Mask-Assisted Seeded Growth of Segmented Metallic Heteronanostructures

Crane, Cameron C.; Tao, Jing; Wang, Feng; Zhu, Yimei; Chen, Jingyi

doi:10.1021/jp5094433

Title: Mask-Assisted Seeded Growth of Segmented Metallic Heteronanostructures

Journal Article · Thu Dec 04 00:00:00 EST 2014 · Journal of Physical Chemistry. C

DOI:https://doi.org/10.1021/jp5094433· OSTI ID:1182540

Crane, Cameron C. ^[1]; Tao, Jing ^[2]; Wang, Feng ^[1]; Zhu, Yimei ^[2]; Chen, Jingyi ^[1]

Univ. of Arkansas, Fayetteville, AR (United States). Dept. of Chemistry and Biochemistry
Brookhaven National Lab. (BNL), Upton, NY (United States). Condensed Matter Physics and Materials Science Division

Controlling the deposition of exotic metals in the seeded growth of multi-metal nanostructures is challenging. This work describes a seeded growth method assisted by a mask for synthesis of segmented binary or ternary metal nanostructures. Silica is used as a mask to partially block the surface of a seed and a second metal is subsequently deposited on the exposed area, forming a bimetallic heterodimer. The initial demonstration was carried out on a Au seed, followed by deposition of Pd or Pt on the seed. It was found that Pd tends to spread out laterally on the seed while Pt inclines to grow vertically into branched topology on Au. Without removal of the SiO₂ mask, Pt could be further deposited on the unblocked Pd of the Pd-Au dimer to form a Pt-Pd-Au trimer. The mask-assisted seeded growth provides a general strategy to construct segmented metallic nanoarchitectures.

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Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Advanced Research Projects Agency - Energy (ARPA-E)

Grant/Contract Number:: SC00112704

OSTI ID:: 1182540

Report Number(s):: BNL-107641-2015-JA; R&D Project: M015MACA; KC0201010

Journal Information:: Journal of Physical Chemistry. C, Vol. 118, Issue 48; ISSN 1932-7447

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 23 works

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