skip to main content

SciTech ConnectSciTech Connect

Title: A Three-Dimensional Microporous Metal-Metalloporphyrin Framework

A new porphyrin-based microporous MOF, {Mn(II)0.5[Mn(II)4Cl(Mn(III)Cl-ttzpp)2(H2O)4]}·(DEF)20·(CH3OH)18·(H2O)12 (UTSA-57), has been constructed from {5,10,15,20-tetrakis[4-(2,3,4,5-tetrazolyl)phenyl]porphyrinato} manganese(III) chloride as the metalloligand. The MOF adopts the rare scu topology with one-dimensional square nanotube-like channels of about 20 Å. UTSA-57a exhibits permanent porosity and displays moderately high performance for C2H2/CH4 separation at room temperature.
; ; ; ; ; ; ;  [1] ;  [2] ;  [2] ;  [2]
  1. Ames
  2. (
Publication Date:
OSTI Identifier:
Resource Type:
Journal Article
Resource Relation:
Journal Name: Inorg. Chem.; Journal Volume: 54; Journal Issue: (1) ; 01, 2015
Research Org:
Advanced Photon Source (APS), Argonne National Laboratory (ANL), Argonne, IL (US)
Sponsoring Org:
Country of Publication:
United States