High Methane Storage Capacity in Aluminum Metal-Organic Frameworks

Gándara, Felipe; Furukawa, Hiroyasu; Lee, Seungkyu; Yaghi, Omar M.

doi:10.1021/ja501606h

Title: High Methane Storage Capacity in Aluminum Metal-Organic Frameworks

Journal Article · Thu Aug 14 00:00:00 EDT 2014 · J. Am. Chem. Soc.

DOI:https://doi.org/10.1021/ja501606h· OSTI ID:1128588

Gándara, Felipe; Furukawa, Hiroyasu; Lee, Seungkyu; Yaghi, Omar M. ^[1]

The use of porous materials to store natural gas in vehicles requires large amounts of methane per unit of volume. Here we report the synthesis, crystal structure and methane adsorption properties of two new aluminum metal–organic frameworks, MOF-519 and MOF-520. Both materials exhibit permanent porosity and high methane volumetric storage capacity: MOF-519 has a volumetric capacity of 200 and 279 cm³ cm^–3 at 298 K and 35 and 80 bar, respectively, and MOF-520 has a volumetric capacity of 162 and 231 cm³ cm^–3 under the same conditions. Furthermore, MOF-519 exhibits an exceptional working capacity, being able to deliver a large amount of methane at pressures between 5 and 35 bar, 151 cm³ cm^–3, and between 5 and 80 bar, 230 cm³ cm^–3.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: FOREIGNDOE - BASIC ENERGY SCIENCES

OSTI ID:: 1128588

Journal Information:: J. Am. Chem. Soc., Vol. 136, Issue (14) ; 04, 2014

Country of Publication:: United States

Language:: ENGLISH

References (36)

