Sodium iron hexacyanoferrate with high Na content as a Na-rich cathode material for Na-ion batteries

You, Ya; Yu, Xi -Qian; Yin, Ya -Xia; Nam, Kyung -Wan; Guo, Yu -Guo

doi:10.1007/s12274-014-0588-7

Title: Sodium iron hexacyanoferrate with high Na content as a Na-rich cathode material for Na-ion batteries

Journal Article · Mon Oct 27 00:00:00 EDT 2014 · Nano Research

DOI:https://doi.org/10.1007/s12274-014-0588-7· OSTI ID:1164333

You, Ya ^[1]; Yu, Xi -Qian ^[2]; Yin, Ya -Xia ^[1]; Nam, Kyung -Wan ^[2]; Guo, Yu -Guo ^[1]

Chinese Academy of Sciences (CAS), Beijing (China)
Brookhaven National Lab. (BNL), Upton, NY (United States)

Owing to the worldwide abundance and low-cost of Na, room-temperature Na-ion batteries are emerging as attractive energy storage systems for large-scale grids. Increasing the Na content in cathode material is one of the effective ways to achieve high energy density. Prussian blue and its analogues (PBAs) are promising Na-rich cathode materials since they can theoretically store two Na ions per formula. However, increasing the Na content in PBAs cathode materials is a big challenge in the current. Here we show that sodium iron hexacyanoferrate with high Na content could be obtained by simply controlling the reducing agent and reaction atmosphere during synthesis. The Na content can reach as high as 1.63 per formula, which is the highest value for sodium iron hexacyanoferrate. This Na-rich sodium iron hexacyanoferrate demonstrates a high specific capacity of 150 mA h g^-1 and remarkable cycling performance with 90% capacity retention after 200 cycles. Furthermore, the Na intercalation/de-intercalation mechanism is systematically studied by in situ Raman, X-ray diffraction and X-ray absorption spectroscopy analysis for the first time. As a result, the Na-rich sodium iron hexacyanoferrate could function as a plenteous Na reservoir and has great potential as a cathode material toward practical Na-ion batteries.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC02-98CH10886

