Enlarged Pore Size in Mesoporous Silica Films Templated by Pluronic F127: Use of Poloxamer Mixtures and Increased Template/SiO[subscript 2] Ratios in Materials Synthesized by Evaporation-Induced Self-Assembly

Dunphy, Darren R.; Sheth, Pratik H.; Garcia, Fred L.; Brinker, C. Jeffrey

doi:10.1021/cm5031624

Title: Enlarged Pore Size in Mesoporous Silica Films Templated by Pluronic F127: Use of Poloxamer Mixtures and Increased Template/SiO[subscript 2] Ratios in Materials Synthesized by Evaporation-Induced Self-Assembly

Journal Article · Mon Jun 08 00:00:00 EDT 2015 · Chem. Mater.

DOI:https://doi.org/10.1021/cm5031624· OSTI ID:1173014

Dunphy, Darren R.; Sheth, Pratik H.; Garcia, Fred L.; Brinker, C. Jeffrey ^[1]

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: DOE - BASIC ENERGY SCIENCES

OSTI ID:: 1173014

Journal Information:: Chem. Mater., Vol. 27, Issue (1) ; 01, 2015

Country of Publication:: United States

Language:: ENGLISH

Citation Metrics:

Cited by: 41 works

Citation information provided by
Web of Science

References (53)

