Frenkel-like Wannier-Mott excitons in few-layer
- Univ. of Michigan, Ann Arbor, MI (United States)
- Inst. of Chemical Technology Prague (Czech Republic)
Optical measurements and first-principles calculations of the band structure and exciton states in direct-gap bulk and few-layer PbI2 indicate that the n = 1 exciton is Frenkel-like in nature in that its energy exhibits a weak dependence on thickness down to atomic-length scales. Results reveal large increases in the gap and exciton binding energy with a decreasing number of layers and a transition of the fundamental gap, which becomes indirect for one and two monolayers. Calculated values are in reasonable agreement with a particle-in-a-box model relying on the Wannier-Mott theory of exciton formation. In conclusion, general arguments and existing data suggest that the Frenkel-like character of the lowest exciton is a universal feature of wide-gap layered semiconductors whose effective masses and dielectric constants give bulk Bohr radii that are on the order of the layer spacing.
- Research Organization:
- Energy Frontier Research Centers (EFRC) (United States). Center for Solar and Thermal Energy Conversion (CSTEC)
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)
- Grant/Contract Number:
- SC0000957; AC02-05CH11231; DMR-1254314
- OSTI ID:
- 1370080
- Alternate ID(s):
- OSTI ID: 1178611
- Journal Information:
- Physical Review. B, Condensed Matter and Materials Physics, Vol. 91, Issue 16; Related Information: CSTEC partners with University of Michigan (lead); Kent State University; ISSN 1098-0121
- Publisher:
- American Physical Society (APS)Copyright Statement
- Country of Publication:
- United States
- Language:
- English
Web of Science
Similar Records
Spin-orbit coupling, strong correlation, and insulator-metal transitions: The ferromagnetic Dirac-Mott insulator
Excitonic emissions and above-band-gap luminescence in the single-crystal perovskite semiconductors and