High pressure induced charge transfer in 3d–4f bimetallic photomagnetic materials

Wu, La-Chin; Nielsen, Morten Bormann; Bremholm, Martin; Madsen, Solveig Rogild; Overgaard, Jacob; Newville, Matt; Chen, Yu -Sheng; Iversen, Bo Brummerstedt

doi:10.1039/c5cc00603a

Title: High pressure induced charge transfer in 3d–4f bimetallic photomagnetic materials

Journal Article · Wed Apr 22 00:00:00 EDT 2015 · ChemComm

DOI:https://doi.org/10.1039/c5cc00603a· OSTI ID:1182770

Wu, La-Chin ^[1]; Nielsen, Morten Bormann ^[1]; Bremholm, Martin ^[1]; Madsen, Solveig Rogild ^[1]; Overgaard, Jacob ^[1]; Newville, Matt ^[2]; Chen, Yu -Sheng ^[2]; Iversen, Bo Brummerstedt ^[1]

Univ. of Aarhus (Denmark)
Univ. of Chicago, IL (United States)

In this work, pressure-induced crystal color change of photo-magnetic materials [Ln(DMF)₄(H₂O)₃(μ-CN)M(CN)₅]·H₂O, Ln = Y, M = Fe (1), Ln = Y, M = Co (2), Ln = Nd, M = Fe (3) (DMF = N,N-dimethyl formamide) are investigated using variable pressure X-ray Absorption Near-Edge Structure (XANES) spectroscopy and X-ray diffraction. For 1 the effect is caused by ligand-to-metal charge transfer (LMCT) on the iron site.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: Danish National Research Foundation (DNRF); National Science Foundation (NSF); USDOE

Grant/Contract Number:: FG02-94ER14466; AC02-06CH11357

OSTI ID:: 1182770

Journal Information:: ChemComm, Vol. 51, Issue 42; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: ENGLISH

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Cited by: 10 works

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