The Chemistry and Applications of Metal-Organic Frameworks Furukawa, H.; Cordova, K. E.; O'Keeffe, M. Science, Vol. 341, Issue 6149, p. 1230444-1230444 https://doi.org/10.1126/science.1230444	journal	August 2013
Metal–Organic Frameworks and Self-Assembled Supramolecular Coordination Complexes: Comparing and Contrasting the Design, Synthesis, and Functionality of Metal–Organic Materials Cook, Timothy R.; Zheng, Yao-Rong; Stang, Peter J. Chemical Reviews, Vol. 113, Issue 1 https://doi.org/10.1021/cr3002824	journal	November 2012
BioMOFs: Metal-Organic Frameworks for Biological and Medical Applications McKinlay, Alistair C.; Morris, Russell E.; Horcajada, Patricia Angewandte Chemie International Edition, Vol. 49, Issue 36, p. 6260-6266 https://doi.org/10.1002/anie.201000048	journal	July 2010
Metal–organic frameworks—prospective industrial applications Mueller, U.; Schubert, M.; Teich, F. J. Mater. Chem., Vol. 16, Issue 7 https://doi.org/10.1039/B511962F	journal	January 2006
Phosphonate and sulfonate metal organic frameworks Shimizu, George K. H.; Vaidhyanathan, Ramanathan; Taylor, Jared M. Chemical Society Reviews, Vol. 38, Issue 5 https://doi.org/10.1039/b802423p	journal	January 2009
Engineering Metal Organic Frameworks for Heterogeneous Catalysis Corma, A.; García, H.; Llabrés i Xamena, F. X. Chemical Reviews, Vol. 110, Issue 8, p. 4606-4655 https://doi.org/10.1021/cr9003924	journal	August 2010
Metal-Organic Frameworks: A Rapidly Growing Class of Versatile Nanoporous Materials Meek, Scott T.; Greathouse, Jeffery A.; Allendorf, Mark D. Advanced Materials, Vol. 23, Issue 2 https://doi.org/10.1002/adma.201002854	journal	October 2010
Functional Porous Coordination Polymers Kitagawa, Susumu; Kitaura, Ryo; Noro, Shin-ichiro Angewandte Chemie International Edition, Vol. 43, Issue 18, p. 2334-2375 https://doi.org/10.1002/anie.200300610	journal	April 2004
Hydrogen storage in metal–organic frameworks Murray, Leslie J.; Dincă, Mircea; Long, Jeffrey R. Chemical Society Reviews, Vol. 38, Issue 5, p. 1294-1314 https://doi.org/10.1039/b802256a	journal	January 2009
Hydrogen Storage in Metal–Organic Frameworks Suh, Myunghyun Paik; Park, Hye Jeong; Prasad, Thazhe Kootteri Chemical Reviews, Vol. 112, Issue 2, p. 782-835 https://doi.org/10.1021/cr200274s	journal	September 2011
Dramatic Tuning of Carbon Dioxide Uptake via Metal Substitution in a Coordination Polymer with Cylindrical Pores Caskey, Stephen R.; Wong-Foy, Antek G.; Matzger, Adam J. Journal of the American Chemical Society, Vol. 130, Issue 33, p. 10870-10871 https://doi.org/10.1021/ja8036096	journal	August 2008
High H2 Adsorption by Coordination-Framework Materials Lin, Xiang; Jia, Junhua; Zhao, Xuebo Angewandte Chemie International Edition, Vol. 45, Issue 44 https://doi.org/10.1002/anie.200601991	journal	November 2006
A partially interpenetrated metal–organic framework for selective hysteretic sorption of carbon dioxide Yang, Sihai; Lin, Xiang; Lewis, William Nature Materials, Vol. 11, Issue 8 https://doi.org/10.1038/nmat3343	journal	June 2012
Switching of myosin-V motion between the lever-arm swing and Brownian search-and-catch Fujita, Keisuke; Iwaki, Mitsuhiro; Iwane, Atsuko H. Nature Communications, Vol. 3, Issue 1 https://doi.org/10.1038/ncomms1934	journal	January 2012
Systematic modulation and enhancement of CO2 : N2 selectivity and water stability in an isoreticular series of bio-MOF-11 analogues Li, Tao; Chen, De-Li; Sullivan, Jeanne E. Chemical Science, Vol. 4, Issue 4 https://doi.org/10.1039/c3sc22207a	journal	January 2013
A New, Methane Adsorbent, Porous Coordination Polymer [{CuSiF6(4,4′-bipyridine)2}n] Noro, Shin-ichiro; Kitagawa, Susumu; Kondo, Mitsuru Angewandte Chemie International Edition, Vol. 39, Issue 12, p. 2081-2084 https://doi.org/10.1002/1521-3773(20000616)39:12<2081::AID-ANIE2081>3.0.CO;2-A	journal	June 2000
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage Eddaoudi, Mohamed; Kim, Jaheon; Rosi, Nathaniel Science, Vol. 295, Issue 5554, p. 469-472 https://doi.org/10.1126/science.1067208	journal	January 2002
Methane storage in advanced porous materials Makal, Trevor A.; Li, Jian-Rong; Lu, Weigang Chemical Society Reviews, Vol. 41, Issue 23 https://doi.org/10.1039/c2cs35251f	journal	January 2012
Methane storage in metal organic frameworks Konstas, Kristina; Osl, Theresa; Yang, Yunxia Journal of Materials Chemistry, Vol. 22, Issue 33 https://doi.org/10.1039/c2jm32719h	journal	January 2012
