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Title: Self-assembling hydrogel scaffolds for photocatalytic hydrogen production

Journal Article · · Nat Chem
DOI:https://doi.org/10.1038/nchem.2075· OSTI ID:1168381

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Argonne-Northwestern Solar Energy Research Center (ANSER)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
SC0001059
OSTI ID:
1168381
Journal Information:
Nat Chem, Vol. 6; Related Information: ANSER partners with Northwestern University (lead); Argonne National Laboratory; University of Chicago; University of Illinois, Urbana-Champaign; Yale University
Country of Publication:
United States
Language:
English

References (35)

Crystal structure of oxygen-evolving photosystem II at a resolution of 1.9 Å journal April 2011
The structure of a plant photosystem I supercomplex at 3.4 Å resolution journal May 2007
Highly Active and Robust Cp* Iridium Complexes for Catalytic Water Oxidation journal July 2009
In Situ Formation of an Oxygen-Evolving Catalyst in Neutral Water Containing Phosphate and Co2+ journal August 2008
A Molecular MoS2 Edge Site Mimic for Catalytic Hydrogen Generation journal February 2012
A Fast Soluble Carbon-Free Molecular Water Oxidation Catalyst Based on Abundant Metals journal March 2010
A Synthetic Nickel Electrocatalyst with a Turnover Frequency Above 100,000 s-1 for H2 Production journal August 2011
Robust Photogeneration of H2 in Water Using Semiconductor Nanocrystals and a Nickel Catalyst journal November 2012
Photoelectrochemical Hydrogen Evolution Using Si Microwire Arrays
  • Boettcher, Shannon W.; Warren, Emily L.; Putnam, Morgan C.
  • Journal of the American Chemical Society, Vol. 133, Issue 5, p. 1216-1219 https://doi.org/10.1021/ja108801m
journal January 2011
Photoinitiated multi-step charge separation and ultrafast charge transfer induced dissociation in a pyridyl-linked photosensitizer–cobaloxime assembly journal January 2013
Photoinitiated multistep charge separation in ferrocene–zinc porphyrin–diiron hydrogenase model complex triads journal January 2011
Wireless Solar Water Splitting Using Silicon-Based Semiconductors and Earth-Abundant Catalysts journal September 2011
Functional Supramolecular Polymers journal February 2012
Functional π-Gelators and Their Applications journal December 2013
Synthesis of perylene-3,4-dicarboximides — Novel highly photostable fluorescent dyes journal July 1995
Self-Assembly-Induced Ultrafast Photodriven Charge Separation in Perylene-3,4-dicarboximide-Based Hydrogen-Bonded Foldamers journal December 2012
Self-Assembly of Perylene Monoimide Substituted Hexa-peri-hexabenzocoronenes: Dyads and Triads at Surfaces journal May 2006
Photophysics and Redox Properties of Rylene Imide and Diimide Dyes Alkylated Ortho to the Imide Groups journal February 2010
Spontaneous and X-ray-Triggered Crystallization at Long Range in Self-Assembling Filament Networks journal December 2009
Self-Assembly, Dynamics, and Phase Transformation Kinetics of Donor−Acceptor Substituted Perylene Derivatives journal June 2010
Self-Assembly of Light-Harvesting Crystalline Nanosheets in Aqueous Media journal April 2013
Perylene bisimide dyes as versatile building blocks for functional supramolecular architectures journal January 2004
The Spectral Signatures of Frenkel Polarons in H- and J-Aggregates journal March 2010
Investigation of the Self-Organization of Lutein and Lutein Diacetate by Electronic Absorption, Circular Dichroism Spectroscopy, and Atomic Force Microscopy journal October 2001
Probing Excitation Delocalization in Supramolecular Chiral Stacks by Means of Circularly Polarized Light:  Experiment and Modeling journal June 2007
Hydrogen generating gel systems induced by visible light journal January 2009
Biomimetic Multifunctional Porous Chalcogels as Solar Fuel Catalysts journal May 2011
Photosensitized Hydrogen Evolution from Water Using Conjugated Polymers Wrapped in Dendrimeric Electrolytes journal September 2004
Photocatalytic Hydrogen Production from Noncovalent Biohybrid Photosystem I/Pt Nanoparticle Complexes journal January 2011
Nature of hydrogen interactions with Ni(II) complexes containing cyclic phosphine ligands with pendant nitrogen bases journal March 2007
A stable molecular nickel catalyst for the homogeneous photogeneration of hydrogen in aqueous solution journal January 2011
Photogeneration of hydrogen from water using CdSe nanocrystals demonstrating the importance of surface exchange journal September 2013
Incorporating Peptides in the Outer-Coordination Sphere of Bioinspired Electrocatalysts for Hydrogen Production journal May 2011
Hydrogen Generating Gel Systems Induced by Visible Light conference January 2008
Perylene Bisimide Dyes as Versatile Building Blocks for Functional Supramolecular Architectures journal November 2004

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Challenges and opportunities for hydrogen production from microalgae journal January 2016
Self-assembling peptide semiconductors journal November 2017
Beyond Covalent Crosslinks: Applications of Supramolecular Gels journal May 2018
Tuning the Supramolecular Structures of Metal-Free Porphyrin via Surfactant Assisted Self-Assembly to Enhance Photocatalytic Performance journal September 2019
Covalent Attachment of the Water-insoluble Ni(P Cy 2 N Phe 2 ) 2 Electrocatalyst to Electrodes Showing Reversible Catalysis in Aqueous Solution journal October 2016
Homogeneous vs. heterogeneous catalysis for hydrogen evolution by a nickel( ii ) bis(diphosphine) complex journal January 2019
Water-Binding-Mediated Gelation/Crystallization and Thermosensitive Superchirality journal May 2018
The Ultrafast Assembly of a Dipeptide Supramolecular Organogel and its Phase Transition from Gel to Crystal journal July 2019
Carbon dots as photosensitisers for solar-driven catalysis text January 2017
Mixing Biomimetic Heterodimers of Nucleopeptides to Generate Biocompatible and Biostable Supramolecular Hydrogels journal March 2015
Perylene Bisimide Dyes with up to Five Independently Introduced Substituents: Controlling the Functionalization Pattern and Photophysical Properties Using Regiospecific Bay Substitution journal July 2019
Self-Healing Hydrogel from a Dipeptide and HCl Sensing journal April 2018
Supramolecular Packing Controls H 2 Photocatalysis in Chromophore Amphiphile Hydrogels journal November 2015
Crystal-Phase Transitions and Photocatalysis in Supramolecular Scaffolds journal April 2017
Supramolecular Packing and Macroscopic Alignment Controls Actuation Speed in Macroscopic Strings of Molecular Motor Amphiphiles journal November 2018
Biocompatible fluorescent supramolecular nanofibrous hydrogel for long-term cell tracking and tumor imaging applications journal November 2015