Poly[bis(N,N-dimethylformamide-[kappa]O)([mu]4-naphthalene-1,5-disulfonato)magnesium(II)]
Journal Article
·
· Acta Crystallogr. E
- SBU
The structure of the title compound, [Mg(C{sub 10}H{sub 6}O{sub 6}S{sub 2})(C{sub 3}H{sub 7}NO){sub 2}]{sub n}, consists of MgO{sub 6} octahedra ({bar 1} symmetry) connected to naphthalene-1,5-disulfonate ligands ({bar 1} symmetry) in the equatoral plane, forming a two-dimensional network propagating parallel to (010). The coordination sphere of the Mg atom is completed by the O atoms of two N,N-dimethylformamide (DMF) molecules in the axial positions. The title compound represents the first time the naphthalene-1,5-disulfonate anion is bound directly to a Mg{sup 2+} atom. Disorder over two positions was found in the DMF molecule in a 0.518 (8):0.482 (8) ratio.
- Research Organization:
- Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
- Sponsoring Organization:
- National Science Foundation (NSF)
- OSTI ID:
- 1022257
- Journal Information:
- Acta Crystallogr. E, Vol. 66, Issue (6) ; 06, 2010; ISSN 1600-5368
- Country of Publication:
- United States
- Language:
- ENGLISH
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