Self-assembling hydrogel scaffolds for photocatalytic hydrogen production

Weingarten, Adam S.; Kazantsev, Roman V.; Palmer, Liam C.; McClendon, Mark; Koltonow, Andrew R.; Samuel, Amanda P.  S.; Kiebala, Derek J.; Wasielewski, Michael R.; Stupp, Samuel I.

doi:10.1038/nchem.2075

Title: Self-assembling hydrogel scaffolds for photocatalytic hydrogen production

Journal Article · Sun Oct 05 00:00:00 EDT 2014 · Nature Chemistry

DOI:https://doi.org/10.1038/nchem.2075· OSTI ID:1162321

Weingarten, Adam S. ^[1]; Kazantsev, Roman V. ^[1]; Palmer, Liam C. ^[2]; McClendon, Mark ^[3]; Koltonow, Andrew R. ^[4]; Samuel, Amanda P. S. ^[1]; Kiebala, Derek J. ^[5]; Wasielewski, Michael R. ^[1]; Stupp, Samuel I. ^[6]

Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry. Argonne-Northwestern Solar Energy Research (ANSER) Center
Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry. Argonne-Northwestern Solar Energy Research (ANSER) Center; Northwestern Univ., Chicago, IL (United States). Simpson Querrey Inst. for BioNanotechnology
Northwestern Univ., Evanston, IL (United States). Dept. of Chemical and Biological Engineering
Northwestern Univ., Evanston, IL (United States). Dept. of Materials Science and Engineering
Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry. Argonne-Northwestern Solar Energy Research (ANSER) Center; Northwestern Univ., Chicago, IL (United States). Simpson Querrey Inst. for BioNanotechnology. Dept. of Materials Science and Engineering. Dept. of Medicine

Integration into a soft material of all the molecular components necessary to generate storable fuels is an interesting target in supramolecular chemistry. The concept is inspired by the internal structure of photosynthetic organelles, such as plant chloroplasts, which colocalize molecules involved in light absorption, charge transport and catalysis to create chemical bonds using light energy. We report in this paper on the light-driven production of hydrogen inside a hydrogel scaffold built by the supramolecular self-assembly of a perylene monoimide amphiphile. The charged ribbons formed can electrostatically attract a nickel-based catalyst, and electrolyte screening promotes gelation. We found the emergent phenomenon that screening by the catalyst or the electrolytes led to two-dimensional crystallization of the chromophore assemblies and enhanced the electronic coupling among the molecules. Finally, photocatalytic production of hydrogen is observed in the three-dimensional environment of the hydrogel scaffold and the material is easily placed on surfaces or in the pores of solid supports.

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Research Organization:: Northwestern Univ., Evanston, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Institutes of Health (NIH); National Science Foundation (NSF)

Grant/Contract Number:: SC0001059; AC02-06CH11357; 5P41RR007707; 8P41GM103543; CHE-9871268

OSTI ID:: 1162321

Alternate ID(s):: OSTI ID: 1820340

Journal Information:: Nature Chemistry, Vol. 6, Issue 11; ISSN 1755-4330

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: ENGLISH

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Cited by: 338 works

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