The adsorption of gold, palladium and platinum from acidic chloride solutions on mesoporous carbons.

Zalupski, Peter R.; McDowell, Rocklan; Dutech, Guy

doi:10.1080/07366299.2014.951278

Title: The adsorption of gold, palladium and platinum from acidic chloride solutions on mesoporous carbons.

Journal Article · Tue Aug 05 00:00:00 EDT 2014 · Solvent Extraction and Ion Exchange

DOI:https://doi.org/10.1080/07366299.2014.951278· OSTI ID:1162231

Zalupski, Peter R. ^[1]; McDowell, Rocklan ^[1]; Dutech, Guy ^[1]

Idaho National Lab. (INL), Idaho Falls, ID (United States)

Studies on the adsorption characteristics of gold, palladium and platinum on mesoporous carbon (CMK-3) and sulfur-impregnated mesoporous carbon (CMK-3/S) evaluated the benefits/drawbacks of the presence of a layer of elemental sulfur inside mesoporous carbon structures. Adsorption isotherms collected for Au(III), Pd(II) and Pt(IV) on those materials suggest that sulfur does enhance the adsorption of those metal ions in mildly acidic environment (pH 3). The isotherms collected in 1 M HCl show that the benefit of sulfur disappears due to the competing influence of large concentration of hydrogen ions on the ion-exchanging mechanism of metal ions sorption on mesoporous carbon surfaces. The collected acid dependencies illustrate similar adsorption characteristics for CMK-3 and CMK-3/S in 1-5 M HCl concentration range. Sorption of metal ions from diluted aqueous acidic mixtures of actual leached electronic waste demonstrated the feasibility of recovery of gold from such liquors.

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Research Organization:: Idaho National Lab. (INL), Idaho Falls, ID (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC07-05ID14517

OSTI ID:: 1162231

Report Number(s):: INL/JOU-14-31753

Journal Information:: Solvent Extraction and Ion Exchange, Vol. 32, Issue 7; ISSN 0736-6299

Publisher:: Taylor and FrancisCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 12 works

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37 INORGANIC
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PHYSICAL AND ANALYTICAL CHEMISTRY
electronic scrap
gold
mesoporous carbons
palladium
precious metals recovery

Title: The adsorption of gold, palladium and platinum from acidic chloride solutions on mesoporous carbons.

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