Water Oxidation Catalysis by Co(II) Impurities in Co(III)[subscript 4]O[subscript 4] Cubanes

Ullman, Andrew M.; Liu, Yi; Huynh, Michael; Bediako, D. Kwabena; Wang, Hongsen; Anderson, Bryce L.; Powers, David C.; Breen, John J.; Abruña, Héctor D.; Nocera, Daniel G.

doi:10.1021/ja5110393

Title: Water Oxidation Catalysis by Co(II) Impurities in Co(III)[subscript 4]O[subscript 4] Cubanes

Journal Article · Wed Dec 17 00:00:00 EST 2014 · J. Am. Chem. Soc.

DOI:https://doi.org/10.1021/ja5110393· OSTI ID:1171259

Ullman, Andrew M.; Liu, Yi; Huynh, Michael; Bediako, D. Kwabena; Wang, Hongsen; Anderson, Bryce L.; Powers, David C.; Breen, John J.; Abruña, Héctor D.; Nocera, Daniel G. ^[1]

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Energy Materials Center at Cornell (EMC2); Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: DOE - BASIC ENERGY SCIENCESNIH

OSTI ID:: 1171259

Journal Information:: J. Am. Chem. Soc., Vol. 136, Issue (50) ; 12, 2014

Country of Publication:: United States

Language:: ENGLISH

References (51)

