Tailoring the composition of ultrathin, ternary alloy PtRuFe nanowires for the methanol oxidation reaction and formic acid oxidation reaction

Scofield, Megan E.; Koenigsmann, Christopher; Wang, Lei; Liu, Haiqing; Wong, Stanislaus S.

doi:10.1039/c4ee02162b

Title: Tailoring the composition of ultrathin, ternary alloy PtRuFe nanowires for the methanol oxidation reaction and formic acid oxidation reaction

Journal Article · Tue Nov 25 00:00:00 EST 2014 · Energy & Environmental Science

DOI:https://doi.org/10.1039/c4ee02162b· OSTI ID:1182473

Scofield, Megan E. ^[1]; Koenigsmann, Christopher ^[1]; Wang, Lei ^[1]; Liu, Haiqing ^[1]; Wong, Stanislaus S. ^[2]

State Univ. of New York at Stony Brook, Stony Brook, NY (United States)
State Univ. of New York at Stony Brook, Stony Brook, NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)

In the search for alternatives to conventional Pt electrocatalysts, we have synthesized ultrathin, ternary PtRuFe nanowires (NW), possessing different chemical compositions in order to probe their CO tolerance as well as electrochemical activity as a function of composition for both (i) the methanol oxidation reaction (MOR) and (ii) the formic acid oxidation reaction (FAOR). As-prepared ‘multifunctional’ ternary NW catalysts exhibited both higher MOR and FAOR activity as compared with binary Pt₇Ru₃ NW, monometallic Pt NW, and commercial catalyst control samples. In terms of synthetic novelty, we utilized a sustainably mild, ambient wet-synthesis method never previously applied to the fabrication of crystalline, pure ternary systems in order to fabricate ultrathin, homogeneous alloy PtRuFe NWs with a range of controlled compositions. Thus, these NWs were subsequently characterized using a suite of techniques including XRD, TEM, SAED, and EDAX in order to verify not only the incorporation of Ru and Fe into the Pt lattice but also their chemical homogeneity, morphology, as well as physical structure and integrity. Lastly, these NWs were electrochemically tested in order to deduce the appropriateness of conventional explanations such as (i) the bi-functional mechanism as well as (ii) the ligand effect to account for our MOR and FAOR reaction data. Specifically, methanol oxidation appears to be predominantly influenced by the Ru content, whereas formic acid oxidation is primarily impacted by the corresponding Fe content within the ternary metal alloy catalyst itself.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC00112704

OSTI ID:: 1182473

Report Number(s):: BNL-107165-2014-JA; EESNBY; R&D Project: PM037; KC0201030

Journal Information:: Energy & Environmental Science, Vol. 8, Issue 1; ISSN 1754-5692

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 241 works

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Modulating Catalytic Activity and Durability of PtFe Alloy Catalysts for Oxygen Reduction Reaction Through Controlled Carbon Shell Formation Kim, Youngjin; Jeffery, A. Anto; Min, Jiho Nanomaterials, Vol. 9, Issue 10 https://doi.org/10.3390/nano9101491	journal	October 2019
Ultrathin PtNiM (M = Rh, Os, and Ir) Nanowires as Efficient Fuel Oxidation Electrocatalytic Materials Zhang, Weiyu; Yang, Yong; Huang, Bolong Advanced Materials, Vol. 31, Issue 15 https://doi.org/10.1002/adma.201805833	journal	February 2019
Aqueous Synthesis of Ultrathin Platinum/Non-Noble Metal Alloy Nanowires for Enhanced Hydrogen Evolution Activity Liu, Zhaojun; Qi, Jing; Liu, Moxuan Angewandte Chemie, Vol. 130, Issue 36 https://doi.org/10.1002/ange.201806194	journal	July 2018
Ternary CoPtAu Nanoparticles as a General Catalyst for Highly Efficient Electro‐oxidation of Liquid Fuels Li, Junrui; Jilani, Safia Z.; Lin, Honghong Angewandte Chemie, Vol. 131, Issue 33 https://doi.org/10.1002/ange.201906137	journal	July 2019
A concise guide to sustainable PEMFCs: recent advances in improving both oxygen reduction catalysts and proton exchange membranes Scofield, Megan E.; Liu, Haiqing; Wong, Stanislaus S. Chemical Society Reviews, Vol. 44, Issue 16 https://doi.org/10.1039/c5cs00302d	journal	January 2015
Concave and duck web-like platinum nanopentagons with enhanced electrocatalytic properties for formic acid oxidation Lai, Jianping; Niu, Wenxin; Li, Suping Journal of Materials Chemistry A, Vol. 4, Issue 3 https://doi.org/10.1039/c5ta08882h	journal	January 2016
Composition-controllable synthesis of defect-rich PtPdCu nanoalloys with hollow cavities as superior electrocatalysts for alcohol oxidation Lan, Jian; Wang, Kai; Yuan, Qiang Materials Chemistry Frontiers, Vol. 1, Issue 6 https://doi.org/10.1039/c6qm00277c	journal	January 2017
Pt nanoparticles anchored over Te nanorods as a novel and promising catalyst for methanol oxidation reaction Yang, Xudong; Xue, Jia; Feng, Ligang Chemical Communications, Vol. 55, Issue 75 https://doi.org/10.1039/c9cc06004a	journal	January 2019
Pt and RhPt dendritic nanowires and their potential application as anodic catalysts for fuel cells Kehoe, Daniel K.; McCarthy, Sarah A.; Romeral, Luis RSC Advances, Vol. 9, Issue 53 https://doi.org/10.1039/c9ra04801d	journal	January 2019
Biaxially strained PtPb/Pt core/shell nanoplate boosts oxygen reduction catalysis Bu, Lingzheng; Zhang, Nan; Guo, Shaojun Science, Vol. 354, Issue 6318 https://doi.org/10.1126/science.aah6133	journal	December 2016
Synergistic Supports Beyond Carbon Black for Polymer Electrolyte Fuel Cell Anodes Huang, Yiyin; Babu, Dickson D.; Wu, Maoxiang ChemCatChem, Vol. 10, Issue 20 https://doi.org/10.1002/cctc.201801094	journal	September 2018
Ultrathin Metallic Nanowire-Based Architectures as High-Performing Electrocatalysts Li, Luyao; Wong, Stanislaus S. ACS Omega, Vol. 3, Issue 3 https://doi.org/10.1021/acsomega.8b00169	journal	March 2018

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