Surfactant Control of Phases in the Synthesis of Mesoporous Silica-Based Materials Huo, Qisheng; Margolese, David I.; Stucky, Galen D. Chemistry of Materials, Vol. 8, Issue 5 https://doi.org/10.1021/cm960137h	journal	January 1996
Ultrastable, Redispersible, Small, and Highly Organomodified Mesoporous Silica Nanotherapeutics Lin, Yu-Shen; Abadeer, Nardine; Hurley, Katie R. Journal of the American Chemical Society, Vol. 133, Issue 50 https://doi.org/10.1021/ja208567v	journal	December 2011
Aerosol-assisted self-assembly of mesostructured spherical nanoparticles Lu, Yunfeng; Fan, Hongyou; Stump, Aaron Nature, Vol. 398, Issue 6724, p. 223-226 https://doi.org/10.1038/18410	journal	March 1999
Continuous formation of supported cubic and hexagonal mesoporous films by sol–gel dip-coating Lu, Yunfeng; Ganguli, Rahul; Drewien, Celeste A. Nature, Vol. 389, Issue 6649 https://doi.org/10.1038/38699	journal	September 1997
Ordered mesoporous materials in catalysis Taguchi, Akira; Schüth, Ferdi Microporous and Mesoporous Materials, Vol. 77, Issue 1 https://doi.org/10.1016/j.micromeso.2004.06.030	journal	January 2005
Functionalized Monolayers on Ordered Mesoporous Supports Feng, X.; Fryxell, G. E.; Wang, L. -Q. Science, Vol. 276, Issue 5314 https://doi.org/10.1126/science.276.5314.923	journal	May 1997
The targeted delivery of multicomponent cargos to cancer cells by nanoporous particle-supported lipid bilayers Ashley, Carlee E.; Carnes, Eric C.; Phillips, Genevieve K. Nature Materials, Vol. 10, Issue 5, p. 389-397 https://doi.org/10.1038/nmat2992	journal	April 2011
Re-examining the Size/Charge Paradigm: Differing in Vivo Characteristics of Size- and Charge-Matched Mesoporous Silica Nanoparticles Townson, Jason L.; Lin, Yu-Shen; Agola, Jacob O. Journal of the American Chemical Society, Vol. 135, Issue 43 https://doi.org/10.1021/ja4082414	journal	October 2013
DNA translocation through an array of kinked nanopores Chen, Zhu; Jiang, Yingbing; Dunphy, Darren R. Nature Materials, Vol. 9, Issue 8, p. 667-675 https://doi.org/10.1038/nmat2805	journal	August 2010
Tailoring of the Nanotexture of Mesoporous Silica Films and Their Functionalized Derivatives for Selectively Harvesting Low Molecular Weight Protein Hu, Ye; Bouamrani, Ali; Tasciotti, Ennio ACS Nano, Vol. 4, Issue 1 https://doi.org/10.1021/nn901322d	journal	December 2009
Synthesis of Ordered and Disordered Silicas with Uniform Pores on the Border between Micropore and Mesopore Regions Using Short Double-Chain Surfactants Ryoo, Ryong; Park, In-Soo; Jun, Shinae Journal of the American Chemical Society, Vol. 123, Issue 8 https://doi.org/10.1021/ja0038326	journal	February 2001
Synthesis and Pore Size Control of Cubic Mesoporous Silica SBA-1 Kim, Mi Jeong; Ryoo, Ryong Chemistry of Materials, Vol. 11, Issue 2 https://doi.org/10.1021/cm980691m	journal	February 1999
Triblock Copolymer Syntheses of Mesoporous Silica with Periodic 50 to 300 Angstrom Pores Zhao, Dongyuan; Feng, Jianglin; Huo, Qisheng Science, Vol. 279, Issue 5350, p. 548-552 https://doi.org/10.1126/science.279.5350.548	journal	January 1998
Nonionic Triblock and Star Diblock Copolymer and Oligomeric Surfactant Syntheses of Highly Ordered, Hydrothermally Stable, Mesoporous Silica Structures Zhao, Dongyuan; Huo, Qisheng; Feng, Jianglin Journal of the American Chemical Society, Vol. 120, Issue 24 https://doi.org/10.1021/ja974025i	journal	June 1998
Characterization of the Porous Structure of SBA-15 Kruk, Michal; Jaroniec, Mietek; Ko, Chang Hyun Chemistry of Materials, Vol. 12, Issue 7 https://doi.org/10.1021/cm000164e	journal	July 2000
Delivery of Small Interfering RNA by Peptide-Targeted Mesoporous Silica Nanoparticle-Supported Lipid Bilayers Ashley, Carlee E.; Carnes, Eric C.; Epler, Katharine E. ACS Nano, Vol. 6, Issue 3 https://doi.org/10.1021/nn204102q	journal	February 2012
Delivery of Ricin Toxin A-Chain by Peptide-Targeted Mesoporous Silica Nanoparticle-Supported Lipid Bilayers Epler, Katharine; Padilla, David; Phillips, Genevieve Advanced Healthcare Materials, Vol. 1, Issue 3, p. 348-353 https://doi.org/10.1002/adhm.201200022	journal	April 2012
Mesoporous Silica Nanoparticle Nanocarriers: Biofunctionality and Biocompatibility Tarn, Derrick; Ashley, Carlee E.; Xue, Min Accounts of Chemical Research, Vol. 46, Issue 3 https://doi.org/10.1021/ar3000986	journal	July 2012
Monodispersed Mesoporous Silica Nanoparticles with Very Large Pores for Enhanced Adsorption and Release of DNA Gao, Fei; Botella, Pablo; Corma, Avelino The Journal of Physical Chemistry B, Vol. 113, Issue 6 https://doi.org/10.1021/jp807956r	journal	February 2009
Preparation and physico-chemical characterization of large-mesopore silica thin films templated by block copolymers for membrane technology Nisticò, Roberto; Scalarone, Dominique; Magnacca, Giuliana Microporous and Mesoporous Materials, Vol. 190 https://doi.org/10.1016/j.micromeso.2014.02.012	journal	May 2014
Microstructural Characterization of Polystyrene- block -poly(ethylene oxide)-Templated Silica Films with Cubic-Ordered Spherical Mesopores Smarsly, Bernd; Xomeritakis, George; Yu, Kui Langmuir, Vol. 19, Issue 18 https://doi.org/10.1021/la034798m	journal	September 2003
Novel block copolymer templates for tuning mesopore connectivity in cage-type mesoporous silica films Torad, Nagy L.; Lian, Hong-Yuan; Wu, Kevin C. -W. Journal of Materials Chemistry, Vol. 22, Issue 37 https://doi.org/10.1039/c2jm33510g	journal	January 2012
Synthesis of Mesoporous Silica from Commercial Poly(ethylene oxide)/Poly(butylene oxide) Copolymers: Toward the Rational Design of Ordered Mesoporous Materials Yu, Chengzhong; Fan, Jie; Tian, Bozhi The Journal of Physical Chemistry B, Vol. 107, Issue 48 https://doi.org/10.1021/jp027046u	journal	December 2003
Self-Assembly and Characterization of Mesostructured Silica Films with a 3D Arrangement of Isolated Spherical Mesopores Yu, K.; Smarsly, B.; Brinker, C. J. Advanced Functional Materials, Vol. 13, Issue 1 https://doi.org/10.1002/adfm.200390005	journal	January 2003
Efficient Functional Delivery of siRNA using Mesoporous Silica Nanoparticles with Ultralarge Pores Na, Hee-Kyung; Kim, Mi-Hee; Park, Kihyun Small, Vol. 8, Issue 11 https://doi.org/10.1002/smll.201200028	journal	March 2012
Facile Preparation of Ultra-Large Pore Mesoporous Silica Nanoparticles and Their Application to the Encapsulation of Large Guest Molecules Shin, Hye-Seon; Hwang, Yong-Kyung; Huh, Seong ACS Applied Materials & Interfaces, Vol. 6, Issue 3 https://doi.org/10.1021/am404709w	journal	January 2014
Tailoring Pore Size of Ordered Mesoporous Silicas Using One or Two Organic Auxiliaries as Expanders Blin, J. L.; Su, B. L. Langmuir, Vol. 18, Issue 13 https://doi.org/10.1021/la020042w	journal	June 2002
Facile synthesis of ordered large-pore mesoporous silica thin film with Im3m symmetry using n-butanol as the cosurfactant Fang, Hua; Zhang, Mei; Shi, Wei-hai Journal of Non-Crystalline Solids, Vol. 352, Issue 21-22 https://doi.org/10.1016/j.jnoncrysol.2006.02.057	journal	July 2006
