Experimental evidence of negative linear compressibility in the MIL-53 metal–organic framework family
- Delft Univ. of Technology (Netherlands)
- Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source
- Centre National de la Recherche Scientifique (CNRS), Paris (France). Inst. de Recherche de Chimie
Here we report a series of powder X-ray diffraction experiments performed on the soft porous crystals MIL-53(Al) and NH2-MIL-53(Al) in a diamond anvil cell under different pressurization media. Systematic refinements of the obtained powder patterns demonstrate that these materials expand along a specific direction while undergoing total volume reduction under an increasing hydrostatic pressure. The results confirm for the first time the negative linear compressibility behaviour of this family of materials, recently predicted from quantum chemical calculations.
- Research Organization:
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Grant/Contract Number:
- SC00112704; AC02-98CH10886
- OSTI ID:
- 1174107
- Report Number(s):
- BNL-107485-2015-JA; CRECF4; R&D Project: LS001
- Journal Information:
- CrystEngComm, Vol. 17, Issue 2; ISSN 1466-8033
- Publisher:
- Royal Society of ChemistryCopyright Statement
- Country of Publication:
- United States
- Language:
- English
Cited by: 100 works
Citation information provided by
Web of Science
Web of Science
Similar Records
Experimental Evidence of Negative Linear Compressibility in the MIL-53 Metal-organic Framework Family
Experimental Evidence of Negative Linear Compressibility in the MIL-53 Metal-Organic Framework Family
Porosity Dependence of Compression and Lattice Rigidity in Metal–Organic Framework Series
Journal Article
·
Mon Mar 24 00:00:00 EDT 2014
· CrystEngComm
·
OSTI ID:1174107
+4 more
Experimental Evidence of Negative Linear Compressibility in the MIL-53 Metal-Organic Framework Family
Journal Article
·
Mon Mar 24 00:00:00 EDT 2014
· CrystEngComm
·
OSTI ID:1174107
+4 more
Porosity Dependence of Compression and Lattice Rigidity in Metal–Organic Framework Series
Journal Article
·
Mon Feb 18 00:00:00 EST 2019
· Journal of the American Chemical Society
·
OSTI ID:1174107
+5 more