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Title: Purification of metal-organic framework materials

Patent ·
OSTI ID:1082493

A method of purification of a solid mixture of a metal-organic framework (MOF) material and an unwanted second material by disposing the solid mixture in a liquid separation medium having a density that lies between those of the wanted MOF material and the unwanted material, whereby the solid mixture separates by density differences into a fraction of wanted MOF material and another fraction of unwanted material.

Research Organization:
Northwestern University (Evanston, IL)
Sponsoring Organization:
USDOE
DOE Contract Number:
FG02-01ER15244
Assignee:
Northwestern University (Evanston, IL)
Patent Number(s):
8,322,534
Application Number:
12/661,771
OSTI ID:
1082493
Country of Publication:
United States
Language:
English

References (24)

A metal–organic framework material that functions as an enantioselective catalyst for olefin epoxidation journal January 2006
Strong H 2 Binding and Selective Gas Adsorption within the Microporous Coordination Solid Mg 3 (O 2 C-C 10 H 6 -CO 2 ) 3 journal July 2005
Metal-organic frameworks journal January 2003
Separating Solids: Purification of Metal-Organic Framework Materials journal July 2008
High H2 Adsorption in a Microporous Metal-Organic Framework with Open Metal Sites journal July 2005
Supermolecular Building Blocks (SBBs) for the Design and Synthesis of Highly Porous Metal-Organic Frameworks journal February 2008
Chemical Reduction of Metal−Organic Framework Materials as a Method to Enhance Gas Uptake and Binding journal August 2007
Design, Synthesis, Structure, and Gas (N2, Ar, CO2, CH4, and H2) Sorption Properties of Porous Metal-Organic Tetrahedral and Heterocuboidal Polyhedra
  • Sudik, Andrea C.; Millward, Andrew R.; Ockwig, Nathan W.
  • Journal of the American Chemical Society, Vol. 127, Issue 19, p. 7110-7118 https://doi.org/10.1021/ja042802q
journal May 2005
Metal–organic frameworks: a new class of porous materials journal August 2004
Hydrogen storage in metal–organic frameworks journal January 2007
A Homochiral Porous Metal−Organic Framework for Highly Enantioselective Heterogeneous Asymmetric Catalysis journal June 2005
Hydrogen Storage in a Microporous Metal−Organic Framework with Exposed Mn 2+ Coordination Sites journal December 2006
The Inconsistency in Adsorption Properties and Powder XRD Data of MOF-5 Is Rationalized by Framework Interpenetration and the Presence of Organic and Inorganic Species in the Nanocavities journal March 2007
Novel 2D and 3D Indium Metal-Organic Frameworks:  Topology and Catalytic Properties journal May 2005
Multifunctionality and Crystal Dynamics of a Highly Stable, Porous Metal−Organic Framework [Zn 4 O(NTB) 2 ] journal May 2005
Framework-Catenation Isomerism in Metal−Organic Frameworks and Its Impact on Hydrogen Uptake journal February 2007
Functional Porous Coordination Polymers journal April 2004
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage journal January 2002
Hydrogen Storage in the Giant-Pore Metal–Organic Frameworks MIL-100 and MIL-101 journal December 2006
Prospects for nanoporous metal-organic materials in advanced separations processes journal January 2004
Microporous Pillared Paddle-Wheel Frameworks Based on Mixed-Ligand Coordination of Zinc Ions journal July 2005
Immobilization of a Metallo Schiff Base into a Microporous Coordination Polymer journal May 2004
An Interweaving MOF with High Hydrogen Uptake journal March 2006
Synthesis and Hydrogen Sorption Properties of Carborane Based Metal−Organic Framework Materials journal October 2007

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