Evolution of Iridium-Based Molecular Catalysts during Water Oxidation with Ceric Ammonium Nitrate Grotjahn, Douglas B.; Brown, Derek B.; Martin, Jessica K. Journal of the American Chemical Society, Vol. 133, Issue 47 https://doi.org/10.1021/ja203095k	journal	November 2011
EPR Evidence for Co(IV) Species Produced During Water Oxidation at Neutral pH McAlpin, J. Gregory; Surendranath, Yogesh; Dincǎ, Mircea Journal of the American Chemical Society, Vol. 132, Issue 20 https://doi.org/10.1021/ja1013344	journal	May 2010
Nickel-borate oxygen-evolving catalyst that functions under benign conditions Dinca, M.; Surendranath, Y.; Nocera, D. G. Proceedings of the National Academy of Sciences, Vol. 107, Issue 23 https://doi.org/10.1073/pnas.1001859107	journal	May 2010
Powering the planet: Chemical challenges in solar energy utilization Lewis, N. S.; Nocera, D. G. Proceedings of the National Academy of Sciences, Vol. 103, Issue 43, p. 15729-15735 https://doi.org/10.1073/pnas.0603395103	journal	October 2006
Electrocatalytic Water Oxidation Beginning with the Cobalt Polyoxometalate [Co₄(H₂O)₂(PW₉O₃₄)₂]^10–: Identification of Heterogeneous CoO_x as the Dominant Catalyst Stracke, Jordan J.; Finke, Richard G. Journal of the American Chemical Society, Vol. 133, Issue 38, p. 14872-14875 https://doi.org/10.1021/ja205569j	journal	September 2011
Mechanism of the Quenching of the Tris(bipyridine)ruthenium(II) Emission by Persulfate: Implications for Photoinduced Oxidation Reactions Lewandowska-Andralojc, A.; Polyansky, D. E. The Journal of Physical Chemistry A, Vol. 117, Issue 40 https://doi.org/10.1021/jp407573d	journal	September 2013
Light-driven wateroxidation with a molecular tetra-cobalt(iii) cubanecluster La Ganga, Giuseppina; Puntoriero, Fausto; Campagna, Sebastiano Faraday Discuss., Vol. 155 https://doi.org/10.1039/C1FD00093D	journal	January 2012
Water Oxidation Mechanism for Synthetic Co–Oxides with Small Nuclearity Li, Xichen; Siegbahn, Per E. M. Journal of the American Chemical Society, Vol. 135, Issue 37 https://doi.org/10.1021/ja4053448	journal	September 2013
Proton–Electron Transport and Transfer in Electrocatalytic Films. Application to a Cobalt-Based O ₂ -Evolution Catalyst Bediako, D. Kwabena; Costentin, Cyrille; Jones, Evan C. Journal of the American Chemical Society, Vol. 135, Issue 28 https://doi.org/10.1021/ja403656w	journal	May 2013
In Situ Formation of an Oxygen-Evolving Catalyst in Neutral Water Containing Phosphate and Co²⁺ Kanan, M. W.; Nocera, D. G. Science, Vol. 321, Issue 5892, p. 1072-1075 https://doi.org/10.1126/science.1162018	journal	August 2008
Water-oxidation catalysis by manganese in a geochemical-like cycle Hocking, Rosalie K.; Brimblecombe, Robin; Chang, Lan-Yun Nature Chemistry, Vol. 3, Issue 6 https://doi.org/10.1038/nchem.1049	journal	May 2011
Solar Energy Supply and Storage for the Legacy and Nonlegacy Worlds Cook, Timothy R.; Dogutan, Dilek K.; Reece, Steven Y. Chemical Reviews, Vol. 110, Issue 11 https://doi.org/10.1021/cr100246c	journal	November 2010
A Functionally Stable Manganese Oxide Oxygen Evolution Catalyst in Acid Huynh, Michael; Bediako, D. Kwabena; Nocera, Daniel G. Journal of the American Chemical Society, Vol. 136, Issue 16 https://doi.org/10.1021/ja413147e	journal	April 2014
A soluble copper–bipyridine water-oxidation electrocatalyst Barnett, Shoshanna M.; Goldberg, Karen I.; Mayer, James M. Nature Chemistry, Vol. 4, Issue 6 https://doi.org/10.1038/nchem.1350	journal	May 2012
Interconversion of dinuclear and oxo-centered trinuclear cobaltic acetates Sumner, C. E. Inorganic Chemistry, Vol. 27, Issue 8 https://doi.org/10.1021/ic00281a004	journal	April 1988
A Co ₄ O ₄ “Cubane” Water Oxidation Catalyst Inspired by Photosynthesis McCool, Nicholas S.; Robinson, David M.; Sheats, John E. Journal of the American Chemical Society, Vol. 133, Issue 30 https://doi.org/10.1021/ja203877y	journal	August 2011
Structural insights into [Co4O4(C5H5N)4(CH3CO2)4]+, a rare Co(IV)-containing cuboidal complex Stich, Troy A.; Krzystek, J.; Mercado, Brandon Q. Polyhedron, Vol. 64 https://doi.org/10.1016/j.poly.2013.05.038	journal	November 2013
Thermochemistry of Proton-Coupled Electron Transfer Reagents and its Implications Warren, Jeffrey J.; Tronic, Tristan A.; Mayer, James M. Chemical Reviews, Vol. 110, Issue 12 https://doi.org/10.1021/cr100085k	journal	December 2010
