A Straight Forward Route for the Development of Metal-Organic Frameworks Functionalized with Aromatic -OH Groups: Synthesis, Characterization, and Gas (N2, Ar, H2, CO2, CH4, NH3) Sorption Properties
- Crete
A facile and general methodology for the development of metal–organic frameworks (MOFs) functionalized with pendant, aromatic hydroxyl (-OH) groups is presented. Extensive gas-sorption studies in representative and important MOFs functionalized with free aromatic -OH groups such as the IRMOF-8 and DUT-6 (or MOF-205), denoted here as 1 and 2, revealed a high CO2/CH4 selectivity for 1 (13.6 at 273 K and 1 bar) and a high NH3 uptake of 16.4 mol kg–1 at 298 K and 1 bar for 2.
- Research Organization:
- Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
- Sponsoring Organization:
- FOREIGNUNIVERSITY
- OSTI ID:
- 1061309
- Journal Information:
- Inorganic Chemistry, Vol. 52, Issue 2; ISSN 0020-1669
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- ENGLISH
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