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Title: Impact of the various spin- and orbital-ordering processes on the multiferroic properties of orthovanadate DyVO3

The orthovanadate DyVO3 crystal, known to exhibit multiple structural, spin-, and orbital-ordering transitions, is presently investigated on the basis of magnetization, heat capacity, resistivity, dielectric, and polarization measurements. Our main result is experimental evidence for the existence of multiferroicity below a high TC of 108 K over a wide temperature range including different spin-orbital-ordered states. The onset of ferroelectricity is found to coincide with the antiferromagnetic C-type spin-ordering transition taking place at 108 K, which indicates that DyVO3 belongs to type-II multiferroics exhibiting a coupling between magnetism and ferroelectricity. Some anomalies detected on the temperature dependence of electric polarization are discussed with respect to the nature of the spin-orbital-ordered states of the V sublattice and the degree of spin alignment in the Dy sublattice. The orthovanadates RVO3 (R= rare earth or Y) form an important new category for searching for high-TC multiferroics.
 [1] ;  [2] ;  [3] ;  [4] ;  [4] ;  [2]
  1. Ames Laboratory
  2. Laboratoire CRISMAT
  3. Institut Laue Langevin
  4. University of Warwick
Publication Date:
OSTI Identifier:
Report Number(s):
IS-J 8418
Journal ID: ISSN 1098-0121; PRBMDO; ArticleNumber: 024418
DOE Contract Number:
Resource Type:
Journal Article
Resource Relation:
Journal Name: Physical Review. B, Condensed Matter and Materials Physics; Journal Volume: 90; Journal Issue: 2
American Physical Society (APS)
Research Org:
Ames Laboratory (AMES), Ames, IA (United States)
Sponsoring Org:
USDOE Office of Science (SC)
Country of Publication:
United States