X-ray Diffraction Study of Arsenopyrite at High Pressure
Abstract
The high-pressure X-ray diffraction study of a natural arsenopyrite was investigated up to 28.2 GPa using in situ angle-dispersive X-ray diffraction and a diamond anvil cell at National Synchrotron Light Source, Brookhaven National Laboratory. The 16:3:1 methanol-ethanol-water mixture was used as a pressure-transmitting medium. Pressures were measured using the ruby-fluorescence method. No phase change has been observed up to 28.2 GPa. The isothermal equation of state (EOS) was determined. The values of K{sub 0}, and K'{sub 0} refined with a third-order Birch-Murnaghan EOS are K{sub 0} = 123(9) GPa, and K'{sub 0} = 5.2(8). Furthermore, we confirm that the linear compressibilities ({beta}) along a, b and c directions of arsenopyrite is elastically isotropic ({beta}{sub a} = 6.82 x 10{sup -4}, {beta}{sub b} = 6.17 x 10{sup -4} and {beta}{sub c} = 6.57 x 10{sup -4} GPa{sup -1}).
- Authors:
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE SC OFFICE OF SCIENCE (SC)
- OSTI Identifier:
- 1042051
- Report Number(s):
- BNL-97729-2012-JA
Journal ID: ISSN 0342-1791; PCMIDU; TRN: US1202733
- DOE Contract Number:
- DE-AC02-98CH10886
- Resource Type:
- Journal Article
- Journal Name:
- Physics and Chemistry of Minerals
- Additional Journal Information:
- Journal Volume: 38; Journal Issue: 2; Journal ID: ISSN 0342-1791
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 43 PARTICLE ACCELERATORS; BNL; DIAMONDS; MIXTURES; NSLS; X-RAY DIFFRACTION
Citation Formats
Fan, D, Ma, M, Zhou, W, Wei, S, Chen, Z, and Xie, H. X-ray Diffraction Study of Arsenopyrite at High Pressure. United States: N. p., 2011.
Web. doi:10.1007/s00269-010-0386-z.
Fan, D, Ma, M, Zhou, W, Wei, S, Chen, Z, & Xie, H. X-ray Diffraction Study of Arsenopyrite at High Pressure. United States. https://doi.org/10.1007/s00269-010-0386-z
Fan, D, Ma, M, Zhou, W, Wei, S, Chen, Z, and Xie, H. 2011.
"X-ray Diffraction Study of Arsenopyrite at High Pressure". United States. https://doi.org/10.1007/s00269-010-0386-z.
@article{osti_1042051,
title = {X-ray Diffraction Study of Arsenopyrite at High Pressure},
author = {Fan, D and Ma, M and Zhou, W and Wei, S and Chen, Z and Xie, H},
abstractNote = {The high-pressure X-ray diffraction study of a natural arsenopyrite was investigated up to 28.2 GPa using in situ angle-dispersive X-ray diffraction and a diamond anvil cell at National Synchrotron Light Source, Brookhaven National Laboratory. The 16:3:1 methanol-ethanol-water mixture was used as a pressure-transmitting medium. Pressures were measured using the ruby-fluorescence method. No phase change has been observed up to 28.2 GPa. The isothermal equation of state (EOS) was determined. The values of K{sub 0}, and K'{sub 0} refined with a third-order Birch-Murnaghan EOS are K{sub 0} = 123(9) GPa, and K'{sub 0} = 5.2(8). Furthermore, we confirm that the linear compressibilities ({beta}) along a, b and c directions of arsenopyrite is elastically isotropic ({beta}{sub a} = 6.82 x 10{sup -4}, {beta}{sub b} = 6.17 x 10{sup -4} and {beta}{sub c} = 6.57 x 10{sup -4} GPa{sup -1}).},
doi = {10.1007/s00269-010-0386-z},
url = {https://www.osti.gov/biblio/1042051},
journal = {Physics and Chemistry of Minerals},
issn = {0342-1791},
number = 2,
volume = 38,
place = {United States},
year = {Sat Dec 31 00:00:00 EST 2011},
month = {Sat Dec 31 00:00:00 EST 2011}
}