OSTI ID:: 1164333

Report Number(s):: BNL-107069-2014-JA; VT1201000-05450-1005554

Journal Information:: Nano Research, Vol. 8, Issue 1; ISSN 1998-0124

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 274 works

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A high over-potential binder-free electrode constructed of Prussian blue and MnO2 for high performance aqueous supercapacitors Zhang, Gaowei; Yao, Hua; Zhang, Feng Nano Research, Vol. 12, Issue 5 https://doi.org/10.1007/s12274-019-2347-2	journal	March 2019
Electrode Materials for Sodium-Ion Batteries: Considerations on Crystal Structures and Sodium Storage Mechanisms Wang, Tianyi; Su, Dawei; Shanmukaraj, Devaraj Electrochemical Energy Reviews, Vol. 1, Issue 2 https://doi.org/10.1007/s41918-018-0009-9	journal	June 2018
Polypyrrole-promoted superior cyclability and rate capability of Na _x Fe[Fe(CN) ₆ ] cathodes for sodium-ion batteries Tang, Yang; Zhang, Wuxing; Xue, Lihong Journal of Materials Chemistry A, Vol. 4, Issue 16 https://doi.org/10.1039/c6ta00876c	journal	January 2016
Development of a new alluaudite-based cathode material with high power and long cyclability for application in Na ion batteries in real-life Kim, Jongsoon; Kim, Hyungsub; Lee, Seongsu J. Mater. Chem. A, Vol. 5, Issue 42 https://doi.org/10.1039/c7ta06693g	journal	January 2017
Novel acetic acid induced Na-rich Prussian blue nanocubes with iron defects as cathodes for sodium ion batteries Li, Lan; Nie, Ping; Chen, Yubo Journal of Materials Chemistry A, Vol. 7, Issue 19 https://doi.org/10.1039/c9ta01965k	journal	January 2019
A flexible cyanometallate coordination polymer electrode for electrochemical dual-mode seawater energy extraction Li, Yucen; Dang, Qi; Shi, Chunjing Journal of Materials Chemistry A, Vol. 7, Issue 40 https://doi.org/10.1039/c9ta07540b	journal	January 2019
Highly crystalline sodium manganese ferrocyanide microcubes for advanced sodium ion battery cathodes Peng, Fangwei; Yu, Lei; Gao, Pengyue Journal of Materials Chemistry A, Vol. 7, Issue 39 https://doi.org/10.1039/c9ta08603j	journal	January 2019
Electrochemical Performance of NaFeFe(CN) ₆ Prepared by Solid Reaction for Sodium Ion Batteries Tang, Wan; Xie, Yingying; Peng, Fangwei Journal of The Electrochemical Society, Vol. 165, Issue 16 https://doi.org/10.1149/2.0701816jes	journal	January 2018
Prussian Blue Analogue Mesoframes for Enhanced Aqueous Sodium-ion Storage Sun, Huiyun; Zhang, Wei; Hu, Ming Crystals, Vol. 8, Issue 1, p. 23 https://doi.org/10.3390/cryst8010023	journal	January 2018
Tin-Decorated Reduced Graphene Oxide and NaLi0.2Ni0.25Mn0.75O as Electrode Materials for Sodium-Ion Batteries Prosini, Pier Paolo; Carewska, Maria; Cento, Cinzia Materials, Vol. 12, Issue 7 https://doi.org/10.3390/ma12071074	journal	April 2019
Morphology and Structure of Electrodeposited Prussian Blue and Prussian White Thin Films Baggio, Bruna; Vicente, Cristiano; Pelegrini, Silvia Materials, Vol. 12, Issue 7 https://doi.org/10.3390/ma12071103	journal	April 2019
A Dual-Insertion Type Sodium-Ion Full Cell Based on High-Quality Ternary-Metal Prussian Blue Analogs Peng, Jian; Wang, Jinsong; Yi, Haocong Advanced Energy Materials, Vol. 8, Issue 11 https://doi.org/10.1002/aenm.201702856	journal	January 2018
Suppressing the P2-O2 Phase Transition of Na _0.67 Mn _0.67 Ni _0.33 O ₂ by Magnesium Substitution for Improved Sodium-Ion Batteries Wang, Peng-Fei; You, Ya; Yin, Ya-Xia Angewandte Chemie, Vol. 128, Issue 26 https://doi.org/10.1002/ange.201602202	journal	May 2016
Size Engineering and Crystallinity Control Enable High‐Capacity Aqueous Potassium‐Ion Storage of Prussian White Analogues Li, Chang; Wang, Xusheng; Deng, Wenjun ChemElectroChem, Vol. 5, Issue 24 https://doi.org/10.1002/celc.201801277	journal	October 2018
Towards K-Ion and Na-Ion Batteries as “Beyond Li-Ion” Kubota, Kei; Dahbi, Mouad; Hosaka, Tomooki The Chemical Record, Vol. 18, Issue 4 https://doi.org/10.1002/tcr.201700057	journal	February 2018
Coordinating gallium hexacyanocobaltate: Prussian blue-based nanomaterial for Li-ion storage Zhang, Kaiqiang; Lee, Tae Hyung; Bubach, Bailey RSC Advances, Vol. 9, Issue 46 https://doi.org/10.1039/c9ra03746b	journal	January 2019
Constructing a 3D compact sulfur host based on carbon-nanotube threaded defective Prussian blue nanocrystals for high performance lithium–sulfur batteries Shen, Guohong; Liu, Zhixiao; Liu, Piao Journal of Materials Chemistry A, Vol. 8, Issue 3 https://doi.org/10.1039/c9ta11209j	journal	January 2020
Cerium Hexacyanocobaltate: A Lanthanide-Compliant Prussian Blue Analogue for Li-Ion Storage Zhang, Kaiqiang; Lee, Tae Hyung; Cha, Joo Hwan ACS Omega, Vol. 4, Issue 25 https://doi.org/10.1021/acsomega.9b03104	journal	December 2019
Reversible structural evolution of sodium-rich rhombohedral Prussian blue for sodium-ion batteries Wang, Wanlin; Gang, Yong; Hu, Zhe Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-14444-4	journal	February 2020

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