Electocatalytic Water Oxidation by Cobalt(III) Hangman β-Octafluoro Corroles Dogutan, Dilek K.; McGuire, Robert; Nocera, Daniel G. Journal of the American Chemical Society, Vol. 133, Issue 24 https://doi.org/10.1021/ja202138m	journal	June 2011
What Determines Catalyst Functionality in Molecular Water Oxidation? Dependence on Ligands and Metal Nuclearity in Cobalt Clusters Smith, Paul F.; Kaplan, Christopher; Sheats, John E. Inorganic Chemistry, Vol. 53, Issue 4 https://doi.org/10.1021/ic402720p	journal	December 2013
Ligand Substitution Reactions at Inorganic Centers ^† Richens, David T. Chemical Reviews, Vol. 105, Issue 6 https://doi.org/10.1021/cr030705u	journal	June 2005
Electrolyte-Dependent Electrosynthesis and Activity of Cobalt-Based Water Oxidation Catalysts Surendranath, Yogesh; Dincǎ, Mircea; Nocera, Daniel G. Journal of the American Chemical Society, Vol. 131, Issue 7 https://doi.org/10.1021/ja807769r	journal	February 2009
Structure and Valency of a Cobalt−Phosphate Water Oxidation Catalyst Determined by in Situ X-ray Spectroscopy Kanan, Matthew W.; Yano, Junko; Surendranath, Yogesh Journal of the American Chemical Society, Vol. 132, Issue 39 https://doi.org/10.1021/ja1023767	journal	October 2010
Efficient water oxidation catalyzed by homogeneous cationic cobalt porphyrins with critical roles for the buffer base Wang, D.; Groves, J. T. Proceedings of the National Academy of Sciences, Vol. 110, Issue 39 https://doi.org/10.1073/pnas.1315383110	journal	September 2013
Photocatalytic Water Oxidation: Tuning Light-Induced Electron Transfer by Molecular Co ₄ O ₄ Cores Berardi, Serena; La Ganga, Giuseppina; Natali, Mirco Journal of the American Chemical Society, Vol. 134, Issue 27 https://doi.org/10.1021/ja303951z	journal	June 2012
Electronic Structure Description of a [Co(III) ₃ Co(IV)O ₄ ] Cluster: A Model for the Paramagnetic Intermediate in Cobalt-Catalyzed Water Oxidation McAlpin, J. Gregory; Stich, Troy A.; Ohlin, C. André Journal of the American Chemical Society, Vol. 133, Issue 39 https://doi.org/10.1021/ja202320q	journal	October 2011
Mechanistic Studies of the Oxygen Evolution Reaction by a Cobalt-Phosphate Catalyst at Neutral pH Surendranath, Yogesh; Kanan, Matthew W.; Nocera, Daniel G. Journal of the American Chemical Society, Vol. 132, Issue 46 https://doi.org/10.1021/ja106102b	journal	November 2010
A molecular ruthenium catalyst with water-oxidation activity comparable to that of photosystem II Duan, Lele; Bozoglian, Fernando; Mandal, Sukanta Nature Chemistry, Vol. 4, Issue 5 https://doi.org/10.1038/nchem.1301	journal	March 2012
Turnover Numbers, Turnover Frequencies, and Overpotential in Molecular Catalysis of Electrochemical Reactions. Cyclic Voltammetry and Preparative-Scale Electrolysis Costentin, Cyrille; Drouet, Samuel; Robert, Marc Journal of the American Chemical Society, Vol. 134, Issue 27, p. 11235-11242 https://doi.org/10.1021/ja303560c	journal	June 2012
Electrochemical Activation of Cp* Iridium Complexes for Electrode-Driven Water-Oxidation Catalysis Thomsen, Julianne M.; Sheehan, Stafford W.; Hashmi, Sara M. Journal of the American Chemical Society, Vol. 136, Issue 39 https://doi.org/10.1021/ja5068299	journal	September 2014
Nucleation, Growth, and Repair of a Cobalt-Based Oxygen Evolving Catalyst Surendranath, Yogesh; Lutterman, Daniel A.; Liu, Yi Journal of the American Chemical Society, Vol. 134, Issue 14 https://doi.org/10.1021/ja3000084	journal	March 2012
Electrochemical and Photoelectrochemical Water Oxidation by Supported Cobalt–Oxo Cubanes Zhang, Biaobiao; Li, Fei; Yu, Fengshou ACS Catalysis, Vol. 4, Issue 3 https://doi.org/10.1021/cs401109u	journal	January 2014
Homogeneous Photochemical Water Oxidation by Biuret-Modified Fe-TAML: Evidence of Fe ^V (O) Intermediate Panda, Chakadola; Debgupta, Joyashish; Díaz Díaz, David Journal of the American Chemical Society, Vol. 136, Issue 35 https://doi.org/10.1021/ja503753k	journal	August 2014
Elucidating the Domain Structure of the Cobalt Oxide Water Splitting Catalyst by X-ray Pair Distribution Function Analysis Du, Pingwu; Kokhan, Oleksandr; Chapman, Karena W. Journal of the American Chemical Society, Vol. 134, Issue 27 https://doi.org/10.1021/ja303826a	journal	June 2012
Cobalt analogs of Ru-based water oxidation catalysts: overcoming thermodynamic instability and kinetic lability to achieve electrocatalytic O2 evolution Rigsby, Matthew L.; Mandal, Sukanta; Nam, Wonwoo Chemical Science, Vol. 3, Issue 10 https://doi.org/10.1039/c2sc20755a	journal	January 2012
