Hydrogenation of Dislocation-Limited Heteroepitaxial Silicon Solar Cells: Preprint
Post-deposition hydrogenation by remote plasma significantly improves performance of heteroepitaxial silicon solar cells. Heteroepitaxial deposition of thin crystal silicon on sapphire for photovoltaics (PV) is an excellent model system for the study and improvement of deposition on inexpensive Al2O3-coated (100) biaxially-textured metal foils. Without hydrogenation, PV conversion efficiencies are less than 1% on our model system. Performance is limited by carrier recombination at electrically active dislocations that result from lattice mismatch, and other defects. We find that low-temperature hydrogenation at 350 degrees C is more effective than hydrogenation at 610 degrees C. In this work, we use measurements such as spectral quantum efficiency, secondary ion mass spectrometry (SIMS), and vibrational Si-H spectroscopies to understand the effects of hydrogenation on the materials and devices. Quantum efficiency increases most at red and green wavelengths, indicating hydrogenation is affecting the bulk more than the surface of the cells. SIMS shows there are 100X more hydrogen atoms in our cells than dangling bonds along dislocations. Yet, Raman spectroscopy indicates that only low temperature hydrogenation creates Si-H bonds; trapped hydrogen does not stably passivate dangling-bond recombination sites at high temperatures.
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- Resource Relation:
- Conference: Presented at the 2012 IEEE Photovoltaic Specialists Conference, 3-8 June 2012, Austin, Texas
- Research Org:
- National Renewable Energy Laboratory (NREL), Golden, CO.
- Sponsoring Org:
- USDOE Office of Energy Efficiency and Renewable Energy Solar Energy Technologies Program
- Country of Publication:
- United States
- 08 HYDROGEN; 14 SOLAR ENERGY; 36 MATERIALS SCIENCE; ATOMS; DEFECTS; DEPOSITION; DISLOCATIONS; HYDROGEN; HYDROGENATION; MASS SPECTROSCOPY; PERFORMANCE; PLASMA; QUANTUM EFFICIENCY; RAMAN SPECTROSCOPY; RECOMBINATION; SAPPHIRE; SILICON; SILICON SOLAR CELLS; WAVELENGTHS SOLAR CELLS; HETEROEPITAXY; EPITAXIAL SILICON; HYDROGEN; Solar Energy - Photovoltaics
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