skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: System and process for capture of H.sub.2S from gaseous process streams and process for regeneration of the capture agent

Patent ·
OSTI ID:1124999

A system and process are disclosed for selective removal and recovery of H.sub.2S from a gaseous volume, e.g., from natural gas. Anhydrous organic, sorbents chemically capture H.sub.2S gas to form hydrosulfide salts. Regeneration of the capture solvent involves addition of an anti-solvent that releases the captured H.sub.2S gas from the capture sorbent. The capture sorbent and anti-solvent are reactivated for reuse, e.g., by simple distillation.

Research Organization:
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC05-76RL01830
Assignee:
Battelle Memorial Institute (Richland, WA)
Patent Number(s):
8,652,237
Application Number:
12/972,125
OSTI ID:
1124999
Resource Relation:
Patent File Date: 2010 Dec 17
Country of Publication:
United States
Language:
English

References (23)

Method of removing gaseous sulfides from gaseous mixtures patent October 1973
Process of scrubbing fuel synthesis gases to remove acid gases and organic sulfur compounds patent January 1979
Using solvents for acidic gas removal patent December 1980
Composition for removing sulfides from industrial gas patent March 1987
Removing hydrogen sulphide from a gas mixture patent September 1990
Methods for regenerating a sulfur scavenging compound from a product of a sulfur scavenging reaction patent September 1994
Continuous bromination process and products thereof patent April 1998
Methods and systems for deacidizing gaseous mixtures patent May 2010
Process for recovering sulfur while sponging light hydrocarbons from hydrodesulfurization hydrogen recycle streams patent-application March 2003
High CO2 to Amine Adsorption Capacity CO2 Scrubbing Processes patent-application March 2012
One-component, switchable ionic liquids derived from siloxylated amines journal January 2009
Single component, reversible ionic liquids for energy applications journal June 2010
The reaction of trimethylamine in liquid hydrogen sulphide: an electrical conductivity study journal June 1983
A reversible zwitterionic SO2-binding organic liquid journal January 2010
Reversible zwitterionic liquids, the reaction of alkanol guanidines, alkanol amidines, and diamines with CO2 journal January 2010
Reversible Uptake of COS, CS2, and SO2: Ionic Liquids with O-Alkylxanthate, O-Alkylthiocarbonyl, and O-Alkylsulfite Anions journal August 2009
Green chemistry: Reversible nonpolar-to-polar solvent journal August 2005
Solubility of Methane in Methyldiethanolamine journal July 2006
IR spectra of H2S isolated in free-standing crystals of Kr and Xe journal August 1998
Reactions of carbon dioxide and hydrogen sulfide with some alkanolamines journal January 1987
Strong Hydrogen Bonds. III. Hydrogen Sulfide-Hydrosulfide Anion Interactions journal December 1966
Switchable Solvents Consisting of Amidine/Alcohol or Guanidine/Alcohol Mixtures journal February 2008
Selective H2S Removal by Nonaqueous Methyldiethanolamine Solutions in an Experimental Apparatus journal June 2002

Cited By (2)