A Highly Porous and Robust (3,3,4)-Connected Metal-Organic Framework Assembled with a 90° Bridging-Angle Embedded Octacarboxylate Ligand
Journal Article
·
· Angewandte Chemie (International Edition)
- TAM
A dicopper(II)-paddle-wheel-based metal-organic framework (PCN-80, see picture) with a rare (3,3,4)-connected topology has been synthesized by using a unique octatopic ligand featuring 90° bridging-angle dicarboxylate moieties. PCN-80 has Brunauer-Emmett-Teller (BET) and Langmuir surface areas of 3850 and 4150 m2g-1, respectively. It exhibits high gas-uptake capacity for H2 and large adsorption selectivity of CO2 over N2.
- Research Organization:
- Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
- Sponsoring Organization:
- NSFOTHERDOE - BASIC ENERGY SCIENCES
- OSTI ID:
- 1034947
- Journal Information:
- Angewandte Chemie (International Edition), Vol. 51, Issue (7) ; 02, 2012; ISSN 1433-7851
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- ENGLISH
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