Solvent Extraction Separation of La3+ and Ba2+ using Imidazolium Ionic Liquids and TODGA Extractant
Journal Article
·
· Separation Science and Technology
OSTI ID:1079262
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
We investigated solvent extractions of La3+ and Ba2+ by N,N,N ,N -tetra(n-octyl)diglycolamide (TODGA) from aqueous solutions in twelve imidazolium-based ionic liquids (ILs), 1-alkyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide / bis(perfluoroethylsulfonyl)imide ([Cnmim][NTf2]/[BETI], n = 2,3, 4, 6, 8, 10). We also found that the corresponding extraction efficiencies were dependent on concentration of TODGA used, the acidity of aqueous phase, alkyl chain length on IL cation, and IL anion as well.
- Research Organization:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Organization:
- USDOE Office of Nuclear Energy (NE)
- DOE Contract Number:
- AC05-00OR22725
- OSTI ID:
- 1079262
- Journal Information:
- Separation Science and Technology, Vol. 47, Issue 14-15; ISSN 1520-5754
- Country of Publication:
- United States
- Language:
- English
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