A Novel Silver Molybdenum Oxyfluoride Perovskite as a Cathode Material for Lithium Batteries
Journal Article
·
· Chemistry of Materials
OSTI ID:1041113
Novel electroactive nanostructured silver molybdenum oxyfluoride (SMOF) perovskites Ag{sup 1+}{sub 3}Mo{sup 6+}(O{sub 3}F{sub 3}) have been successfully synthesized by a mechanochemical reaction. The formation of this perovskite was investigated throughout the Ag-Mo composition range with the use of either Ag{sup 1+} or Ag{sup 2+} in the form of AgF and AgF{sub 2} as the reactant, respectively. The compositional study combined with X-ray diffraction and extensive Raman investigation was utilized to determine structure and cation distribution and infer oxidation state. Finally, preliminary electrochemical characterization of the perovskites vs lithium was investigated.
- Research Organization:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Organization:
- USDOE EE OFFICE OF ENERGY EFFICIENCY & RENEWABLE ENERGY (EERE)
- DOE Contract Number:
- DE-AC02-98CH10886
- OSTI ID:
- 1041113
- Report Number(s):
- BNL-90342-2009-JA; CMATEX; R&D Project: MA-453-MAEA; VT0301010; TRN: US201211%%418
- Journal Information:
- Chemistry of Materials, Vol. 21, Issue 10; ISSN 0897-4756
- Country of Publication:
- United States
- Language:
- English
Similar Records
A Novel Silver Molybdenum Oxyfluoride Perovskite as a Cathode Material for Lithium Batteries
Silver-Intermediated Perovskite La0.9FeO3–δ toward High-Performance Cathode Catalysts for Nonaqueous Lithium–Oxygen Batteries
Synthesis of the novel perovskite-type oxyfluoride PbScO{sub 2}F under high pressure and high temperature
Journal Article
·
Thu Jan 01 00:00:00 EST 2009
· Chemistry of Materials
·
OSTI ID:1041113
+1 more
Silver-Intermediated Perovskite La0.9FeO3–δ toward High-Performance Cathode Catalysts for Nonaqueous Lithium–Oxygen Batteries
Journal Article
·
Mon Nov 11 00:00:00 EST 2019
· ACS Catalysis
·
OSTI ID:1041113
+8 more
Synthesis of the novel perovskite-type oxyfluoride PbScO{sub 2}F under high pressure and high temperature
Journal Article
·
Wed Oct 15 00:00:00 EDT 2008
· Journal of Solid State Chemistry
·
OSTI ID:1041113
+1 more