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Title: Controlling magnetoelectric coupling by nanoscale phase transformation instrain engineered bismuth ferrite

Journal Article · · Nanoscale
DOI:https://doi.org/10.1039/c2nr00039c· OSTI ID:1041088
 [1];  [2];  [3];  [1];  [4];  [2];  [2];  [5];  [4];  [6];  [2];  [1]
  1. University of Washington, Seattle
  2. ORNL
  3. Xiangtan University, Xiangtan Hunan, China
  4. National Chiao Tung University, Hsinchu, Taiwan
  5. National Cheng Kung University, Tainan, Taiwan
  6. University of New South Wales

The magnetoelectric coupling in multiferroic materials is promising for a wide range of applications, yet manipulating magnetic ordering by electric field proves elusive to obtain and difficult to control. In this paper, we explore the prospect of controlling magnetic ordering in misfit strained bismuth ferrite (BiFeO3, BFO) films, combining theoretical analysis, numerical simulations, and experimental characterizations. Electric field induced transformation from a tetragonal phase to a distorted rhombohedral one in strain engineered BFO films has been identified by thermodynamic analysis, and realized by scanning probe microscopy (SPM) experiment. By breaking the rotational symmetry of a tip-induced electric field as suggested by phase field simulation, the morphology of distorted rhombohedral variants has been delicately controlled and regulated. Such capabilities enable nanoscale control of magnetoelectric coupling in strain engineered BFO films that is difficult to achieve otherwise, as demonstrated by phase field simulations.

Research Organization:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
DE-AC05-00OR22725
OSTI ID:
1041088
Journal Information:
Nanoscale, Vol. 4, Issue 10; ISSN 2040-3364
Country of Publication:
United States
Language:
English