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Title: Thermoelectric skutterudite compositions and methods for producing the same

Patent ·
OSTI ID:1163752

Compositions related to skutterudite-based thermoelectric materials are disclosed. Such compositions can result in materials that have enhanced ZT values relative to one or more bulk materials from which the compositions are derived. Thermoelectric materials such as n-type and p-type skutterudites with high thermoelectric figures-of-merit can include materials with filler atoms and/or materials formed by compacting particles (e.g., nanoparticles) into a material with a plurality of grains each having a portion having a skutterudite-based structure. Methods of forming thermoelectric skutterudites, which can include the use of hot press processes to consolidate particles, are also disclosed. The particles to be consolidated can be derived from (e.g., grinded from), skutterudite-based bulk materials, elemental materials, other non-Skutterudite-based materials, or combinations of such materials.

Research Organization:
Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FG02-00ER45805
Assignee:
Massachusetts Institute of Technology (Cambridge, MA)
Patent Number(s):
8,883,047
Application Number:
12/990,268
OSTI ID:
1163752
Resource Relation:
Patent File Date: 2009 Apr 30
Country of Publication:
United States
Language:
English

References (12)

Co-Sb based thermoelectric material and a method of producing the same patent July 1999
Thermodynamically metastable skutterudite crystalline-structured compounds patent November 1999
Skutterudite thermoelectric material thermoelectric couple and method of producing the same patent March 2001
Semiconductor materials with skutterudite type crystal lattice structures optimized for selected thermoelectric properties and methods of preparation patent March 2001
Nanocomposites with high thermoelectric figures of merit patent December 2008
Thermoelectric devices based on materials with filled skutterudite structutres patent-application November 2002
Thermoelectric material and method for producing same patent-application March 2006
Method for reverse link overload control in a wireless communication system patent-application August 2006
Methods for High Figure-of-Merit in Nanostructured Thermoelectric Materials patent-application August 2008
Making Thermoelectric Materials by Mechanosynthesis patent-application August 2009
Nanostructured Co1−xNixSb3 skutterudites: Synthesis, thermoelectric properties, and theoretical modeling journal January 2003
High figure of merit in partially filled ytterbium skutterudite materials journal January 2000

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