Dramatically Different Conductivity Properties of Metal-Organic Framework Polymorphs of Tl(TCNQ): An Unexpected Room-Temperature Crystal-to-Crystal Phase Transition
Journal Article
·
· Angewandte Chemie (International Edition)
- TAM
Tl(TCNQ) polymorphs with very different charge-transport properties have been isolated, one of which undergoes a remarkable crystal-to-crystal phase transition to the second phase when exposed to ambient water vapor (see picture; TCNQ=tetracyanoquinodimethane).
- Research Organization:
- Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
- Sponsoring Organization:
- OTHERNSF
- OSTI ID:
- 1028997
- Journal Information:
- Angewandte Chemie (International Edition), Vol. 50, Issue (29) ; 07, 2011; ISSN 1433-7851
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- ENGLISH
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