Mesocellular Siliceous Foams with Uniformly Sized Cells and Windows Schmidt-Winkel, Patrick; Lukens,, Wayne W.; Zhao, Dongyuan Journal of the American Chemical Society, Vol. 121, Issue 1 https://doi.org/10.1021/ja983218i	journal	January 1999
Control of pore size and condensation rate of cubic mesoporous silica thin films using a swelling agent Hwang, Young Kyu; Patil, Kashinath Rangu; Jhung, Sung Hwa Microporous and Mesoporous Materials, Vol. 78, Issue 2-3 https://doi.org/10.1016/j.micromeso.2004.10.026	journal	March 2005
One-Pot Route to Produce Hierarchically Porous Titania Thin Films by Controlled Self-Assembly, Swelling, and Phase Separation Malfatti, Luca; Bellino, Martín G.; Innocenzi, Plinio Chemistry of Materials, Vol. 21, Issue 13 https://doi.org/10.1021/cm900289c	journal	July 2009
Preparation and characterization of organo-modified SBA-15 by using polypropylene glycol as a swelling agent Park, Byeong-Gyu; Guo, Wanping; Cui, Xiuguo Microporous and Mesoporous Materials, Vol. 66, Issue 2-3 https://doi.org/10.1016/j.micromeso.2003.09.013	journal	December 2003
Expansion of the F127-templated mesostructure in aerosol-generated particles by using polypropylene glycol as a swelling agent Sörensen, Malin H.; Corkery, Robert W.; Pedersen, Jan Skov Microporous and Mesoporous Materials, Vol. 113, Issue 1-3 https://doi.org/10.1016/j.micromeso.2007.10.045	journal	August 2008
Tuning the Mesopore Size of Titania Thin Films Using a Polymeric Swelling Agent Wu, Qing Liu; Rankin, Stephen E. The Journal of Physical Chemistry C, Vol. 115, Issue 24 https://doi.org/10.1021/jp2021193	journal	May 2011
Effect of Cosolvents and Cosolutes upon Aggregation Transitions in Aqueous Solutions of the Poloxamer F87 (Poloxamer P237): A High Sensitivity Differential Scanning Calorimetry Study Armstrong, Jonathan; Chowdhry, Babur; Mitchell, John The Journal of Physical Chemistry, Vol. 100, Issue 5 https://doi.org/10.1021/jp951390s	journal	January 1996
Versatile Fabrication of Distorted Cubic Mesoporous Silica Film Using CTAB Together with a Hydrophobic Organic Additive Naik, Sajo P.; Yokoi, Toshiyuki; Fan, Wei The Journal of Physical Chemistry B, Vol. 110, Issue 20 https://doi.org/10.1021/jp060869p	journal	May 2006
Homopolymer induced phase evolution in mesoporous silica from evaporation induced self-assembly process Liu, Chong; Deng, Yonghui; Liu, Jia Microporous and Mesoporous Materials, Vol. 116, Issue 1-3 https://doi.org/10.1016/j.micromeso.2008.05.043	journal	December 2008
Micellization and Gelation of Mixed Copolymers P123 and F127 in Aqueous Solution Chaibundit, Chiraphon; Ricardo, Nágila M. P. S.; Costa, Flávia de M. L. L. Langmuir, Vol. 23, Issue 18 https://doi.org/10.1021/la701157j	journal	August 2007
Binary mixing of micelles using Pluronics for a nano-sized drug delivery system Lee, Eun Seong; Oh, Young Taik; Youn, Yu Seok Colloids and Surfaces B: Biointerfaces, Vol. 82, Issue 1 https://doi.org/10.1016/j.colsurfb.2010.08.033	journal	January 2011
Micellar formulations for drug delivery based on mixtures of hydrophobic and hydrophilic Pluronic® block copolymers Oh, Kyung T.; Bronich, Tatiana K.; Kabanov, Alexander V. Journal of Controlled Release, Vol. 94, Issue 2-3 https://doi.org/10.1016/j.jconrel.2003.10.018	journal	February 2004
Syntheses of complex mesoporous silicas using mixtures of nonionic block copolymer surfactants: Understanding formation of different structures using solubility parameters Chen, Lan; Xu, Ju; Zhang, Wen-Hua Journal of Colloid and Interface Science, Vol. 353, Issue 1 https://doi.org/10.1016/j.jcis.2010.09.043	journal	January 2011
Structural Design of Mesoporous Silica by Micelle-Packing Control Using Blends of Amphiphilic Block Copolymers Kim, Ji Man; Sakamoto, Yasuhiro; Hwang, Young Kyu The Journal of Physical Chemistry B, Vol. 106, Issue 10 https://doi.org/10.1021/jp014280w	journal	March 2002
Tailoring the Pore Structure of SBA-16 Silica Molecular Sieve through the Use of Copolymer Blends and Control of Synthesis Temperature and Time Kim, Tae-Wan; Ryoo, Ryong; Kruk, Michal The Journal of Physical Chemistry B, Vol. 108, Issue 31 https://doi.org/10.1021/jp048582k	journal	August 2004
Adsorption properties of phenolic resin-based mesoporous carbons obtained by using mixed templates of Pluronic F127 and Brij 58 or Brij 78 polymers Choma, Jerzy; Żubrowska, Anna; Górka, Joanna Adsorption, Vol. 16, Issue 4-5 https://doi.org/10.1007/s10450-010-9230-5	journal	June 2010
Determination of BET surface areas of porous thin films using surface acoustic wave devices Ricco, A. J.; Frye, G. C.; Martin, S. J. Langmuir, Vol. 5, Issue 1 https://doi.org/10.1021/la00085a053	journal	January 1989
Continuous Mesoporous Silica Films with Highly Ordered Large Pore Structures Zhao, Dongyuan; Yang, Peidong; Melosh, Nick Advanced Materials, Vol. 10, Issue 16 https://doi.org/10.1002/(SICI)1521-4095(199811)10:16<1380::AID-ADMA1380>3.0.CO;2-8	journal	November 1998
Adsorption Hysteresis of Nitrogen and Argon in Pore Networks and Characterization of Novel Micro- and Mesoporous Silicas Thommes, Matthias; Smarsly, Bernd; Groenewolt, Matthijs Langmuir, Vol. 22, Issue 2 https://doi.org/10.1021/la051686h	journal	January 2006
Characterization of Lipid-Templated Silica and Hybrid Thin Film Mesophases by Grazing Incidence Small-Angle X-ray Scattering Dunphy, Darren R.; Alam, Todd M.; Tate, Michael P. Langmuir, Vol. 25, Issue 16 https://doi.org/10.1021/la900748r	journal	August 2009
Simulation and Interpretation of 2D Diffraction Patterns from Self-Assembled Nanostructured Films at Arbitrary Angles of Incidence: From Grazing Incidence (Above the Critical Angle) to Transmission Perpendicular to the Substrate Tate, Michael P.; Urade, Vikrant N.; Kowalski, Jonathon D. The Journal of Physical Chemistry B, Vol. 110, Issue 20 https://doi.org/10.1021/jp0566008	journal	May 2006
Peering into the Self-Assembly of Surfactant Templated Thin-Film Silica Mesophases Doshi, Dhaval A.; Gibaud, Alain; Goletto, Valerie Journal of the American Chemical Society, Vol. 125, Issue 38 https://doi.org/10.1021/ja0295523	journal	September 2003
Evaporation-Controlled Self-Assembly of Silica Surfactant Mesophases Gibaud, A.; Grosso, D.; Smarsly, B. The Journal of Physical Chemistry B, Vol. 107, Issue 25 https://doi.org/10.1021/jp027612l	journal	June 2003
Hydration and Conformation of Temperature-Dependent Micellization of PEO−PPO−PEO Block Copolymers in Aqueous Solutions by FT-Raman Guo, Chen; Wang, Jing; Liu, Hui-zhou Langmuir, Vol. 15, Issue 8 https://doi.org/10.1021/la981036w	journal	April 1999
Convective Assembly of 2D Lattices of Virus-like Particles Visualized by In-Situ Grazing-Incidence Small-Angle X-Ray Scattering Ashley, Carlee E.; Dunphy, Darren R.; Jiang, Zhang Small, Vol. 7, Issue 8 https://doi.org/10.1002/smll.201001665	journal	March 2011

