Electrically conducting porphyrin and porphyrin-fullerene electropolymers
Patent
·
OSTI ID:1126698
Compounds with aryl ring(s) at porphyrin meso position(s) bearing an amino group in position 4 relative to the porphyrin macrocycle, and at least one unsubstituted 5 (hydrogen-bearing) meso position with the 10-, 15-, and/or 20-relationship to the aryl ring bearing the amino group, and metal complexes thereof, feature broad spectral absorption throughout the visible region. These compounds are electropolymerized to form electrically conducting porphyrin and porphyrin-fullerene polymers that are useful in photovoltaic applications. The structure of one such electrically conducting porphyrin polymer is shown below. ##STR00001##
- Research Organization:
- Arizona State University, Scottsdale, AZ, USA
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- FG02-03ER15393
- Assignee:
- Arizona Board of Regents for and on behalf of Arizona State University (Scottsdale, AZ)
- Patent Number(s):
- 8,669,359
- Application Number:
- 12/552,187
- OSTI ID:
- 1126698
- Country of Publication:
- United States
- Language:
- English
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