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Title: Thermodynamics and Transport Phenomena in High Temperature Steam Electrolysis Cells

Journal Article · · Journal of Heat Transfer
DOI:https://doi.org/10.1115/1.4005132· OSTI ID:1035587

Hydrogen can be produced from water splitting with relatively high efficiency using high temperature electrolysis. This technology makes use of solid-oxide cells, running in the electrolysis mode to produce hydrogen from steam, while consuming electricity and high temperature process heat. The overall thermal-to-hydrogen efficiency for high temperature electrolysis can be as high as 50%, which is about double the overall efficiency of conventional low-temperature electrolysis. Current large-scale hydrogen production is based almost exclusively on steam reforming of methane, a method that consumes a precious fossil fuel while emitting carbon dioxide to the atmosphere. An overview of high temperature electrolysis technology will be presented, including basic thermodynamics, experimental methods, heat and mass transfer phenomena, and computational fluid dynamics modeling.

Research Organization:
Idaho National Lab. (INL), Idaho Falls, ID (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
DE-AC07-05ID14517
OSTI ID:
1035587
Report Number(s):
INL/JOU-12-24961; JHTRAO; TRN: US201205%%154
Journal Information:
Journal of Heat Transfer, Vol. 134, Issue 3; ISSN 0022-1481
Country of Publication:
United States
Language:
English