Water Oxidation Catalysis Beginning with Co₄(H₂O)₂(PW₉O₃₄)₂^10– When Driven by the Chemical Oxidant Ruthenium(III)tris(2,2′-bipyridine): Stoichiometry, Kinetic, and Mechanistic Studies en Route to Identifying the True Catalyst Stracke, Jordan J.; Finke, Richard G. ACS Catalysis, Vol. 4, Issue 1, p. 79-89 https://doi.org/10.1021/cs4006925	journal	December 2013
Mechanistic Studies of the Oxygen Evolution Reaction Mediated by a Nickel–Borate Thin Film Electrocatalyst Bediako, D. Kwabena; Surendranath, Yogesh; Nocera, Daniel G. Journal of the American Chemical Society, Vol. 135, Issue 9 https://doi.org/10.1021/ja3126432	journal	February 2013
Distinguishing Homogeneous from Heterogeneous Catalysis in Electrode-Driven Water Oxidation with Molecular Iridium Complexes Schley, Nathan D.; Blakemore, James D.; Subbaiyan, Navaneetha K. Journal of the American Chemical Society, Vol. 133, Issue 27 https://doi.org/10.1021/ja2004522	journal	July 2011
Dimerization of the [Co2III(OH)2] core to the first example of a [Co4IIIO4] cubane: potential insights into photosynthetic water oxidation Dimitrou, Katerina; Folting, Kirsten; Streib, William E. Journal of the American Chemical Society, Vol. 115, Issue 14 https://doi.org/10.1021/ja00067a077	journal	July 1993
Fragments of Layered Manganese Oxide Are the Real Water Oxidation Catalyst after Transformation of Molecular Precursor on Clay Najafpour, M. M.; Moghaddam, Atefeh N.; Dau, Holger Journal of the American Chemical Society, Vol. 136, Issue 20 https://doi.org/10.1021/ja5028716	journal	May 2014
Differentiating Homogeneous and Heterogeneous Water Oxidation Catalysis: Confirmation that [Co₄(H₂O)₂(α-PW₉O₃₄)₂]^10– Is a Molecular Water Oxidation Catalyst Vickers, James W.; Lv, Hongjin; Sumliner, Jordan M. Journal of the American Chemical Society, Vol. 135, Issue 38, p. 14110-14118 https://doi.org/10.1021/ja4024868	journal	September 2013
Intermediate-Range Structure of Self-Assembled Cobalt-Based Oxygen-Evolving Catalyst Farrow, Christopher L.; Bediako, D. Kwabena; Surendranath, Yogesh Journal of the American Chemical Society, Vol. 135, Issue 17 https://doi.org/10.1021/ja401276f	journal	April 2013
Electrochemical evidence for catalytic water oxidation mediated by a high-valent cobalt complex Wasylenko, Derek J.; Ganesamoorthy, Chelladurai; Borau-Garcia, Javier Chemical Communications, Vol. 47, Issue 14 https://doi.org/10.1039/c0cc05522k	journal	January 2011
Spectroscopic Studies of Nanoparticulate Thin Films of a Cobalt-Based Oxygen Evolution Catalyst Liu, Yi; Nocera, Daniel G. The Journal of Physical Chemistry C, Vol. 118, Issue 30 https://doi.org/10.1021/jp5008347	journal	April 2014
Bidirectional and Unidirectional PCET in a Molecular Model of a Cobalt-Based Oxygen-Evolving Catalyst Symes, Mark D.; Surendranath, Yogesh; Lutterman, Daniel A. Journal of the American Chemical Society, Vol. 133, Issue 14 https://doi.org/10.1021/ja110908v	journal	April 2011
Synthesis, Structure, Spectral and Electrochemical Properties, and Catalytic Use of Cobalt(III)−Oxo Cubane Clusters Chakrabarty, Rajesh; Bora, Sanchay J.; Das, Birinchi K. Inorganic Chemistry, Vol. 46, Issue 22 https://doi.org/10.1021/ic7011759	journal	October 2007
Nucleation and Growth Mechanisms of an Electrodeposited Manganese Oxide Oxygen Evolution Catalyst Huynh, Michael; Bediako, D. Kwabena; Liu, Yi The Journal of Physical Chemistry C, Vol. 118, Issue 30 https://doi.org/10.1021/jp501768n	journal	April 2014
Reduction Potentials Involving Inorganic Free Radicals in Aqueous Solution Stanbury, David M. Advances in Inorganic Chemistry https://doi.org/10.1016/S0898-8838(08)60194-4	book	January 1989
Solar fuels generation and molecular systems: is it homogeneous or heterogeneous catalysis? Artero, Vincent; Fontecave, Marc Chem. Soc. Rev., Vol. 42, Issue 6 https://doi.org/10.1039/C2CS35334B	journal	January 2013
A Fast Soluble Carbon-Free Molecular Water Oxidation Catalyst Based on Abundant Metals Yin, Q.; Tan, J. M.; Besson, C. Science, Vol. 328, Issue 5976, p. 342-345 https://doi.org/10.1126/science.1185372	journal	March 2010
Water Oxidation Catalysis Beginning with 2.5 μM [Co₄(H₂O)₂(PW₉O₃₄)₂]^10–: Investigation of the True Electrochemically Driven Catalyst at ≥600 mV Overpotential at a Glassy Carbon Electrode Stracke, Jordan J.; Finke, Richard G. ACS Catalysis, Vol. 3, Issue 6, p. 1209-1219 https://doi.org/10.1021/cs400141t	journal	April 2013

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