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Title: Preparation of functionalized zeolitic frameworks

Patent ·
OSTI ID:1150640

The disclosure provides zeolitic frameworks for gas separation, gas storage, catalysis and sensors. More particularly the disclosure provides zeolitic frameworks (ZIFs). The ZIF of the disclosure comprises any number of transition metals or a homogenous transition metal composition.

Research Organization:
Univ. of California, Oakland, CA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FG02-06ER15813
Assignee:
The Regents of the University of California (Oakland, CA); The Regents of the University of Michigan (Ann Arbor, MI)
Patent Number(s):
8,809,546
Application Number:
13/630,554
OSTI ID:
1150640
Country of Publication:
United States
Language:
English

References (110)

Gas adsorption agents particularly for separating H.sub.2 from a gaseous phase patent November 1982
Apparatus for the microcollimation of particles, detector and particle detection process, process for the manufacture and use of said microcollimating apparatus patent May 1997
Crystalline metal-organic microporous materials patent July 1997
Neutron individual dose meter neutron dose rate meter, neutron detector and its method of manufacture patent September 1998
Gas storage apparatus, gaseous fuel automobile using the gas storage apparatus, gas storage method and methane adsorbing-retaining agent patent January 1999
Neutron detector patent March 1999
Solid state neutron detector array patent August 1999
Ionizing radiation detector patent June 2000
Nucleic acid detection patent November 2001
Method for oxidizing an organic compound having at least one C-C double bond patent February 2002
Method for reacting an organic compound with a hydroperoxide patent November 2002
Coated semiconductor devices for neutron detection patent November 2002
Method for oxidizing an organic compound containing at least one C-C double bond patent February 2003
Pocked surface neutron detector patent April 2003
Process for producing polyalkylene carbonates patent September 2003
Process for the epoxidation of an organic compound with oxygen or an oxygen-delivering compounds using catalysts containing metal-organic frame-work materials patent September 2003
Method for converting an organic compound with a hydroperoxide patent April 2004
Shaped bodies containing metal-organic frameworks patent May 2005
Method of storing, uptaking, releasing of gases by novel framework materials patent August 2005
Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage patent August 2005
Nanoscale faceted polyhedra patent November 2005
Molecular wire injection sensors patent December 2005
Process for preparing hydrogen peroxide from the elements patent March 2006
Organometallic building materials and method for producing the same patent October 2006
Shaped bodies containing metal-organic frameworks patent April 2009
Preparation of functionalized zeolitic frameworks patent November 2012
Preparation of functionalized zeolitic frameworks patent July 2013
Process for the alkoxylation of organic compounds in the presence of novel framework materials patent-application April 2003
Implementation of a strategy for achieving extraordinary levels of surface area and porosity in crystals patent-application November 2004
Gas storage system patent-application December 2004
Process for the alkoxylation of monools in the presence of metallo-organic framework materials patent-application January 2005
ADSORPTIVE GAS SEPARATION OF MULTI-COMPONENT GASES patent-application June 2010
PREPARATION OF FUNCTIONALIZED ZEOLITIC FRAMEWORKS patent-application July 2010
Gas Sensor Incorporating a Porous Framework patent-application February 2012
Synthesis, Structure, and Carbon Dioxide Capture Properties of Zeolitic Imidazolate Frameworks journal January 2010
Reticular synthesis and the design of new materials journal June 2003
Semi-insulating bulk GaAs thermal neutron imaging arrays journal June 1996
Sputtered boron films on silicon surface barrier detectors journal June 1967
High efficiency neutron sensitive amorphous silicon pixel detectors journal January 1994
Neutron Detectors Made From Chemically Vapour Deposited Semiconductors journal January 1997
Thin-film-coated bulk GaAs detectors for thermal and fast neutron measurements
  • McGregor, D. S.; Klann, R. T.; Gersch, H. K.
  • Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 466, Issue 1, p. 126-141 https://doi.org/10.1016/S0168-9002(01)00835-X
journal June 2001
Design considerations for thin film coated semiconductor thermal neutron detectors—I: basics regarding alpha particle emitting neutron reactive films
  • McGregor, D. S.; Hammig, M. D.; Yang, Y.-H.
  • Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 500, Issue 1-3, p. 272-308 https://doi.org/10.1016/S0168-9002(02)02078-8
journal March 2003
Self-biased boron-10 coated high-purity epitaxial GaAs thermal neutron detectors journal January 2000
New surface morphology for low stress thin-film-coated thermal neutron detectors journal August 2002
A new neutron detector development based on silicon semiconductor and 6LiF converter journal June 1997
A neutron detector to monitor the intensity of transmitted neutrons for small-angle neutron scattering instruments
  • De Lurgio, Patrick M.; Klann, Raymond T.; Fink, Charles L.
  • Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 505, Issue 1-2, p. 46-49 https://doi.org/10.1016/S0168-9002(03)01017-9
journal June 2003
The effect of incremental gamma-ray doses and incremental neutron fluences upon the performance of self-biased 10B-coated high-purity epitaxial GaAs thermal neutron detectors
  • Gersch, H. K.; McGregor, D. S.; Simpson, P. A.
  • Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 489, Issue 1-3, p. 85-98 https://doi.org/10.1016/S0168-9002(02)00793-3
journal August 2002
Designs for thin-film-coated semiconductor thermal neutron detectors conference January 2002
Recent results from thin-film-coated semiconductor neutron detectors
  • McGregor, Douglas S.; Klann, Raymond T.; Sanders, Jeffrey D.
  • International Symposium on Optical Science and Technology, Vol. 4784 https://doi.org/10.1117/12.455697
conference January 2003
A route to high surface area, porosity and inclusion of large molecules in crystals journal February 2004
Porous Metal−Organic Polyhedra:  25 Å Cuboctahedron Constructed from 12 Cu2(CO2)4 Paddle-Wheel Building Blocks journal May 2001
Open Square-Grid Coordination Polymers of the Dimensions 20×20 Å: Remarkably Stable and Crystalline Solids Even after Guest Removal June 0745
Selective binding and removal of guests in a microporous metal–organic framework journal December 1995
Selective Guest Binding by Tailored Channels in a 3-D Porous Zinc(II)−Benzenetricarboxylate Network journal March 1997
Hydrothermal Synthesis of a Metal-Organic Framework Containing Large Rectangular Channels journal October 1995
Porous Germanates:  Synthesis, Structure, and Inclusion Properties of Ge7O14.5F2·[(CH3)2NH2]3(H2O)0.86 journal August 1998
Establishing Microporosity in Open Metal−Organic Frameworks:  Gas Sorption Isotherms for Zn(BDC) (BDC = 1,4-Benzenedicarboxylate) journal August 1998
Transformation of Germanium Dioxide to Microporous Germanate 4-Connected Nets journal October 1998
From Condensed Lanthanide Coordination Solids to Microporous Frameworks Having Accessible Metal Sites journal March 1999
An Open-Framework Germanate with Polycubane-Like Topology journal March 1999
A Microporous Lanthanide-Organic Framework journal September 1999
Cu2(ATC)·6H2O:  Design of Open Metal Sites in Porous Metal−Organic Crystals (ATC:  1,3,5,7-Adamantane Tetracarboxylate) journal November 2000
Tertiary Building Units:  Synthesis, Structure, and Porosity of a Metal−Organic Dendrimer Framework (MODF-1) October 2001
Cu2[o-Br-C6H3(CO2)2]2(H2O)2·(DMF)8(H2O)2:  A Framework Deliberately Designed To Have the NbO Structure Type journal January 2002
Die Kristallstruktur des Eisen(II)-Derivates des Imidazols journal September 1978
Darstellung und Kristallstruktur des Mangan(II)- und Zink(II)-Derivates des Imidazols journal May 1980
Molecular building blocks approach to the assembly of zeolite-like metal–organic frameworks (ZMOFs) with extra-large cavities journal January 2006
Polybis(4-azabenzimidazolato)-iron(II) and -cobalt(II). 3-D single diamond-like framework materials which exhibit spin canting and ferromagnetic ordering at low temperatures † journal January 2000
Crystal engineering of binary metal imidazolate and triazolate frameworks journal January 2006
Exceptional chemical and thermal stability of zeolitic imidazolate frameworks journal June 2006
Synthesis and Characterization of Zirconogermanates journal September 2003