Cited By (8)

Influence of Chain Architecture on Nanopore Accessibility in Polyelectrolyte Block‐Co‐Oligomer Functionalized Mesopores Brilmayer, Robert; Hess, Christian; Andrieu‐Brunsen, Annette Small, Vol. 15, Issue 41 https://doi.org/10.1002/smll.201902710	journal	August 2019
Gravure printing for mesoporous film preparation Herzog, Nicole; Brilmayer, Robert; Stanzel, Mathias RSC Advances, Vol. 9, Issue 41 https://doi.org/10.1039/c9ra04266k	journal	January 2019
Growth and Functionalization of Particle-Based Mesoporous Silica Films and Their Usage in Catalysis Wu, Pei-Hsuan; Mäkie, Peter; Odén, Magnus Nanomaterials, Vol. 9, Issue 4 https://doi.org/10.3390/nano9040562	journal	April 2019
Mesoporous Silica Nanoparticles: A Comprehensive Review on Synthesis and Recent Advances Narayan, Reema; Nayak, Usha; Raichur, Ashok Pharmaceutics, Vol. 10, Issue 3 https://doi.org/10.3390/pharmaceutics10030118	journal	August 2018
Optimisation of Surface-Initiated Photoiniferter-Mediated Polymerisation under Confinement, and the Formation of Block Copolymers in Mesoporous Films Tom, Jessica; Brilmayer, Robert; Schmidt, Johannes Polymers, Vol. 9, Issue 12 https://doi.org/10.3390/polym9100539	journal	October 2017
Influence of Chain Architecture on Nanopore Accessibility in Polyelectrolyte Block‐Co‐Oligomer Functionalized Mesopores Brilmayer, Robert; Hess, Christian; Andrieu‐Brunsen, Annette Wiley https://doi.org/10.26083/tuprints-00019924	text	January 2021
Growth and functionalization of particle-based Mesoporous Silica films and their usage in catalysis Wu, Pei-Hsuan; Mäkie, Peter; Odén, Magnus Universität Ulm https://doi.org/10.18725/oparu-39414	text	January 2019
Optimisation of Surface-Initiated Photoiniferter-Mediated Polymerisation under Confinement, and the Formation of Block Copolymers in Mesoporous Films Tom, Jessica; Brilmayer, Robert; Schmidt, Johannes MDPI https://doi.org/10.26083/tuprints-00019931	text	January 2021

