Nickel Phosphine Catalysts with Pendant Amines for Electrocatalytic Oxidation of Alcohols
Abstract
Nickel phosphine complexes with pendant amines have been found to be electrocatalysts for the oxidation of primary and secondary alcohols, with turnover frequencies as high as 3.3 s-1. These complexes are the first electrocatalysts for alcohol oxidation based on non-precious metals, which will be critical for use in fuel cells. The research by CJW, ESW, and AMA was supported by the US Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. The research by JASR was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.
- Authors:
- Publication Date:
- Research Org.:
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Molecular Electrocatalysis (CME)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1182935
- Report Number(s):
- PNNL-SA-107999
KC0302010; KC0307010
- DOE Contract Number:
- AC05-76RL01830
- Resource Type:
- Journal Article
- Journal Name:
- Chemical Communications, 51(28):6172-6174
- Additional Journal Information:
- Journal Name: Chemical Communications, 51(28):6172-6174
- Country of Publication:
- United States
- Language:
- English
- Subject:
- Electrocatalysis; Alcohol Oxidation; Molecular Catalysis
Citation Formats
Weiss, Charles J., Wiedner, Eric S., Roberts, John A., and Appel, Aaron M. Nickel Phosphine Catalysts with Pendant Amines for Electrocatalytic Oxidation of Alcohols. United States: N. p., 2015.
Web. doi:10.1039/C5CC01107H.
Weiss, Charles J., Wiedner, Eric S., Roberts, John A., & Appel, Aaron M. Nickel Phosphine Catalysts with Pendant Amines for Electrocatalytic Oxidation of Alcohols. United States. https://doi.org/10.1039/C5CC01107H
Weiss, Charles J., Wiedner, Eric S., Roberts, John A., and Appel, Aaron M. 2015.
"Nickel Phosphine Catalysts with Pendant Amines for Electrocatalytic Oxidation of Alcohols". United States. https://doi.org/10.1039/C5CC01107H.
@article{osti_1182935,
title = {Nickel Phosphine Catalysts with Pendant Amines for Electrocatalytic Oxidation of Alcohols},
author = {Weiss, Charles J. and Wiedner, Eric S. and Roberts, John A. and Appel, Aaron M.},
abstractNote = {Nickel phosphine complexes with pendant amines have been found to be electrocatalysts for the oxidation of primary and secondary alcohols, with turnover frequencies as high as 3.3 s-1. These complexes are the first electrocatalysts for alcohol oxidation based on non-precious metals, which will be critical for use in fuel cells. The research by CJW, ESW, and AMA was supported by the US Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. The research by JASR was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.},
doi = {10.1039/C5CC01107H},
url = {https://www.osti.gov/biblio/1182935},
journal = {Chemical Communications, 51(28):6172-6174},
number = ,
volume = ,
place = {United States},
year = {Sat Apr 11 00:00:00 EDT 2015},
month = {Sat Apr 11 00:00:00 EDT 2015}
}
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