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Title: Carbonation of metal silicates for long-term CO2 sequestration

Patent ·
OSTI ID:1128516

In a preferred embodiment, the invention relates to a process of sequestering carbon dioxide. The process comprises the steps of: (a) reacting a metal silicate with a caustic alkali-metal hydroxide to produce a hydroxide of the metal formerly contained in the silicate; (b) reacting carbon dioxide with at least one of a caustic alkali-metal hydroxide and an alkali-metal silicate to produce at least one of an alkali-metal carbonate and an alkali-metal bicarbonate; and (c) reacting the metal hydroxide product of step (a) with at least one of the alkali-metal carbonate and the alkali-metal bicarbonate produced in step (b) to produce a carbonate of the metal formerly contained in the metal silicate of step (a).

Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC05-00OR22725
Assignee:
UT-Battelle, LLC (Oak Ridge, TN); University of Tennessee Research Foundation (Knoxville, TN); Virginia Museum of Natural History (Martinsville, VA)
Patent Number(s):
8,673,256
Application Number:
13/361,215
OSTI ID:
1128516
Country of Publication:
United States
Language:
English

References (20)

Process of separating the constituents of mineral silicates patent May 1924
Process for the manufacture of magnesium products patent March 1953
Method for continuous digestion of aluminous ore patent December 1963
Process for beneficiation of titaniferous ores patent October 1972
Process for producing hydrates of calcium-magnesium silicates patent November 1973
Recovery of magnesium from magnesium silicates patent November 1978
Production of magnesium oxide from magnesium silicates by basic extraction of silica patent October 1984
Carbonation of metal silicates for long-term CO2 sequestration patent February 2012
CO2 disposal by means of silicates journal June 1990
Progress on binding CO2 in mineral substrates journal January 1997
A Program to Develop CO2 Sequestration Via Mineral Carbonation book January 2003
Carbon dioxide sequestration as stable carbonate minerals – environmental barriers journal August 2001
Mitigation of CO2 by Chemical Conversion:  Plausible Chemical Reactions and Promising Products journal March 1996
Magnesium Hydroxide Dehydroxylation/Carbonation Reaction Processes: Implications for Carbon Dioxide Mineral Sequestration journal April 2002
Feasibility of CO2 Fixation via Artificial Rock Weathering journal September 2001
Mineral Carbonation and ZECA book January 2003
A new CO2 disposal process via artificial weathering of calcium silicate accelerated by acetic acid journal April 2001
Absorption and fixation of carbon dioxide by rock weathering journal January 1997
Carbon dioxide disposal in carbonate minerals journal January 1995
A Guide to CO2 Sequestration journal June 2003

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