A highly porous metal–organic framework, constructed from a cuboctahedral super-molecular building block, with exceptionally high methane uptake Stoeck, Ulrich; Krause, Simon; Bon, Volodymyr Chemical Communications, Vol. 48, Issue 88 https://doi.org/10.1039/c2cc34840c	journal	January 2012
A Chemically Functionalizable Nanoporous Material [Cu₃(TMA)₂(H₂O)₃]_n Chui, Stephen S.-Y.; Lo, Samuel M.-F.; Charmant, Jonathan P. H. Science, Vol. 283, Issue 5405, p. 1148-1150 https://doi.org/10.1126/science.283.5405.1148	journal	February 1999
Evaluating metal–organic frameworks for natural gas storage Mason, Jarad A.; Veenstra, Mike; Long, Jeffrey R. Chemical Science, Vol. 5, Issue 1, p. 32-51 https://doi.org/10.1039/C3SC52633J	journal	January 2014
Methane Storage in Metal–Organic Frameworks: Current Records, Surprise Findings, and Challenges Peng, Yang; Krungleviciute, Vaiva; Eryazici, Ibrahim Journal of the American Chemical Society, Vol. 135, Issue 32, p. 11887-11894 https://doi.org/10.1021/ja4045289	journal	July 2013
Rod Packings and Metal−Organic Frameworks Constructed from Rod-Shaped Secondary Building Units Rosi, Nathaniel L.; Kim, Jaheon; Eddaoudi, Mohamed Journal of the American Chemical Society, Vol. 127, Issue 5, p. 1504-1518 https://doi.org/10.1021/ja045123o	journal	February 2005
Hydrogen adsorption in a nickel based coordination polymer with open metal sites in the cylindrical cavities of the desolvated framework Dietzel, Pascal D. C.; Panella, Barbara; Hirscher, Michael Chemical Communications, Issue 9 https://doi.org/10.1039/b515434k	journal	January 2006
Design and synthesis of an exceptionally stable and highly porous metal-organic framework Li, Hailian; Eddaoudi, Mohamed; M., O'Keeffe Nature, Vol. 402, Issue 6759, p. 276-279 https://doi.org/10.1038/46248	journal	November 1999
Ultrahigh Porosity in Metal-Organic Frameworks Furukawa, H.; Ko, N.; Go, Y. B. Science, Vol. 329, Issue 5990, p. 424-428 https://doi.org/10.1126/science.1192160	journal	July 2010
A route to high surface area, porosity and inclusion of large molecules in crystals Chae, Hee K.; Siberio-Pérez, Diana Y.; Kim, Jaheon Nature, Vol. 427, Issue 6974, p. 523-527 https://doi.org/10.1038/nature02311	journal	February 2004
Metal-Organic Framework from an Anthracene Derivative Containing Nanoscopic Cages Exhibiting High Methane Uptake Ma, Shengqian; Sun, Daofeng; Simmons, Jason M. Journal of the American Chemical Society, Vol. 130, Issue 3 https://doi.org/10.1021/ja0771639	journal	January 2008
A Rationale for the Large Breathing of the Porous Aluminum Terephthalate (MIL-53) Upon Hydration Loiseau, Thierry; Serre, Christian; Huguenard, Clarisse Chemistry - A European Journal, Vol. 10, Issue 6 https://doi.org/10.1002/chem.200305413	journal	March 2004
Metal Insertion in a Microporous Metal−Organic Framework Lined with 2,2′-Bipyridine Bloch, Eric D.; Britt, David; Lee, Chain Journal of the American Chemical Society, Vol. 132, Issue 41, p. 14382-14384 https://doi.org/10.1021/ja106935d	journal	October 2010
The Magnetic Möbius Strip: Synthesis, Structure, and Magnetic Studies of Odd-Numbered Antiferromagnetically Coupled Wheels Cador, Olivier; Gatteschi, Dante; Sessoli, Roberta Angewandte Chemie International Edition, Vol. 43, Issue 39 https://doi.org/10.1002/anie.200460211	journal	October 2004
Magnetic Anisotropy of the Antiferromagnetic Ring [Cr8F8Piv16] van Slageren, Joris; Sessoli, Roberta; Gatteschi, Dante Chemistry - A European Journal, Vol. 8, Issue 1 https://doi.org/10.1002/1521-3765(20020104)8:1<277::AID-CHEM277>3.0.CO;2-D	journal	January 2002
[Al ₄ (OH) ₂ (OCH ₃ ) ₄ (H ₂ N-bdc) ₃ ]⋅ x H ₂ O: A 12-Connected Porous Metal-Organic Framework with an Unprecedented Aluminum-Containing Brick Ahnfeldt, Tim; Guillou, Nathalie; Gunzelmann, Daniel Angewandte Chemie International Edition, Vol. 48, Issue 28 https://doi.org/10.1002/anie.200901409	journal	June 2009
Deconstructing the Crystal Structures of Metal–Organic Frameworks and Related Materials into Their Underlying Nets O’Keeffe, Michael; Yaghi, Omar M. Chemical Reviews, Vol. 112, Issue 2, p. 675-702 https://doi.org/10.1021/cr200205j	journal	September 2011
Synthesis and Hydrogen Storage Properties of Be ₁₂ (OH) ₁₂ (1,3,5-benzenetribenzoate) ₄ Sumida, Kenji; Hill, Matthew R.; Horike, Satoshi Journal of the American Chemical Society, Vol. 131, Issue 42 https://doi.org/10.1021/ja9072707	journal	October 2009

