Investigations into the Polymorphs and Hydration Products of UO3
This work focuses on progress in gaining a better understanding of the polymorphic nature of the UO{sub 3} and UO{sub 3}-water system; one of several important materials associated with the nuclear fuel cycle. The UO{sub 3}-water system is complex and has not been fully characterized, even though these species are common throughout the fuel cycle. For example, most production schemes for UO{sub 3} result in a mixture of up to six different polymorphic phases, and small differences in these conditions will affect phase genesis that ultimately results in measureable changes to the end product. Here we summarize our efforts to better characterize the UO{sub 3}-water system with optical techniques for the purpose of developing some predictive capability of estimating process history and utility, e.g. for polymorphic phases of unknown origin. Specifically, we have investigated three industrially relevant production pathways of UO{sub 3} and discovered a previously unknown low temperature route to {beta}-UO{sub 3}. Powder x-ray diffraction and optical spectroscopies were utilized in our characterization of the UO{sub 3}-water system. Pure phases of UO{sub 3}, its hydrolysis products and starting materials were used to establish optical spectroscopic signatures for these compounds. Preliminary aging studies were conducted on the {alpha}- and {gamma}-phases of UO{sub 3}.
- Research Organization:
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC05-76RL01830
- OSTI ID:
- 1045118
- Report Number(s):
- PNNL-SA-87572; NN2001000; TRN: US1203516
- Resource Relation:
- Conference: Chemical, Biological, Radiological, Nuclear, and Explosives (CBRNE) Sensing XIII, April 24, 2012, Baltimore, Maryland. Proceedings of the SPIE, 8358:Article No. 83581R
- Country of Publication:
- United States
- Language:
- English
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