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Title: Long-Range Chemical Sensitivity in the Sulfur K-Edge X-ray Absorption Spectra of Substituted Thiophenes

Journal Article · · Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory
DOI:https://doi.org/10.1021/jp505766f· OSTI ID:1179612
 [1];  [1];  [2];  [2];  [2];  [2];  [3];  [1]
  1. Molecular and Environmental Sciences Group, Department of Geological Sciences, University of Saskatchewan, Saskatoon, Saskatchewan S7N 5E2, Canada
  2. ExxonMobil Research and Engineering Company, Annandale, New Jersey 08801, United States
  3. School of Chemistry and Physics, The University of Adelaide, Adelaide, South Australia 5005, Australia

Sponsoring Organization:
USDOE Office of Science (SC), Biological and Environmental Research (BER); USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
AC02-76SF00515; AC02-98CH10886
OSTI ID:
1179612
Journal Information:
Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory, Journal Name: Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory Vol. 118 Journal Issue: 36; ISSN 1089-5639
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 29 works
Citation information provided by
Web of Science

References (49)

In situ observation of the generation of isothiocyanates from sinigrin in horseradish and wasabi journal August 2001
Electronic Structure Description of the cis -MoOS Unit in Models for Molybdenum Hydroxylases journal January 2008
A new method for the synthesis of dinaphtho[1,2-b;2′,1′-d]thiophenes and selenophenes journal January 2007
Speciation of sulfur in humic and fulvic acids using X-ray absorption near-edge structure (XANES) spectroscopy journal February 1997
Resonance Effect in Hammett Relationship. II. Sigma Constants in Electrophilic Reactions and their Intercorrelation journal September 1959
Physical Organic Chemistry journal October 1958
Linear free energy ortho-correlations in the thiophen series. Part IV. Kinetics of alkaline hydrolysis of some methyl 3-substituted thiophen-2-carboxylates in aqueous methanol journal January 1976
The last decade of global anthropogenic sulfur dioxide: 2000–2011 emissions journal January 2013
Localizing the Chemical Forms of Sulfur in Vivo Using X-ray Fluorescence Spectroscopic Imaging: Application to Onion ( Allium cepa ) Tissues journal July 2009
Sulfur K-Edge Absorption Spectra of Na 2 SO 4 , Na 2 SO 3 , Na 2 S 2 O 3 , and Na 2 S 2 O x ( x =5–8) journal February 1986
SO2 inhalation modulates the expression of pro-inflammatory and pro-apoptotic genes in rat heart and lung journal January 2011
Direct determination and quantification of sulfur forms in coals from the Argonne Premium Sample Program journal January 1991
From molecules to solids with the DMol3 approach journal November 2000
An all‐electron numerical method for solving the local density functional for polyatomic molecules journal January 1990
Molecular Characterization of Sulfur Compounds in Venezuela Crude Oil and Its SARA Fractions by Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry journal September 2010
Functional Groups and Sulfur K-Edge XANES Spectra: Divalent Sulfur and Disulfides journal August 2010
Anisotropic x-ray absorption in layered compounds journal December 1977
Sulfur and iron analyses of marine archaeological wood in shipwrecks from the Baltic Sea and Scandinavian waters journal July 2012
The Sulfur Chemistry of Shiitake Mushroom journal January 2004
Thermophysical, crystalline and infrared studies of the 2- and 3-thiophenecarboxylic acids journal September 2003
Sulfur 1 s near edge x-ray absorption fine structure spectroscopy of thiophenic and aromatic thioether compounds journal June 2013
XAS spectroscopy, sulfur, and the brew within blood cells from Ascidia ceratodes journal February 2014
Sulfur Speciation in Petroleum:  Atmospheric Pressure Photoionization or Chemical Derivatization and Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry journal September 2007
Speciation of organic sulfur compounds using comprehensive two-dimensional gas chromatography coupled to time-of-flight mass spectrometry: A powerful tool for petroleum refining journal June 2014
X-Ray Absorption Spectroscopy as a Probe of Microbial Sulfur Biochemistry: the Nature of Bacterial Sulfur Globules Revisited journal August 2008
Chemical Form and Distribution of Selenium and Sulfur in the Selenium Hyperaccumulator Astragalus bisulcatus journal February 2003
The Interpretation of Sulfur K-Edge XANES Spectra: A Case Study on Thiophenic and Aliphatic Sulfur Compounds journal March 2009
Polarized X-ray Absorption Spectroscopy of Cupric Chloride Dihydrate journal June 1995
Anthropogenic sulfur dioxide emissions: 1850–2005 journal January 2011
Sulfur K-edge X-ray absorption spectroscopy for determining the chemical speciation of sulfur in biological systems journal December 1998
Characterization of Sulfur-Containing Functional Groups in Sedimentary Humic Substances by X-ray Absorption Near-Edge Structure Spectroscopy journal May 1997
Analysis of Sulfur Biochemistry of Sulfur Bacteria Using X-ray Absorption Spectroscopy journal July 2001
Radical Cation of Dibenzothiophene Fully Annelated with Bicyclo[2.2.2]octene Units:  X-ray Crystal Structure and Electronic Properties journal November 2004
Inner shell excitation of thiophene and thiolane: Gas, solid, and monolayer states journal November 1986
Sulfur X-ray Absorption Spectroscopy of Living Mammalian Cells:  An Enabling Tool for Sulfur Metabolomics. In Situ Observation of Uptake of Taurine into MDCK Cells journal December 2007
Measurement of soft X-ray absorption spectra with a fluorescent ion chamber detector
  • Lytle, F. W.; Greegor, R. B.; Sandstrom, D. R.
  • Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 226, Issue 2-3 https://doi.org/10.1016/0168-9002(84)90077-9
journal October 1984
X-ray Absorption Fine Structure (XAFS) Spectroscopic Characterization of Emissions from Combustion of Fossil Fuels journal January 2002
Vibrational, X-ray absorption, and Mössbauer spectra of sulfate minerals from the weathered massive sulfide deposit at Iron Mountain, California journal May 2011
The crystal and molecular structure of β-thiophenic acid journal December 1964
Sulfur K-edge x-ray absorption spectroscopy of petroleum asphaltenes and model compounds journal April 1989
X-ray Absorption Spectroscopy at the Sulfur K-Edge: A New Tool to Investigate the Biochemical Mechanisms of Neurodegeneration journal January 2012
Characterization of solid bitumens originating from thermal chemical alteration and thermochemical sulfate reduction journal September 2010
Sulfur speciation in kerogen and bitumen from gas and oil shales journal March 2014
Acid Rain: A Serious Regional Environmental Problem journal June 1974
Sulfur speciation in heavy petroleums: Information from X-ray absorption near-edge structure journal March 1991
Microbial Desulfurization of a Crude Oil Middle-Distillate Fraction: Analysis of the Extent of Sulfur Removal and the Effect of Removal on Remaining Sulfur journal January 1999
X-ray Absorption Spectroscopic Investigation of Sulfur Sites in Coal: Organic Sulfur Identification journal October 1984
Structure of dibenzothiophen journal January 1970
Speciation of Iron and Sulfate in Acid Waters:  Aqueous Clusters to Mineral Precipitates journal January 2005

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