Local environment and composition of magnesium gallium layered double hydroxides determined from solid-state 1H and 71Ga NMR spectroscopy
Journal Article
·
· Journal of Solid State Chemistry, 219:242-246
Ordering of gallium(III) in a series of magnesium gallium layered double hydroxides (LDH’s), [Mg1-xGax(OH)2(NO3)x yH2O], was determined using solid-state 1H and 71Ga NMR spectroscopy. Depletion of Ga in these LDH’s is demonstrated to be the result of soluble [Ga(OH)4]-complexes formed during synthesis.
- Research Organization:
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Environmental Molecular Sciences Lab. (EMSL)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC05-76RL01830
- OSTI ID:
- 1166859
- Report Number(s):
- PNNL-SA-100729; 44623; KP1704020
- Journal Information:
- Journal of Solid State Chemistry, 219:242-246, Journal Name: Journal of Solid State Chemistry, 219:242-246
- Country of Publication:
- United States
- Language:
- English
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