Computation of Aromatic C3N4 Networks and Synthesis of the Molecular Precursor N(C3N3)3Cl6 journal September 2003
Three-periodic nets and tilings: regular and quasiregular nets journal December 2002
Three-periodic nets and tilings: semiregular nets journal October 2003
[Cd16In64S134]44-: 31-Å Tetrahedron with a Large Cavity journal April 2003
Design of Frameworks with Mixed Triangular and Octahedral Building Blocks Exemplified by the Structure of [Zn4O(TCA)2] Having the Pyrite Topology journal August 2003
Layered Structures Constructed from New Linkages of Ge7(O,OH,F)19 Clusters journal February 2003
Design of New Materials for Methane Storage journal March 2004
Hydrogen Sorption in Functionalized Metal−Organic Frameworks
  • Rowsell, Jesse L. C.; Millward, Andrew R.; Park, Kyo Sung
  • Journal of the American Chemical Society, Vol. 126, Issue 18, p. 5666-5667 https://doi.org/10.1021/ja049408c
journal May 2004
Metal–organic frameworks: a new class of porous materials journal August 2004
Rod Packings and Metal−Organic Frameworks Constructed from Rod-Shaped Secondary Building Units journal February 2005
Two Polymorphs of Cobalt(II) Imidazolate Polymers Synthesized Solvothermally by Using One Organic Template N , N -Dimethylacetamide journal July 2004
A New Route to Supramolecular Isomers via Molecular Templating:  Nanosized Molecular Polygons of Copper(I) 2-Methylimidazolates journal October 2004
[Co5(im)10⋅2 MB]∞: A Metal-Organic Open-Framework with Zeolite-Like Topology journal April 2002
van der Waals Volumes and Radii journal March 1964
Positions of cations and molecules in zeolites with the faujasite-type framework I. Dehydrated Ca-exchanged faujasite journal August 1968
Infinite polymeric frameworks consisting of three dimensionally linked rod-like segments journal July 1989
Building Molecular Crystals journal July 1992
Turning Down the Heat: Design and Mechanism in Solid-State Synthesis journal March 1993
Nanoporous Molecular Sandwiches: Pillared Two-Dimensional Hydrogen-Bonded Networks with Adjustable Porosity journal April 1997
Aerogels—Airy Materials: Chemistry, Structure, and Properties journal February 1998
Organic-functionalized molecular sieves as shape-selective catalysts journal May 1998
Self-Assembly of [2]Catenanes Containing Metals in Their Backbones journal January 1999
Design and synthesis of an exceptionally stable and highly porous metal-organic framework journal November 1999
Variable Pore Size, Variable Chemical Functionality, and an Example of Reactivity within Porous Phenylacetylene Silver Salts journal September 1999
Highly Porous and Stable Metal−Organic Frameworks: Structure Design and Sorption Properties journal February 2000
A New, Methane Adsorbent, Porous Coordination Polymer [{CuSiF6(4,4′-bipyridine)2}n] journal June 2000
Design of Solids from Molecular Building Blocks: Golden Opportunities for Solid State Chemistry journal June 2000
Large Free Volume in Maximally Interpenetrating Networks:  The Role of Secondary Building Units Exemplified by Tb2(ADB)3[(CH3)2SO]4·16[(CH3)2SO]1 journal May 2000
Modular Chemistry: Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal−Organic Carboxylate Frameworks journal April 2001
Assembly of Metal−Organic Frameworks from Large Organic and Inorganic Secondary Building Units:  New Examples and Simplifying Principles for Complex Structures journal August 2001
Nickel(II) Phosphate VSB-5: A Magnetic Nanoporous Hydrogenation Catalyst with 24-Ring Tunnels journal August 2001
Coordination of Deprotonated Saccharin in Copper(II) Complexes. Structural Role of the Saccharinate Directed by the Ancillary N-heterocyclic Ligands journal January 2002
Growth of Pure Ni(OH)2 Single Crystals from Solution — Control of the Crystal Size journal January 2002
Lithium Insertion into Titanium Phosphates, Silicates, and Sulfates journal December 2002
Infinite Secondary Building Units and Forbidden Catenation in Metal-Organic Frameworks journal January 2002
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage journal January 2002
Surface Area Evaluation of Coordination Polymers Having Rectangular Micropores journal March 2002
Syntheses and Characterization of Microporous Coordination Polymers with Open Frameworks journal February 2002
Hydrogen Storage in Microporous Metal-Organic Frameworks journal May 2003

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