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Three Cd( ii ) coordination polymers constructed from a series of multidentate ligands derived from cyclotriphosphazene: synthesis, structures and luminescence properties Chen, Xi; Dong, Hong-Xia; Peng, Hua-Nan CrystEngComm, Vol. 20, Issue 25 https://doi.org/10.1039/c8ce00537k	journal	January 2018
Novel ferrocene-based nanoporous organic polymers for clean energy application Liu, Qingquan; Tang, Zhe; Wu, Minda RSC Advances, Vol. 5, Issue 12 https://doi.org/10.1039/c4ra12834f	journal	January 2015
Improved luminescence properties by the self-assembly of lanthanide compounds with a 1-D chain structure for the sensing of CH ₃ COOH and toxic HS ⁻ anions Xu, Yuan-Yi; Chen, Peng; Gao, Ting CrystEngComm, Vol. 21, Issue 39 https://doi.org/10.1039/c9ce01077g	journal	January 2019
The role of metal–organic frameworks in a carbon-neutral energy cycle Schoedel, Alexander; Ji, Zhe; Yaghi, Omar M. Nature Energy, Vol. 1, Issue 4 https://doi.org/10.1038/nenergy.2016.34	journal	April 2016
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Five transition metal coordination polymers driven by a semirigid trifunctional nicotinic acid ligand: selective adsorption and magnetic properties Bai, Nannan; Gao, Ruicheng; Wang, Haihua CrystEngComm, Vol. 20, Issue 38 https://doi.org/10.1039/c8ce01003j	journal	January 2018
Natural gas upgrading using a fluorinated MOF with tuned H2S and CO2 adsorption selectivity Belmabkhout, Youssef; Bhatt, Prashant M.; Adil, Karim Nature Energy, Vol. 3, Issue 12 https://doi.org/10.1038/s41560-018-0267-0	journal	October 2018
Luminescent zinc metal–organic framework (ZIF-90) for sensing metal ions, anions and small molecules Liu, Chang; Yan, Bing Photochemical & Photobiological Sciences, Vol. 14, Issue 9 https://doi.org/10.1039/c5pp00107b	journal	January 2015
Computational design of tetrazolate-based metal–organic frameworks for CH ₄ storage Wu, Xuanjun; Peng, Liang; Xiang, Sichen Physical Chemistry Chemical Physics, Vol. 20, Issue 48 https://doi.org/10.1039/c8cp05724a	journal	January 2018
Fine Tuning of MOF-505 Analogues To Reduce Low-Pressure Methane Uptake and Enhance Methane Working Capacity Zhang, Mingxing; Zhou, Wei; Pham, Tony Angewandte Chemie International Edition, Vol. 56, Issue 38 https://doi.org/10.1002/anie.201704974	journal	August 2017
In situ synthesis and structural characterization of a series of acylhydrazidate-extended Ln ³⁺ and Zn ²⁺ coordination polymers Wang, Yan-Ning; Yu, Jie-Hui; Xu, Ji-Qing Inorg. Chem. Front., Vol. 1, Issue 9 https://doi.org/10.1039/c4qi00100a	journal	January 2014
A metal–organic framework with immobilized Ag( i ) for highly efficient desulfurization of liquid fuels Huang, Minhui; Chang, Ganggang; Su, Ye Chemical Communications, Vol. 51, Issue 61 https://doi.org/10.1039/c5cc03648h	journal	January 2015
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Water adsorption and proton conduction of a cobalt( ii ) complex assembled by triazine-based polycarboxylate Feng, Lu; Zhou, Min; Ye, Fan Dalton Transactions, Vol. 48, Issue 40 https://doi.org/10.1039/c9dt03038g	journal	January 2019
Selective carbon dioxide adsorption by mixed-ligand porous coordination polymers Bhattacharya, Biswajit; Ghoshal, Debajyoti CrystEngComm, Vol. 17, Issue 44 https://doi.org/10.1039/c5ce01246e	journal	January 2015
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A Heterobimetallic 2-D Coordination Polymer [Na2(Cu2I2(2pyCOO)4)(H2O)4]n (2pyCOO−=picolinate) within a 3-D Supramolecular Architecture Kamari, Anis; Haque, Rosenani; Razali, Mohd Crystals, Vol. 6, Issue 10 https://doi.org/10.3390/cryst6100096	journal	October 2016
