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Title: Re-entrant Lithium Local Environments and Defect Driven Electrochemistry of Li- and Mn-Rich Li-Ion Battery Cathodes

Journal Article · · Journal of the American Chemical Society
DOI:https://doi.org/10.1021/ja511299y· OSTI ID:1169658
 [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1]
  1. Chemical Sciences and Engineering Division, ‡Materials Sciences Division, and §X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439, United States
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Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO)
OSTI ID:
1169658
Journal Information:
Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Vol. 137 Journal Issue: 6; ISSN 0002-7863
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 156 works
Citation information provided by
Web of Science

References (41)

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Effect of High Voltage on the Structure and Electrochemistry of LiNi 0.5 Mn 0.5 O 2 :  A Joint Experimental and Theoretical Study journal October 2006
Correlating hysteresis and voltage fade in lithium- and manganese-rich layered transition-metal oxide electrodes journal August 2013
Demonstrating Oxygen Loss and Associated Structural Reorganization in the Lithium Battery Cathode Li[Ni0.2Li0.2Mn0.6]O2 journal June 2006
Improved Capacity Retention for LiVO 2 by Cr Substitution journal December 2012
NMR Studies of Cathode Materials for Lithium-Ion Rechargeable Batteries journal October 2004
Quantifying Hysteresis and Voltage Fade in xLi 2 MnO 3 ● (1-x)LiMn 0.5 Ni 0.5 O 2 Electrodes as a Function of Li 2 MnO 3 Content journal December 2013
Electrodes with High Power and High Capacity for Rechargeable Lithium Batteries journal February 2006
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Examining Hysteresis in Composite x Li 2 MnO 3 ·(1– x )LiMO 2 Cathode Structures journal March 2013
Operando X-ray Absorption Study of the Redox Processes Involved upon Cycling of the Li-Rich Layered Oxide Li 1.20 Mn 0.54 Co 0.13 Ni 0.13 O 2 in Li Ion Batteries journal March 2014
6 Li MAS NMR Studies of the Local Structure and Electrochemical Properties of Cr-doped Lithium Manganese and Lithium Cobalt Oxide Cathode Materials for Lithium-Ion Batteries journal May 2002
Cation Ordering in Li[Ni x Mn x Co (1–2 x ) ]O 2 -Layered Cathode Materials: A Nuclear Magnetic Resonance (NMR), Pair Distribution Function, X-ray Absorption Spectroscopy, and Electrochemical Study journal December 2007
Electrochemical and Structural Study of the Layered, “Li-Excess” Lithium-Ion Battery Electrode Material Li[Li 1/9 Ni 1/3 Mn 5/9 ]O 2 journal July 2009
Combined Neutron Diffraction, NMR, and Electrochemical Investigation of the Layered-to-Spinel Transformation in LiMnO 2 journal August 2004
Understanding the NMR shifts in paramagnetic transition metal oxides using density functional theory calculations journal May 2003
Building better batteries journal February 2008
Li2MnO3-stabilized LiMO2 (M = Mn, Ni, Co) electrodes for lithium-ion batteries journal January 2007
Insight into the Atomic Structure of Cycled Lithium-Rich Layered Oxide Li 1.20 Mn 0.54 Co 0.13 Ni 0.13 O 2 Using HAADF STEM and Electron Nanodiffraction journal December 2014
A comparison of destabilization mechanisms of the layered NaxMO2 and LixMO2 compounds upon alkali de-intercalation journal January 2012
Lithium MAS NMR studies of cathode materials for lithium-ion batteries journal June 2003
Layered-to-Spinel Phase Transition in Li[sub x]MnO[sub 2] journal January 2001
Effect of Cooling Rates on Phase Separation in 0.5Li 2 MnO 3 ·0.5LiCoO 2 Electrode Materials for Li-Ion Batteries journal May 2014
Voltage Fade of Layered Oxides: Its Measurement and Impact on Energy Density journal January 2013
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Determining the Lithium Local Environments in the Lithium Manganates LiZn 0.5 Mn 1.5 O 4 and Li 2 MnO 3 by Analysis of the 6 Li MAS NMR Spinning Sideband Manifolds journal April 2002
Correlating cation ordering and voltage fade in a lithium–manganese-rich lithium-ion battery cathode oxide: a joint magnetic susceptibility and TEM study journal January 2013
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6Li MAS NMR and in situ X-ray studies of lithium nickel manganese oxides journal June 2003
First Evidence of Manganese–Nickel Segregation and Densification upon Cycling in Li-Rich Layered Oxides for Lithium Batteries journal July 2013

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