Designing Higher Surface Area Metal-Organic Frameworks: Are Triple Bonds Better than Phenyls?
Journal Article
·
· Journal of the American Chemical Society
We have synthesized, characterized, and computationally validated the high Brunauer-Emmett-Teller surface area and hydrogen uptake of a new, noncatenating metal-organic framework (MOF) material, NU-111. Our results imply that replacing the phenyl spacers of organic linkers with triple-bond spacers is an effective strategy for boosting molecule-accessible gravimetric surface areas of MOFs and related high-porosity materials.
- Research Organization:
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Sponsoring Organization:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office
- DOE Contract Number:
- AC36-08GO28308
- OSTI ID:
- 1050109
- Report Number(s):
- NREL/JA-5200-55919; JACSAT; TRN: US201218%%480
- Journal Information:
- Journal of the American Chemical Society, Vol. 134, Issue 24; ISSN 0002-7863
- Country of Publication:
- United States
- Language:
- English
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