Surface-Induced Orientation Control of CuPc Molecules for the Epitaxial Growth of Highly Ordered Organic Crystals on Graphene

Journal Article · Tue Jan 01 00:00:00 EST 2013 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/ja3125096· OSTI ID:1068091

Xiao, Kai ^[1]; Deng, Wan ^[1]; Keum, Jong Kahk ^[1]; Yoon, Mina ^[1]; Vlassiouk, Ivan V ^[1]; Clark, Kendal W ^[1]; Li, An-Ping ^[1]; Kravchenko, Ivan I ^[1]; Gu, Gong ^[2]; Payzant, E Andrew ^[1]; Sumpter, Bobby ^[1]; Smith, Sean C ^[1]; Browning, Jim ^[1]; Geohegan, David B ^[1]

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1. ORNL
2. University of Tennessee, Knoxville (UTK)

The epitaxial growth and preferred molecular orientation of copper phthalocyanine (CuPc) molecules on graphene has been systematically investigated and compared with growth on Si substrates, demonstrating the role of surface-mediated interactions in determining molecular orientation. X-ray scattering and diffraction, scanning tunneling microscopy, scanning electron microscopy, and first-principles theoretical calculations were used to show that the nucleation, orientation and packing of CuPc molecules on films of graphene are fundamentally different compared to those grown on Si substrates. Interfacial dipole interactions induced by charge transfer between CuPc molecules and graphene are shown to epitaxially align the CuPc mole-cules in a face-on orientation in a series of ordered superstructures. At high temperatures, CuPc molecules lie flat with respect to the graphene substrate to form strip-like CuPc crystals with micron sizes containing monocrystalline grains. Such large epitaxial crystals may potentially enable bulk-like properties to improve the device properties in organic electronics, which charge transport, exciton diffusion and dissociation are currently limited by grain size effects and molecular orientation.

• Research Organization: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
• Sponsoring Organization: USDOE Office of Science (SC)
• DOE Contract Number: DE-AC05-00OR22725
• OSTI ID: 1068091
• Journal Information: Journal of the American Chemical Society, Vol. 135, Issue 9; ISSN 0002--7863
• Country of Publication: United States
• Language: English