[NaCu(2,4-HPdc)(2,4-Pdc)] Mixed Metal-Organic Framework as a Heterogeneous Catalyst: A Mixed Metal-Organic Framework as a Heterogeneous Catalyst Larrea, Edurne S.; Fernández de Luis, Roberto; Orive, Joseba European Journal of Inorganic Chemistry, Vol. 2015, Issue 28 https://doi.org/10.1002/ejic.201500431	journal	September 2015
An efficient approach to modulate the coordination number of yttrium ions for diverse network formation Park, Jiwon; Koo, Jin Young; Choi, Hee Cheul CrystEngComm, Vol. 21, Issue 28 https://doi.org/10.1039/c9ce00676a	journal	January 2019
Functional materials discovery using energy–structure–function maps Pulido, Angeles; Chen, Linjiang; Kaczorowski, Tomasz Nature, Vol. 543, Issue 7647 https://doi.org/10.1038/nature21419	journal	March 2017
Unraveling Structure and Dynamics in Porous Frameworks via Advanced In Situ Characterization Techniques Bon, Volodymyr; Brunner, Eike; Pöppl, Andreas Advanced Functional Materials, Vol. 30, Issue 41 https://doi.org/10.1002/adfm.201907847	journal	January 2020
Water-induced phase transformation of a Cu ^II coordination framework with pyridine-2,5-dicarboxylate and di-2-pyridyl ketone: synchrotron radiation analysis Llano-Tomé, Francisco; Bazán, Begoña; Urtiaga, M. Karmele CrystEngComm, Vol. 17, Issue 33 https://doi.org/10.1039/c5ce01033k	journal	January 2015
Two new cadmium metal-organic frameworks based on a mixed-donor ligand Wang, Xiaofang; Song, Qingshan; Pan, Ying Chemical Research in Chinese Universities, Vol. 32, Issue 4 https://doi.org/10.1007/s40242-016-5489-8	journal	May 2016
Benzene adsorption on synthesized and commercial metal–organic frameworks Gwardiak, Sylwia; Szczęśniak, Barbara; Choma, Jerzy Journal of Porous Materials, Vol. 26, Issue 3 https://doi.org/10.1007/s10934-018-0678-0	journal	September 2018
Why Design Matters: From Decorated Metal Oxide Clusters to Functional Metal–Organic Frameworks Schoedel, Alexander; Rajeh, Sahar Topics in Current Chemistry, Vol. 378, Issue 1 https://doi.org/10.1007/s41061-020-0281-0	journal	February 2020
Tuning the Gate‐Opening Pressure in a Switching pcu Coordination Network, X‐pcu‐5‐Zn, by Pillar‐Ligand Substitution Zhu, Ai‐Xin; Yang, Qing‐Yuan; Mukherjee, Soumya Angewandte Chemie, Vol. 131, Issue 50 https://doi.org/10.1002/ange.201909977	journal	October 2019
A (3,6)-connected metal–organic framework with high CH ₄ binding affinity and uptake capacity Liu, Huiyan; Wang, Qian; Zhang, Mingxing CrystEngComm, Vol. 17, Issue 26 https://doi.org/10.1039/c5ce00612k	journal	January 2015
A Versatile Al ^III -Based Metal-Organic Framework with High Physicochemical Stability Wang, Zhuo-Wei; Chen, Min; Liu, Chun-Sen Chemistry - A European Journal, Vol. 21, Issue 48 https://doi.org/10.1002/chem.201502615	journal	October 2015
Synthesis of sulfamic acid supported on Cr-MIL-101 as a heterogeneous acid catalyst and efficient adsorbent for methyl orange dye El-Hakam, Sohier A.; Samra, Salem E.; El-Dafrawy, Shady M. RSC Advances, Vol. 8, Issue 37 https://doi.org/10.1039/c8ra02941e	journal	January 2018
Tailoring the pore geometry and chemistry in microporous metal–organic frameworks for high methane storage working capacity Shao, Kai; Pei, Jiyan; Wang, Jia-Xin Chemical Communications, Vol. 55, Issue 76 https://doi.org/10.1039/c9cc06239d	journal	January 2019
Coordinative alignment of molecules in chiral metal-organic frameworks Lee, S.; Kapustin, E. A.; Yaghi, O. M. Science, Vol. 353, Issue 6301 https://doi.org/10.1126/science.aaf9135	journal	August 2016
Assembly of metal–organic polyhedra into highly porous frameworks for ethene delivery Stoeck, Ulrich; Senkovska, Irena; Bon, Volodymyr Chemical Communications, Vol. 51, Issue 6 https://doi.org/10.1039/c4cc07920e	journal	January 2015
Tuning fluorocarbon adsorption in new isoreticular porous coordination frameworks for heat transformation applications Lin, Rui-Biao; Li, Tai-Yang; Zhou, Hao-Long Chemical Science, Vol. 6, Issue 4 https://doi.org/10.1039/c4sc03985h	journal	January 2015
