Formation of Large Polysulfide Complexes during the Lithium-Sulfur Battery Discharge

Journal Article · Wed Jan 01 00:00:00 EST 2014 · Physical Review Applied

DOI:https://doi.org/10.1103/PhysRevApplied.2.034004· OSTI ID:1159442

Wang, Bin ^[1]; Alhassan, Saeed M. ^[2]; Pantelides, Sokrates T ^[3]

---

1. Vanderbilt University, Nashville
2. The Petroleum Institute
3. ORNL

Sulfur cathodes have much larger capacities than transition-metal-oxide cathodes used in commercial lithium-ion batteries but suffer from unsatisfactory capacity retention and long-term cyclability. Capacity degradation originates from soluble lithium polysulfides gradually diffusing into the electrolyte. Understanding of the formation and dynamics of soluble polysulfides during the discharging process at the atomic level remains elusive, which limits further development of lithium-sulfur (Li-S) batteries. Here we report first-principles molecular dynamics simulations and density functional calculations, through which the discharging products of Li-S batteries are studied. We find that, in addition to simple Li2Sn (1 n 8) clusters generated from single cyclooctasulfur (S8) rings, large Li-S clusters form by collectively coupling several different rings to minimize the total energy. At high lithium concentration, a Li-S network forms at the sulfur surfaces. The results can explain the formation of the soluble Li-S complex, such as Li2S8, Li2S6, and Li2S4, and the insoluble Li2S2 and Li2S structures. In addition, we show that the presence of oxygen impurities in graphene, particularly oxygen atoms bonded to vacancies and edges, may stabilize the lithium polysulfides that may otherwise diffuse into the electrolyte.

• Research Organization: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
• Sponsoring Organization: USDOE Office of Science (SC)
• DOE Contract Number: DE-AC05-00OR22725
• OSTI ID: 1159442
• Journal Information: Physical Review Applied, Vol. 2, Issue 3; ISSN 2331--7019
• Country of Publication: United States
• Language: English