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Title: Molecular quantum magnetism in LiZn2Mo3O8

Inelastic neutron scattering for temperatures below 30 K from a powder of LiZn2Mo3O8 demonstrates this triangular-lattice antiferromagnet hosts collective magnetic excitations from spin 1/2 Mo3O13 molecules. Apparently gapless ( \Delta < 0.2 meV) and extending at least up to 2.5 meV, the low energy magnetic scattering cross section is surprisingly broad in momentum space and involves one third of the spins present above 100 K. The data are compatible with the presence of valencebonds involving nearest-neighbor and next-nearest-neighbor spins forming a disordered or dynamic state.
 [1] ;  [1] ;  [1] ;  [1] ;  [2] ;  [3] ;  [1] ;  [3]
  1. Johns Hopkins University
  2. NCNR and University of Maryland
  3. ORNL
Publication Date:
OSTI Identifier:
DOE Contract Number:
Resource Type:
Journal Article
Resource Relation:
Journal Name: Physical Review Letters; Journal Volume: 112; Journal Issue: 2
Research Org:
Oak Ridge National Laboratory (ORNL); Spallation Neutron Source
Sponsoring Org:
SC USDOE - Office of Science (SC)
Country of Publication:
United States