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Title: Activity Coefficients at Infinite Dilution of Organic Compounds in Trihexyl(tetradecyl)phophonium Bis(trifluoromethylsulfonyl)imide Using Inverse Gas Chromatography

Abstract

Activity coefficients at infinite dilution of organic compounds in the ionic liquid (IL) trihexyl(tetradecyl) phosphonium bis(trifluoromethylsulfonyl)imide were determined using inverse gas chromatography at three temperatures, T ) (302.45, 322.35, and 342.45) K. Linear free energy relationship (LFER) correlations have been obtained for describing the gas-to-IL and water-to-IL partition coefficients.

Authors:
 [1];  [2];  [2];  [2];  [3];  [1]
  1. Laboratoire de Thermodynamique des Milieux Polyphases, Nancy-Universite, Nancy, France
  2. University of North Texas
  3. ORNL
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1078196
DOE Contract Number:  
DE-AC05-00OR22725
Resource Type:
Journal Article
Journal Name:
Journal of Chemical & Engineering Data
Additional Journal Information:
Journal Volume: 54; Journal Issue: 3; Journal ID: ISSN 0021--9568
Country of Publication:
United States
Language:
English

Citation Formats

Revelli, Anne-Laure, Sprunger, Laura, Gibbs, Jennifer, Acree, William, Baker, Gary A, and Mutelet, Fabrice. Activity Coefficients at Infinite Dilution of Organic Compounds in Trihexyl(tetradecyl)phophonium Bis(trifluoromethylsulfonyl)imide Using Inverse Gas Chromatography. United States: N. p., 2009. Web. doi:10.1021/je800754w.
Revelli, Anne-Laure, Sprunger, Laura, Gibbs, Jennifer, Acree, William, Baker, Gary A, & Mutelet, Fabrice. Activity Coefficients at Infinite Dilution of Organic Compounds in Trihexyl(tetradecyl)phophonium Bis(trifluoromethylsulfonyl)imide Using Inverse Gas Chromatography. United States. https://doi.org/10.1021/je800754w
Revelli, Anne-Laure, Sprunger, Laura, Gibbs, Jennifer, Acree, William, Baker, Gary A, and Mutelet, Fabrice. 2009. "Activity Coefficients at Infinite Dilution of Organic Compounds in Trihexyl(tetradecyl)phophonium Bis(trifluoromethylsulfonyl)imide Using Inverse Gas Chromatography". United States. https://doi.org/10.1021/je800754w.
@article{osti_1078196,
title = {Activity Coefficients at Infinite Dilution of Organic Compounds in Trihexyl(tetradecyl)phophonium Bis(trifluoromethylsulfonyl)imide Using Inverse Gas Chromatography},
author = {Revelli, Anne-Laure and Sprunger, Laura and Gibbs, Jennifer and Acree, William and Baker, Gary A and Mutelet, Fabrice},
abstractNote = {Activity coefficients at infinite dilution of organic compounds in the ionic liquid (IL) trihexyl(tetradecyl) phosphonium bis(trifluoromethylsulfonyl)imide were determined using inverse gas chromatography at three temperatures, T ) (302.45, 322.35, and 342.45) K. Linear free energy relationship (LFER) correlations have been obtained for describing the gas-to-IL and water-to-IL partition coefficients.},
doi = {10.1021/je800754w},
url = {https://www.osti.gov/biblio/1078196}, journal = {Journal of Chemical & Engineering Data},
issn = {0021--9568},
number = 3,
volume = 54,
place = {United States},
year = {Thu Jan 01 00:00:00 EST 2009},
month = {Thu Jan 01 00:00:00 EST 2009}
}