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Title: Synthesis of Mg(OH)2, MgO, and Mg nanoparticles using laser ablation of magnesium in water and solvents

Journal Article · · Optics and Lasers in Engineering
 [1];  [1];  [1];  [1];  [2]
  1. National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States)
  2. Univ. of Pittsburgh, PA (United States)

Laser ablation of magnesium in deionized water (DW), solutions of DW and sodium dodecyl sulfate (SDS) with different concentrations, acetone and 2-propanol has been conducted. The results showed that ablation in acetone and 2-propanol yielded MgO and Mg nanocrystallites as isolated particles and agglomerated chains probably intermixed with organic residues resulting from the alteration/decomposition of the solvents under the high-energy conditions. Brucite-like Mg(OH)2 particles were mainly produced by laser ablation of Mg in either DW or DW-SDS solutions. Ablation in DW yielded particles of fiber-like shapes having a diameter of about 5-10nm and length-as long as 150 nm. Materials produced in DW-SDS solutions were composed of various size and shape particles. Some had rough surfaces with irregular shapes. Small particles were about 20-30 nm and larger particles were about 120 nm. Particles with rodlike, triangular, and plate-like shapes were also observed.

Research Organization:
National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV, and Albany, OR (United States)
Sponsoring Organization:
USDOE Assistant Secretary for Fossil Energy (FE)
OSTI ID:
1015118
Report Number(s):
NETL-TPR-2182
Journal Information:
Optics and Lasers in Engineering, Vol. 46, Issue 11; ISSN 0143-8166
Publisher:
Elsevier
Country of Publication:
United States
Language:
English

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