Similar Records

Time resolved in situ GISAXS Experiment of Evaporation Induced Self-assembly of CTAB Templated Silica Thin Films under Controlled Humidity

Journal Article · Sat Jan 01 00:00:00 EST 2005 · International Journal of Nanoscience (IJN) · OSTI ID:1173014

Dourdain, S; Colas, M; Bardeau, J; +3 more

Nano-Structured Mesoporous Silica Wires with Intra-Wire Lamellae via Evaporation-Induced Self-Assembly in Space-Confined Channels

Journal Article · Sun Apr 06 00:00:00 EDT 2014 · Journal of Nanomaterials · OSTI ID:1173014

Hu, Michael Z.; Shi, Donglu; Blom, Douglas Allen

Electron Microscopy and Nitrogen Adsorption Studies of Film-Type Carbon Replicas with Large Pore Volume Synthesized by Using Colloidal Silica and SBA-15 as Templates

Journal Article · Tue Jan 01 00:00:00 EST 2008 · Carbon · OSTI ID:1173014

Liang, Chengdu; Dai, Sheng

Title: Enlarged Pore Size in Mesoporous Silica Films Templated by Pluronic F127: Use of Poloxamer Mixtures and Increased Template/SiO[subscript 2] Ratios in Materials Synthesized by Evaporation-Induced Self-Assembly

Citation Formats

References (53)

Cited By (8)

Similar Records

Related Subjects