesoporous carbons with improved charge storage capacity by tailoring N-dopant density with solvent-assisted synthesis Almeida, Vitor C.; Silva, Rafael; Acerce, Muharrem J. Mater. Chem. A, Vol. 2, Issue 36 https://doi.org/10.1039/c4ta02236j	journal	January 2014
Slat templated formation of efficient oxygen reduction electrocatalyst with a fluidic precursor Tan, Yao Materials Research Express, Vol. 5, Issue 5 https://doi.org/10.1088/2053-1591/aac464	journal	May 2018

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