A water-stable lanthanide-organic framework as a recyclable luminescent probe for detecting pollutant phosphorus anions Xu, Hang; Cao, Chun-Shuai; Zhao, Bin Chemical Communications, Vol. 51, Issue 51 https://doi.org/10.1039/c5cc02596f	journal	January 2015
A superstable 3p-block metal–organic framework platform towards prominent CO ₂ and C1/C2-hydrocarbon uptake and separation performance and strong Lewis acid catalysis for CO ₂ fixation Zhang, Jian-Wei; Ji, Wen-Juan; Hu, Man-Cheng Inorganic Chemistry Frontiers, Vol. 6, Issue 3 https://doi.org/10.1039/c8qi01396a	journal	January 2019
The guest-dependent thermal response of the flexible MOF Zn ₂ (BDC) ₂ (DABCO) Kim, Yonghwi; Haldar, Ritesh; Kim, Hyunuk Dalton Trans., Vol. 45, Issue 10 https://doi.org/10.1039/c5dt03710g	journal	January 2016
Cu ^II –PDC-bpe frameworks (PDC = 2,5-pyridinedicarboxylate, bpe = 1,2-di(4-pyridyl)ethylene): mapping of herringbone-type structures Llano-Tomé, Francisco; Bazán, Begoña; Urtiaga, Miren-Karmele CrystEngComm, Vol. 16, Issue 37 https://doi.org/10.1039/c4ce00989d	journal	January 2014
The electrochemical properties, nitrogen adsorption, and photocatalytic activities of three 3D metal–organic frameworks bearing the rigid terphenyl tetracarboxylates ligands Mu, Bao; Li, Chang-Xia; Song, Ming CrystEngComm, Vol. 18, Issue 17 https://doi.org/10.1039/c6ce00087h	journal	January 2016
Isotherms of individual pores by gas adsorption crystallography Cho, Hae Sung; Yang, Jingjing; Gong, Xuan Nature Chemistry, Vol. 11, Issue 6 https://doi.org/10.1038/s41557-019-0257-2	journal	May 2019
Template-Directed Synthesis of Porous and Protective Core-Shell Bionanoparticles Li, Shaobo; Dharmarwardana, Madushani; Welch, Raymond P. Angewandte Chemie, Vol. 128, Issue 36 https://doi.org/10.1002/ange.201604879	journal	August 2016
Fine Tuning of MOF-505 Analogues To Reduce Low-Pressure Methane Uptake and Enhance Methane Working Capacity Zhang, Mingxing; Zhou, Wei; Pham, Tony Angewandte Chemie, Vol. 129, Issue 38 https://doi.org/10.1002/ange.201704974	journal	August 2017
A Metal-Organic Framework with a Pore Size/Shape Suitable for Strong Binding and Close Packing of Methane Lin, Jiao-Min; He, Chun-Ting; Liu, Yan Angewandte Chemie International Edition, Vol. 55, Issue 15 https://doi.org/10.1002/anie.201511006	journal	March 2016
Molecular Retrofitting Adapts a Metal–Organic Framework to Extreme Pressure Kapustin, Eugene A.; Lee, Seungkyu; Alshammari, Ahmad S. ACS Central Science, Vol. 3, Issue 6 https://doi.org/10.1021/acscentsci.7b00169	journal	June 2017
Unexpected Nonresponsive Behavior of a Flexible Metal-Organic Framework under Conformational Changes of a Photoresponsive Guest Molecule Das, Dipanwita; Agarkar, Harshawardhan ACS Omega, Vol. 3, Issue 7 https://doi.org/10.1021/acsomega.8b00903	journal	July 2018
Characterization of Adsorption Enthalpy of Novel Water-Stable Zeolites and Metal-Organic Frameworks Kim, Hyunho; Cho, H. Jeremy; Narayanan, Shankar Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep19097	journal	January 2016
The Impact of Post-Synthetic Linker Functionalization of MOFs on Methane Storage: The Role of Defects Szilágyi, Petra Ágota; Serra-Crespo, Pablo; Gascon, Jorge Frontiers in Energy Research, Vol. 4 https://doi.org/10.3389/fenrg.2016.00009	journal	March 2016
Implementing Metal-Organic Frameworks for Natural Gas Storage Mahmoud, Eyas; Ali, Labeeb; El Sayah, Asmaa Crystals, Vol. 9, Issue 8 https://doi.org/10.3390/cryst9080406	journal	August 2019
X-Ray Diffraction under Extreme Conditions at the Advanced Light Source Stan, Camelia; Beavers, Christine; Kunz, Martin Quantum Beam Science, Vol. 2, Issue 1 https://doi.org/10.3390/qubs2010004	journal	January 2018

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